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31.
A. A. Udovenko N. V. Makarenko R. L. Davidovich L. A. Zemnukhova E. V. Kovaleva 《Journal of Structural Chemistry》2010,51(4):765-768
Single crystal X-ray diffraction analysis is used to determine the crystal structure of a newly synthesized molecular complex
compound of antimony(III) fluoride with L-leucine of the composition SbF3(C6H13NO2) (orthohombic crystal system: a = 5.7948(8) ?, b = 6.2433(9) ?, c = 28.594(4) ?, Z = 4, P212121 space group). The structure consists of SbF3 molecules and L-leucine bound into polymer chains by bidentate bridging carboxyl groups of amino acid molecules. Weak Sb…F(1)b bonds combine the adjacent chains into polymer ribbons organized by N-H…. F and N-H…. O hydrogen bonds into a framework. 相似文献
32.
Increasing interest in studying community structures, or clusters in complex networks arising in various applications has led to a large and diverse body of literature introducing numerous graph-theoretic models relaxing certain characteristics of the classical clique concept. This paper analyzes the elementary clique-defining properties implicitly exploited in the available clique relaxation models and proposes a taxonomic framework that not only allows to classify the existing models in a systematic fashion, but also yields new clique relaxations of potential practical interest. Some basic structural properties of several of the considered models are identified that may facilitate the choice of methods for solving the corresponding optimization problems. In addition, bounds describing the cohesiveness properties of different clique relaxation structures are established, and practical implications of choosing one model over another are discussed. 相似文献
33.
Kovaleva V. V. Kuznetsov N. M. Vdovichenko A. Yu. Zagoskin Y. D. Grigoriev T. E. Chvalun S. N. 《Doklady Physical Chemistry》2022,502(2):23-27
Doklady Physical Chemistry - The rheological behavior of a 1 wt % suspension of highly porous chitosan particles in polydimethylsiloxane in a high electric field has been studied as a function of... 相似文献
34.
Diphenylphosphinoylallenes containing a ClCH2 group were synthesized, and their reaction with cytisine was studied. It was shown that the reaction involves exclusives as nucleophilic substitution of chlorine in the chloromethyl group. The synthesized conjugates of cytisine with diphenylphosphinoylallene derivatives are of interest as potential agonists of nicotinic acetylcholine neuroreceptors (nAChRs). 相似文献
35.
A. A. Udovenko N. V. Makarenko R. L. Davidovich L. A. Zemnikhova E. V. Kovaleva 《Journal of Structural Chemistry》2010,51(5):904-908
The crystal structure of L-leucinium tetrafluoroantimonate(III) of the composition (C6H14NO2)SbF4 (orthorhombic symmetry: a = 6.1459(6) Å, b = 14.994(1) Å, c = 24.789(2) Å, Z = 8, P 212121 space group) synthesized for the first time is determined. The (C6H14NO2)SbF4 structure represents a new structure type of tetrafluoroantimonate(III). It is formed by (C6H14NO2)+ cations and chain complex [Sb2F8]n 2n anions composed of Sb2F8 dimers linked into chains by bridging F atoms. The Sb2F8 dimers consist of SbF3 and SbF5 groups bound by bridging fluoride atoms of the SbF5 group. Chains in the structure are linked by N-H…F, N-H…O, and O-H…F hydrogen bonds into a three-dimensional framework. 相似文献
36.
A procedure and instrument for the determination of dissolved electrolytes and nonelectrolytes in solutions are described. The analysis was performed by measuring the size of a polymer granule placed in the test solution. It was found that various polymers can be used for the determination of the nature or concentration of a solute. This allows one to perform the analysis in various solvents. The use of small granules allows one to decrease the sample volume to tenths fractions of a microliter. 相似文献
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L. S. Molochnikov E. G. Kovaleva E. L. Golovkina I. A. Kirilyuk I. A. Grigor’ev 《Colloid Journal》2007,69(6):769-776
Acidic characteristics of various inorganic materials, such as silica gel, aluminum, and titanium(IV) oxides, original and modified with F? and SO 4 2? ions, in the form of hydrogels and nanostructured powders doped by copper(II) ions, are studied. It is shown that pH values inside pores of the studied sorbents (pHintr) differ from the pH of external solutions by 0.5–1.1 units. In the pores of original γ-Al2O3, the pHintr values are higher, while, in pores of γ-Al2O3 samples modified with F? и SO 4 2? , as well as nonmodified α-Al2O3, SiO2 gel, and TiO2 hydrogels, pHintr are lower compared to the pH of the external solution. It is found that pHintr decreases, as the content of Cu2+ ions in the TiO2 phase grows, and, beginning with a certain moment, it coincides with pH of an equilibrium solution. The pK a values of functional group dissociation in some materials are determined. It is shown that, using spin probes, that is, pH-sensitive nitroxyl radicals, the electrostatic potential of the surface of nanostructured TiO2 can be estimated. 相似文献
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