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51.
Terence Davis Matthew C Dix Michal J Rokicki Amy JC Brook Caroline S Widdowson David Kipling Mark C Bagley 《Chemistry Central journal》2011,5(1):1-5
To develop more potent small molecules with enhanced free radical scavenger properties, a series of N-substituted isatin derivatives was synthesized, and the cytoprotective effect on the apoptosis of PC12 cells induced by H2O2 was screened. All these compounds were found to be active, and N-ethyl isatin was found with the most potent activity of 69.7% protective effect on PC12 cells. Structure-activity relationship analyses showed the bioactivity of N-alkyl isatins decline as the increasing of the chain of the alkyl group, furthermore odd-even effect was found in the activity, which is interesting for further investigation. 相似文献
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Deeply supercooled water droplets held containerless in an acoustic levitator are investigated with high-energy X-ray scattering. The temperature dependence of the X-ray structure function is found to be nonlinear. Comparison with two popular computer models reveals that structural changes are predicted too abrupt by the TIP5P-E model, while the rate of change predicted by TIP4P-Ew is in much better agreement with experiment. The abrupt structural changes, predicted by the TIP5P-E model to occur in the temperature range between 260 and 240?K as water approaches the homogeneous nucleation limit, are unrealistic. Both models underestimate the distance between neighbouring oxygen atoms and overestimate the sharpness of the OO distance distribution. 相似文献
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Seidel S Bionta RM Blewitt G Bratton CB Casper D Ciocio A Claus R Dye ST Errede S Foster GW Gajewski W Ganezer KS Goldhaber M Haines TJ Jones TW Kielczewska D Kropp WR Learned JG LoSecco JM Matthews J Park HS Price L Reines F Schultz J Shumard E Sinclair D Sobel HW Stone JL Sulak L Svoboda R Thornton G van der Velde JC Wuest C 《Physical review letters》1988,61(22):2522-2525
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Shashwati Sen DK Aswal Ajay Singh TV Chandrasekhar Rao KP Muthe JC Vyas LC Gupta SK Gupta VC Sahni 《Pramana》2002,58(5-6):867-870
The MgB2 superconductor, synthesized using solid-state and liquid-phase sintering methods, have been characterized for various properties.
The upper critical field, irreversibility line and critical current density have been determined using magnetization data.
The current-voltage characteristics recorded under an applied magnetic field revealed the existence of vortex glass transition.
The surface analysis using X-ray photoelectron spectroscopy shows that MgB2 is sensitive to atmospheric degradation. 相似文献
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Park HS Blewitt G Cortez BG Foster GW Gajewski W Haines TJ Kielczewska D LoSecco JM Bionta RM Bratton CB Casper D Chrysicopoulou P Claus R Errede S Ganezer KS Goldhaber M Jones TW Kropp WR Learned JG Lehmann E Reines F Schultz J Seidel S Shumard E Sinclair D Sobel HW Stone JL Sulak LR Svoboda R van der Velde JC Wuest C 《Physical review letters》1985,54(1):22-25
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High-energy X-ray scattering (HEXS) has been used to understand the coordination environment of the uranyl ion in a perchlorate solution. Assuming the two coordinating oxo ligands bound to U(VI) are represented in a peak in the pair distribution function (PDF) at 1.766(1) A, integration of the peak intensity is used to quantify the charge located on the oxygens. The dioxo ligands are essentially neutral, as predicted by numerous published calculations, with a charge of -16.4(8) electrons. The peak in the PDF at 2.420(1) A is consistent with equatorial ligating waters. The intensity of this peak is inconsistent with an integral coordination number and is used to propose a solution equilibrium of five and four waters coordinating to the uranyl(VI) ion favoring the five-coordinate species. This equilibrium is then used to experimentally determine that five-coordinate uranyl is 1.19+/-0.42 kcal/mol more stable than its four-coordinate counterpart under the conditions of the experiment. Further peaks in the Fourier transform of the scattering data at 4.50, 7, and 8.7 A are attributed to uranium-solvent correlations. 相似文献