Imbalance of zinc ion (Zn
2+) in human body causes diseases like Alzheimer’s and Parkinson’s and therefore Zn
2+ estimation in biological fluids has diagnostic values. Fluorescence “off-on” sensors have advantages of high sensitivity and in situ application over other sensors. A new fluorescent “off-on” Zn
2+ sensor, N-benzoate-N′ salicylaldehyde ethynelediamine (
L), has been synthesisied. In 1:1(v/v) CH
3OH:PBS (PBS?=?phosphate buffer solution),
L shows
ca. 20 times enhancement in fluorescence intensity on interaction with Zn
2+, due to snapping of photoinduced electron transfer (PET) process, which is selective over metal ions - Na
+, K
+, Ca
2+, Ni
2+, Cu
2+, Cd
2+, Hg
2+ and Pb
2+. These metal ions either individually or all together does not interfere the sensing ability of
L towards Zn
2+. A 1:1 interaction between
L and Zn
2+ ion with binding constant 10
4.25 has been established from spectroscopic data.
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