Decoding the dynamics of a single trapped atom from photon correlations

Received: 4 September 1998     

Polymer based optical interconnect components for high-speed Datacom approaches - Micromachining supported manufacturing

Optical data communication will play an important role in future high speed data links. Especially in Datacom applications data rates in Gbps area will be desired. An overall low cost approach is needed on both sides, for the opto-electronic integration and for the passive optical interconnects. Opto-electronic integration will be reached through the use of one- or bidirectional transceivers for Datacom based - in future - on surface emitting lasers (VCSEL), instead of LEDs used today, and economically favorable silicon detectors. This additionally requires passive optical interconnects using beam shaped low-cost micro-optical components such as, microlenses for in- and out-coupling which are more and more popular in recently developed opto-electronic devices.Ideally, micro-optical components can be integrated in passive optical interconnects and replicated in polymer materials for the cost reducing. Hence, the increase of data rate depends on the quality of the optical surfaces. In this paper the micromechanical manufacturing technologies of microcomponents with optical surfaces are discussed. Furthermore, polymer based components are presented which can be used for coupling and routing of optical signals, e.g. a passive optical interconnect for the passive coupling into photodiode or from VCSEL and optical N × M star couplers. The polymer based interconnect module has been realized in different polymers (polymethyl methacrylate, PMMA, and cycloolefin copolymer, COC). Total loses and data rates achieved are 3.3 dB and 2 Gbps, respectively. Average total loss an e.g., polymer based 16 × 16 optical star coupler is better than 17 dB per channel with a uniformity of 3 dB. For replication of polymer substrates of these components hot embossing tools have been produced by combination of deep lithography, ultra-precise milling and micro-machining.     

Determination of flunixin and ketoprofen in milk by liquid chromatography-tandem mass spectrometry

A relatively fast, simple and very selective liquid chromatography-tandem mass spectrometry (LC-MS-MS) method for the detection of flunixin, its 5-hydroxymetabolite and ketoprofen in raw milk has been developed and validated. After a simple extraction with acetonitrile and partial evaporation of the organic phase, the extract was filtered and directly injected into the LC-MS-MS system on a Symmetry C₁₈ column. The parent ions were selected for further fragmentation with argon. The method developed was partially validated according to Commission Decision 2002/657/EC [Commission Decision 2002/657/EC implementing Council Directive 96/23/EC concerning the performance of analytical methods and the interpretation of results]. The validation parameters were linearity, specificity, repeatability, recovery and decision limit (CCα). CCα varied from 0.5 μg kg⁻¹ for flunixin and 5-hydroxyflunixin to 1 μg kg⁻¹ for ketoprofen.Holstein-Friesian cows were given either Ketofen^® or Finadyne^® via an intravenous injection at the maximum dose as written in the instructions. Cows were milked twice a day and all samples were analysed by the method described. The highest concentrations found for ketoprofen, flunixin and 5-hydroxyflunixin were 2.5, 6.7 and 590 μg l⁻¹, respectively. The concentration of 5-hydroxyflunixin declined rapidly to concentrations below the MRL value of 40 μg l⁻¹. It can be concluded that the withdrawal time proposed by the pharmaceutical companies, 12 h after the last dosing, is acceptable for both compounds.     

High power and high efficiency green light emitting diode on free‐standing semipolar (11$ \bar 2 $2) bulk GaN substrate

We demonstrate a high power green InGaN/GaN multiple‐quantum‐well (MQW) light emitting diode (LED) with a peak emission wavelength of 516 nm grown on low extended defect density semipolar (11 2) bulk GaN substrate by metal organic chemical vapor deposition. The output power and external quantum efficiency (EQE) at drive currents of 20 and 100 mA under direct current (DC) operation were 5.0 mW, 10.5% and 15.6 mW, 6.3%, respectively. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Rigid-rod push-pull naphthalenediimide photosystems

Design, synthesis and evaluation of advanced rigid-rod pi-stack photosystems with asymmetric scaffolds are reported. The influence of push-pull rods on self-organization, photoinduced charge separation and photosynthetic activity is investigated and turns out to be surprisingly small overall.     

Excited-state dynamics of donor-acceptor bridged systems containing a boron-dipyrromethene chromophore: interplay between charge separation and reorientational motion

The excited-state dynamics of a series of electron donor-acceptor bridged systems (DABS) consisting of a boron-dipyrromethene chromophore covalently linked to a dinitro-substituted triptycene has been investigated using femtosecond time-resolved spectroscopy. The chromophores differ by the number of bromine atom substituents. The fluorescence lifetime of the DABS without any bromine atom is strongly reduced when going from toluene to polar solvents, this shortening being already present in chloroform. This effect is about 10 times weaker with a single bromine atom and negligible with two bromine atoms on the chromophore. The excited-state lifetime shortening is ascribed to a charge transfer from the excited chromophore to a nitrobenzene moiety, the driving force of this process depending on the number of bromine substituents. The occurrence of this process is further confirmed by the investigation of the excited-state dynamics of the chromophore alone in pure nitrobenzene. Surprisingly, no correlation between the charge separation time constant and the dielectric properties of the solvents could be observed. However, a good correlation between the charge separation time constant and the diffusional reorientation time of the chromophore alone, measured by fluorescence anisotropy, was found. Quantum chemistry calculations suggest that quasi-free rotation about the single bond linking the chromophore to the triptycene moiety permits a sufficient coupling of the donor and the acceptor to ensure efficient charge separation. The charge separation dynamics in these molecules is thus controlled by the reorientational motion of the donor relative to the acceptor.