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71.
The Pd-catalysed conjugate addition of arylboronic acids to α,β-unsaturated cyclic ketones was studied under controlled microwave irradiation conditions. A variety of catalysts, bases and
solvents was explored in order to achieve optimum yields in the shortest possible reaction time. Under optimised conditions
(Pd(OAc)2/2,2′-bipyridine and KF in a mixture of toluene, water, and acetic acid and 10 min microwave irradiation), a range of arylboronic
acids was successfully added to several cyclic enones. With chiral phosphane ligands, a promising enantioselectivity was obtained
(85 % ee). 相似文献
72.
Sofia Nikolaou Sérgio Hiroshi Toma Vagner Roberto de Souza Juliano B. Alves Koiti Araki Henrique Eisi Toma 《Transition Metal Chemistry》2011,36(7):775-783
The triruthenium carboxylate cluster [Ru3O(OAc)6(py)2(bpp)]+ (OAc = acetate) containing the bridging 1,3-bis(4-pyridyl)propane (bpp) ligand, and its dimeric species [{Ru3O(OAc)6(py2)}2(μ-bpp)]2+ were synthesized in order to investigate their inclusion compounds with β-cyclodextrin (β-CD). Characterization of the complexes
was carried out based on spectroscopic, electrochemical and spectroelectrochemical techniques, while the formation of inclusion
complexes was evaluated using 1H NMR/NOESY spectroscopy. Since bpp is a flexible ligand, a DFT study was carried out in order to characterize its conformational
isomers and their possible role in the host–guest chemistry with β-CD. Instead of observing the formation of inclusion compounds
with different stoichiometries, we observed the formation of 1:1 bpp/β-CD compounds in which the bpp ligand assumes different
conformations. The assembly of polymetallic rotaxane species was successfully demonstrated by monitoring the 1H NMR spectra of the monomeric cluster species in the presence of aquapentacyanoferrate(II) ions and β-CD. 相似文献
73.
Vukomanović M Zavašnik-Bergant T Bračko I Skapin SD Ignjatović N Radmilović V Uskoković D 《Colloids and surfaces. B, Biointerfaces》2011,87(2):226-235
A step-by-step analysis of the formation and the drug loading of the poly(D,L-lactide-co-glycolide)/hydroxyapatite (PLGA/HAp) composite was carried out in a perspective of the following parameters: the structure, the morphology and the adsorption/desorption properties of the composite's bioceramic part. The authors demonstrated the importance of the material's capacity to form a fine dispersion of solid HAp particles, as an initial step, for the further loading of the drug and for the formation of the core-shell structures. The nanometer-sized rods of HAp have the capacity of ensuring a rapid adsorption and a controlled desorption of the drug from their surface, and they can act as a nucleating site for the formation of polymeric cores. Each component of this material was labeled with fluorescence dye, which enabled an insight into the distribution of the components in the core-shells that were obtained as the final outcome. Such an analysis showed a high level of uniformity among the cores enclosed within polymeric shells. From a practical perspective, the labeling of each component of the composite can be regarded as an additional functionality of the material: labeling can enable us to monitor its action during the healing process. This ability to be easily detected is expected to enhance the procedure for the controlled delivery of antibiotics after their local implantation of carriers loaded with the antibiotic and to provide more careful control over this process. 相似文献
74.
Singh P Toma FM Kumar J Venkatesh V Raya J Prato M Verma S Bianco A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(24):6772-6780
Single‐walled carbon nanotubes (SWCNTs) have been covalently functionalized with uracil nucleobase. The hybrids have been characterized by using complementary spectroscopic and microscopic techniques including solid‐state NMR spectroscopy. The uracil‐functionalized SWCNTs are able to self‐assemble into regular nanorings with a diameter of 50–70 nm, as observed by AFM and TEM. AFM shows that the rings do not have a consistent height and thickness, which indicates that they may be formed by separate bundles of CNTs. The simplest model for the nanoring formation likely involves two bundles of CNTs interacting with each other via uracil–uracil base‐pairing at both CNT ends. These nanorings can be envisaged for the development of advanced electronic circuits. 相似文献
75.
The popularity of dedicated microwave reactors in many academic and industrial laboratories has produced a plethora of synthetic protocols that are based on this enabling technology. In the majority of examples, transformations that require several hours when performed using conventional heating under reflux conditions reach completion in a few minutes or even seconds in sealed-vessel, autoclave-type, microwave reactors. However, one severe drawback of microwave chemistry is the difficulty in scaling this technology to a production-scale level. This Concept article demonstrates that this limitation can be overcome by translating batch microwave chemistry to scalable continuous-flow processes. For this purpose, conventionally heated micro- or mesofluidic flow devices fitted with a back-pressure regulator are employed, in which the high temperatures and pressures attainable in a sealed-vessel microwave chemistry batch experiment can be mimicked. 相似文献
76.
Given a graph G and a bipartition of its vertices, the edge-ratio is the minimum for both classes so defined of their number of internal edges divided by their number of cut edges. We prove that maximizing edge-ratio is NP-complete. 相似文献
77.
Karin Cvetko-Vah Damjana Kokol Bukov?ek Toma? Ko?ir Ganna Kudryavtseva 《Acta Mathematica Hungarica》2011,131(1-2):1-24
We prove that the minimal cardinality of a semitransitive subsemigroup in the singular part $\mathcal{I}_{n}\setminus \mathcal{S}_{n}$ of the symmetric inverse semigroup $\mathcal{I}_{n}$ is 2n?p+1, where p is the greatest proper divisor of n, and classify all semitransitive subsemigroups of this minimal cardinality. 相似文献
78.
Nenad Velisavljevic & Yogesh K. Vohra 《高压研究》2013,33(2):295-302
It is generally observed that the rare earth metals adapt an orthorhombic alpha-uranium (α-U) structure at high pressures following the delocalization of 4f shell under compression. We examine the stability of the α-U structure in praseodymium metal at ultrahigh pressures of 313 GPa (volume compression V/V 0?=?0.343) in a diamond anvil cell at room temperature. X-ray diffraction data show a transformation from the α-U structure to a primitive orthorhombic P212121 phase at 147±5 GPa, which is characterized by the anisotropic compressibility of various crystallographic axes. This anisotropic compressibility leads to an interesting situation when the b-axis and the c-axis of the orthorhombic phase become nearly equal above 260 GPa and the structure can be regarded as a pseudo-tetragonal phase. Our present study shows that the 4f band metal Pr does not adapt a body centred tetragonal phase as predicted by theory, but instead novel crystallographic phases are observed at extreme compressions. The present results have a broader impact on the stability of the α-U phase in a variety of f-band systems at high pressures. 相似文献
79.
In this paper we use the notion of statistical convergence of infinite series naturally introduced as the statistical convergence of the sequence of the partial sums of the series. We will discuss some questions related to the convergence of subseries of a given series. 相似文献
80.
Holomorphic vector bundles on primary Kodaira surfaces 总被引:2,自引:0,他引:2