Sequential single pion production explaining the dibaryon "d*(2380)" peak

In this study, we investigate the two step sequential one pion production mechanism, that is, \begin{document}$ np(I=0)\to $\end{document}\begin{document}$ \pi^-pp $\end{document} followed by the fusion reaction \begin{document}$ pp\to \pi^+d $\end{document}, to describe the \begin{document}$ np\to \pi^+\pi^-d $\end{document} reaction with \begin{document}$ \pi^+\pi^- $\end{document} in state \begin{document}$ I=0 $\end{document}. In this reaction, a narrow peak identified with a "\begin{document}$ d(2380) $\end{document}" dibaryon has been previously observed. We discover that the second reaction step \begin{document}$ pp\to \pi^+d $\end{document} is driven by a triangle singularity that determines the position of the peak of the reaction and the high strength of the cross section. The combined cross section of these two mechanisms produces a narrow peak with a position, width, and strength, that are compatible with experimental observations within the applied approximations made. This novel interpretation of the peak accomplished without invoking a dibaryon explains why this peak has remained undetected in other reactions.     

Highly C6-selective and quantitative modification of cellulose: nucleoside-appended celluloses to solubilize single walled carbon nanotubes

Cellulose derivatives having thymidine and/or trimethylammonium appendages exclusively at C6 positions can be prepared in a convenient manner through C6-selective bromination/azidation on cellulose to afford 6-azido-6-deoxycellulose followed by chemoselective [3 + 2] cycloadditions using Cu⁺ as a catalyst. These cellulose derivatives take unique sheet-like structures and function as “wrapping papers” to effectively disperse single-walled carbon nanotubes in water.     

Acceptable distortion and magnification of images on reflective surfaces in an augmented reality system

In this paper, we investigated the consistency of visual perception for the change of reflection images in an augmented reality setting. Reflection images with distortion and magnification were generated by changing the capture position of the environment map. Observers evaluated the distortion and magnification in reflection images where the reflected objects were arranged symmetrically or asymmetrically. Our results confirmed that the observers’ visual perception was more sensitive to changes in distortion than in magnification in the reflection images. Moreover, the asymmetrical arrangement of reflected objects effectively expands the acceptable range of distortion compared with the symmetrical arrangement.     

Helix-mediated over 1 nm-range chirality recognition by ligand-to-ligand interactions of dinuclear helicates

Long-range chirality recognition between the two chiral guest ligands can be tuned based on the helix distances (d_Ln–Ln = 11.5 and 14.0 Å) of bis-diketonate bridged dinuclear lanthanide complexes (2Th and 3Th, respectively) used as mediators. Both 2Th and 3Th form one-dimensional (1D) helical structures upon terminal binding of two chiral guest co-ligands (L^R or L^S). Long-range chiral self-recognition is achieved in self-assembly of 2Th with L^R and L^S to preferentially form homochiral assemblies, 2Th-L^R·L^R and 2Th-L^S·L^S, whereas there is no direct molecular interaction between the two guest ligands at the terminal edges. X-ray crystal structure analysis and density functional theory studies reveal that long-range chiral recognition is achieved by terminal ligand-to-ligand interactions between the bis-diketonate ligands and chiral guest co-ligands. Conversely, in self-assembly of 3Th with a longer helix length, statistical binding of L^R and L^S occurs, forming heterochiral (3Th-L^R·L^S) and homochiral (3Th-L^R·L^R and 3Th-L^S·L^S) assemblies in an almost 1 : 1 ratio. When phenyl side arms of the chiral guest co-ligands are replaced by isopropyl groups (L′^R and L′^S), chiral self-recognition is also achieved in the self-assembly process of 3Th with the longer helix length to generate homochiral (3Th-L′^R·L′^R and 3Th-L′^S·L′^S) assemblies as the favored products. Thus, subtle modification of the chiral guests is capable of achieving over 1.4 nm-range chirality recognition.

Long-range chirality recognition between the two chiral guest ligands can be tuned based on the helix distances (d_Ln–Ln = 11.5 and 14.0 Å) of bis-diketonate bridged dinuclear lanthanide complexes (2Th and 3Th, respectively).     

One-pot reactions of bicyclic zinc enolate generated from Ni-catalyzed reductive cyclization to furnish octahydro-4,7-ethanobenzofuran-9-one derivatives

The one-pot reactions of catalytically generated bicyclic zinc enolate with various electrophiles are reported. The zinc enolate as a key intermediate is efficiently delivered from Ni-catalyzed reductive cyclization of alkynyl cyclohexadienone. Employing aldehydes, imine, nitroalkene, and α,β-unsaturated carbonyl compounds as electrophiles, this new class of one-pot reactions gave multi-functionalized cis-hydrobenzofurans and octahydro-4,7-ethanobenzofuran-9-one derivatives in moderate to good yields.