Synthesis and spectroscopic characterization of two tetrasubstituted cationic porphyrin derivatives

An imidazolium tetrasubstituted cationic porphyrin derivative (the free base and its Zn(II) complex) with five-membered heterocyclic groups in the meso-positions were synthesized using microwave irradiation, and the compounds obtained characterized by (1)H-NMR and mass spectrometry. We observed that under microwave irradiation the yield is similar to when the synthesis is performed under conventional heating, however, the time required to prepare the porphyrins decreases enormously. In order to investigate the electronic state of these compounds, we employed UV-Vis and fluorescence spectroscopy combined with quantum chemical calculations. The results reveal the presence, in both compounds, of a large number of electronic states involving the association between the Soret and a blue-shifted band. The Soret band in both compounds also shows a considerable solvent dependence. As for emission, these compounds present low quantum yield at room temperature and no solvent influence on the fluorescence spectra was observed.     

以纤维素/AmimCl溶液制备纤维素气凝胶

利用离子液体AmimCl溶解结合超临界CO2干燥的方法制备了纤维素气凝胶材料.研究了不同初始浓度的纤维素溶液及其在不同凝固浴中制备的纤维素凝胶的流变行为,进一步考察了纤维素溶液浓度和凝固浴种类对纤维素气凝胶材料结构的影响.结果表明,随着初始纤维素溶液浓度的增大,气凝胶的孔结构逐渐致密,比表面积随之减小;凝固浴的组成对纤维素气凝胶的结构也有较大影响.采用适当的制备条件,可以制备出高比表面积的纤维素气凝胶材料.对纤维素气凝胶的热性能进行了表征,结果表明所得到的气凝胶材料具有较好的热稳定性和较高的炭残余含量.     

Streamline bifurcations and scaling theory for a multiple-wake model

We investigate the interaction between multiple arrays of (reverse) von Kármán streets as a model for the mid-wake regions produced by schooling fish. There exist configurations where an infinite array of vortex streets is in relative equilibrium, that is, the streets move together with the same translational velocity. We examine the topology of the streamline patterns in a frame moving with the same translational velocity as the streets. Fluid is advected along different paths depending on the distance separating two adjacent streets. When the distance between the streets is large enough, each street behaves as a single von Kármán street and fluid moves globally between two adjacent streets. When the streets get closer to each other, the number of streets that enter into partnership in transporting fluid among themselves increases. This observation motivates a bifurcation analysis which links the distance between streets to the maximum number of streets transporting fluid among themselves. We describe a scaling law relating the number of streets that enter into partnership as a function of the three main parameters associated with the system, two associated with each individual street (determining the aspect ratio of the street), and a third associated with the distance between neighboring streets. In the final section we speculate on the timescale associated with the lifetime of the coherence of this mid-wake scaling regime.     

Symmetric power functoriality for holomorphic modular forms

Publications mathématiques de l'IHÉS - We show that stationary characters on irreducible lattices $\Gamma < G$ of higher-rank connected semisimple Lie groups are conjugation...     

Influence of entrance channel properties on heavy-ion reaction dynamics

In the fusion of heavy nuclei, there is a distribution of fusion barrier energies resulting from coupling between intrinsic motion and internal degrees of freedom. Precise experimental measurements of excitation functions have allowed the extraction of the distributions by taking the second derivative using a point-difference method. In the case of statically deformed nuclei, experimental data shows that the different fusion barrier energies correspond to different physical configurations of the colliding nuclei, the latter affecting the subsequent dynamical trajectories over the potential energy surface, influencing the ultimate reaction products, as for example in quasi-fission. The fusion barrier distribution is also valuable in understanding the fusion of weakly bound nuclei, enabling a reliable prediction of the expected fusion cross-sections, and thus the determination of fusion suppression factors at above-barrier energies. Received: 1 May 2001 / Accepted: 4 December 2001     

费密共振和甲烷的振动能谱

用局域模模型来解释甲烷的伸展和弯曲振动能谱，其中伸展振动和弯曲振动间的相互作用用费密共振项来描写，它由一个伸展振子的玻色产生（或湮没）算子和两个弯曲振子的玻色湮没（或产生）算子乘积的T_d不变组合构成．这模型包含10个参数，与已发表的甲烷振动能谱的实验数据比较，得到能量的方均根偏差为12.38cm^－1． 关键词：     

硒的原子吸收分析进展

本文对1985年以来硒的原子吸收分析,从石墨炉法、氢化物法、氢化物-石墨炉法和火焰法四个方面的分析进展进行综合评述。