Unusual rearrangement in the reactions of phenylmalonic acid dihydrazide with 1, 3‐Diketones

Phenylmalonic acid dihydrazide reacted with 2,4‐pentanedione to give, unexpectedly, 5,7‐dimethyl‐1,3‐dioxo‐2‐phenyl‐2,3‐dihydro‐1H‐pyrazolo[1,2‐a]pyrazole‐4‐ylium 5. The structure of the product is confirmed by X‐ray crystallography.     

Compositional dependence of the electrical conductivity of calcium vanadate glassy semiconductors

Scanning electron microscopy (SEM), X- ray diffraction (XRD), density (d), oxygen molar volume (V_m) and dc conductivity of different compositions of calcium vanadate glasses are reported. SEM exhibits a surface without any presence of a microstructure which is a characteristic of the amorphous phase. The overall features of these XRD curves confirm the amorphous nature of the present glasses. Density was observed to decrease with an increase in V₂O₅ content. The experimental results were analyzed with reference to theoretical models existing in the literature. It has been observed that the high-temperature conductivity data are consistent with Mott's nearest-neighbor hopping model. However, both Mott variable-range hopping (VRH) and Greaves intermediate range hopping models are found to be applicable. The hopping at high temperatures in the calcium vanadate glasses occurs by non-adiabatic process in contrast to the vanadate glasses formed with conventional network formers. The hopping model of Schnakenberg can predict the temperature dependence of the conductivity data. The percolation model of Triberis and Friedman applied to the small polaron hopping (SPH) regime is also consistent with data. The various model parameters such as density of states, hopping energy, etc., obtained from the best fits were found to be consistent with the glass compositions.     

Natural convection flows of Prabhakar-like fractional Maxwell fluids with generalized thermal transport

Journal of Thermal Analysis and Calorimetry - Natural convective flows of Prabhakar-like fractional viscoelastic fluids over an infinite vertical heated wall are studied by introducing the...     

Domino reactions of 1,3-bis-silyl enol ethers with benzopyrylium triflates: efficient synthesis of fluorescent 6H-benzo[c]chromen-6-ones, dibenzo[c,d]chromen-6-ones, and 2,3-dihydro-1H-4,6-dioxachrysen-5-ones

The condensation of 1,3-bis-silyl enol ethers with benzopyrylium triflates, generated in situ by the reaction of chromones with Me3SiOTf, afforded functionalized 2,3-dihydrobenzopyrans; treatment of the latter with NEt3 or BBr3 resulted in a domino retro-Michael-aldol-lactonization reaction and the formation of a variety of 7-hydroxy-6H-benzo[c]chromen-6-ones. The hydroxy group was functionalized by using Suzuki cross-coupling reactions. The methodology reported was applied to the synthesis of the natural product autumnariol and a new fluorescence dye, which exhibits promising optical properties. 2,3-Dihydro-1H-4,6-dioxachrysen-5-ones were prepared by condensation of chromones with 1,3-bis-silyl enol ethers containing a remote chloride group, domino retro-Michael-aldol-lactonization, and an intramolecular Williamson reaction.     

No slip boundary effects in non-Darcian mixed convection from a vertical wall in saturated porous media. Analytical solution

An analytical study is made for wall effects in non-Darcy mixed convection from vertical impermeable surfaces embedded in a saturated porous medium. The governing equations are transformed into a dimensionless form by non-similar transformation to cover both forced and natural convection dominated regimes. Two different dimensionless parameters that measure the strength of mixed convection were found in both regimes. The parameters of forced convection dominated regime can be related to those of natural convection dominated regime. An approximate analytical solution for the governing equations was obtained. Temperature and velocity profiles for both regimes are presented. Received on 9 September 1997     

Magnetic field effect on heat transfer and fluid flow characteristics of blood flow in multi-stenosis arteries

Heat and fluid flow characteristics of blood flow in multi-stenosis arteries in the presence of magnetic field is considered. A mathematical model of the multi-stenosis inside the arteries is introduced. A finite difference scheme is used to solve the governing equations in terms of vorticity-stream function along with their boundary conditions. The effect of magnetic field and the degree of stenosis on wall shear stress and Nusselt number is investigated. It was found that magnetic field modifies the flow patterns and increases the heat transfer rate. The severity of the stenosis affects the wall shear stress characteristics significantly. The magnetic field torque will increase the thermal boundary layer thickness and the temperature gradient in the streaming blood, and hence increasing the local Nusselt number     

Efficient synthesis of biaryl lactones by domino retro-Michael-aldol-lactonization reactions

Biaryl lactones were prepared by novel domino retro-Michael-aldol-lactonization reactions of 2,3-dihydropyrans.