Fatigue Properties of Nickel Titanium and their Improvement Using Low-Energy High-Current Electron Beams

Russian Physics Journal - It is shown that by irradiating nickel titanium surfaces with a low-energy high-current electron beam of a microsecond duration at the energy densities of Es = 1.5 and 3.7...     

A Combined Model of Charging of the Surface and Bulk of a Dielectric Target by Electrons with the Energies 10–30 keV

Russian Physics Journal - A physico-mathematical model of the processes of radiation-induced charging of dielectric materials with open surfaces, irradiated with monoenergetic electrons in the...     

Direct use of unassigned resonances in NMR structure calculations with proxy residues

We present a method that significantly enhances the robustness of (automated) NMR structure determination by allowing the NOE data corresponding to unassigned NMR resonances to be used directly in the calculations. The unassigned resonances are represented by additional atoms or groups of atoms that have no interaction with the regular protein atoms except through distance restraints. These so-called "proxy" residues can be used to generate NOE-based distance restraints in a similar fashion as for the assigned part of the protein. If sufficient NOE information is available, the restraints are expected to place the proxies at positions close to the correct atoms for the unassigned resonance, which can facilitate subsequent assignment. Convergence can be further improved by supplying additional information about the possible identities of the unassigned resonances. We have implemented this approach in the widely used automated assignment and structure calculation protocols ARIA and CANDID. We find that it significantly increases the robustness of structure calculations with regard to missing assignments and yields structures of higher quality. Our approach is still able to find correctly folded structures with up to 30% randomly missing resonance assignments, and even when only backbone and beta resonances are present! This should be of significant value to NMR-based structural proteomics initiatives.     

Measuring direction in the coupling of biological oscillators: a case study for electroreceptors of paddlefish

Recently developed methods for estimating directionality in the coupling between oscillators were tested on experimental time series data from electroreceptors of paddlefish, because each electroreceptor contains two distinct types of noisy oscillators. One type of oscillator is in the sensory epithelia, and another type is in the terminals of afferent neurons. Based on morphological organization and our previous work, we expected unidirectional coupling, whereby epithelial oscillations synaptically influence the spiking oscillators of afferent neurons. Using directionality analysis we confirmed unidirectional coupling of oscillators embedded in electroreceptors. We studied the performance of directionality algorithms for decreasing length of data. Also, we experimentally varied the strength of oscillator coupling, to test the effect of coupling strength on directionality algorithms.     

Synthesis,structure, and electric properties of oxygen-deficient perovskites Ba<Subscript>3</Subscript>In<Subscript>2</Subscript>ZrO<Subscript>8</Subscript> and Ba<Subscript>4</Subscript>In<Subscript>2</Subscript>Zr<Subscript>2</Subscript>O<Subscript>11</Subscript>

Perovskite phases Ba₃In₂ZrO₈ and Ba₄In₂Zr₂O₁₁ with the nominal concentration of structural oxygen vacancies 1/9 and 1/12, respectively, were synthesized by solid-phase and solution methods. X-ray diffraction showed cubic symmetry of both phases with the unit cell parameter a = 0.4193(2) and 0.4204(3) nm, respectively. The absence of superstructural lines resulted in the conclusion on statistical arrangement of oxygen vacancies. Thermogravimetry and mass spectrometry proved that both phases can reversibly absorb water from gas phase (pH₂O = 2 × 10⁻² atm) with observed correlation between the concentration of oxygen vacancies and amount of absorbed water. The total water amount was up to 0.9 mol per formula unit or, if recalculated for perovskite unit ABO₃, 0.3 and 0.23 mol H₂O, respectively. The temperature curves of coductivity in the atmosphere with various partial water vapor pressures (pH₂O = 3 × 10⁻⁵ and 2 × 10⁻² atm) showed significantly higher conductivity and lower activation energy (0.52 eV) in humid atmosphere due to proton transfer. The proton conductivity is up to 5 × 10⁻⁴ Ohm⁻¹ cm⁻¹ at 300°C for Ba₃In₂ZrO₈ specimen. IR spectrometry showed that protons in the structure exist primarily in OH-groups.