全文获取类型
收费全文 | 1232篇 |
免费 | 56篇 |
国内免费 | 4篇 |
专业分类
化学 | 893篇 |
晶体学 | 10篇 |
力学 | 49篇 |
数学 | 122篇 |
物理学 | 218篇 |
出版年
2023年 | 8篇 |
2022年 | 63篇 |
2021年 | 51篇 |
2020年 | 45篇 |
2019年 | 36篇 |
2018年 | 44篇 |
2017年 | 38篇 |
2016年 | 76篇 |
2015年 | 35篇 |
2014年 | 40篇 |
2013年 | 124篇 |
2012年 | 66篇 |
2011年 | 69篇 |
2010年 | 41篇 |
2009年 | 50篇 |
2008年 | 59篇 |
2007年 | 44篇 |
2006年 | 41篇 |
2005年 | 39篇 |
2004年 | 28篇 |
2003年 | 33篇 |
2002年 | 23篇 |
2001年 | 16篇 |
2000年 | 12篇 |
1999年 | 7篇 |
1998年 | 11篇 |
1997年 | 17篇 |
1996年 | 15篇 |
1995年 | 10篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 5篇 |
1983年 | 10篇 |
1982年 | 6篇 |
1981年 | 10篇 |
1980年 | 4篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1975年 | 5篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1970年 | 3篇 |
1961年 | 3篇 |
排序方式: 共有1292条查询结果,搜索用时 15 毫秒
131.
Distributed point source method (DPSM) is gradually gaining popularity in the field of non-destructive evaluation (NDE). DPSM is a semi-analytical technique that can be used to calculate the ultrasonic fields produced by transducers of finite dimension placed in homogeneous or non-homogeneous media. This technique has been already used to model ultrasonic fields in homogeneous and multi-layered fluid structures. In this paper the method is extended to model the ultrasonic fields generated in both fluid and solid media near a fluid-solid interface when the transducer is placed in the fluid half-space near the interface. Most results in this paper are generated by the newly developed DPSM technique that requires matrix inversion. This technique is identified as the matrix inversion based DPSM technique. Some of these results are compared with the results produced by the Rayleigh-Sommerfield integral based DPSM technique. Theory behind both matrix inversion based and Rayleigh-Sommerfield integral based DPSM techniques is presented in this paper. The matrix inversion based DPSM technique is found to be very efficient for computing the ultrasonic field in non-homogeneous materials. One objective of this study is to model ultrasonic fields in both solids and fluids generated by the leaky Rayleigh wave when finite size transducers are inclined at Rayleigh critical angles. This phenomenon has been correctly modelled by the technique. It should be mentioned here that techniques based on paraxial assumptions fail to model the critical reflection phenomenon. Other advantages of the DPSM technique compared to the currently available techniques for transducer radiation modelling are discussed in the paper under Introduction. 相似文献
132.
Synthesis of Nanoporous Ni‐Co Mixed Oxides by Thermal Decomposition of Metal‐Cyanide Coordination Polymers 下载免费PDF全文
Mohamed B. Zakaria Dr. Ming Hu Dr. Malay Pramanik Dr. Cuiling Li Dr. Jing Tang Prof. Ali Aldalbahi Prof. Saad M. Alshehri Dr. Victor Malgras Prof. Yusuke Yamauchi 《化学:亚洲杂志》2015,10(7):1541-1545
A straightforward strategy to prepare nanoporous metal oxides with well‐defined shapes is highly desirable. Through thermal treatment and a proper selection of metal‐cyanide coordination polymers, nanoporous nickel‐cobalt mixed oxides with different shapes (i.e., flakes and cubes) can be easily prepared. Our nanoporous materials demonstrate high electrocatalytic activity for oxygen evolution reaction. 相似文献
133.
Alkylation of N,N-dialkylcarboxamides with 1,3-dehydroadamantane has been accomplished for the first time. The reaction involves the C–H bond in the α-position with respect to the carbonyl group and provides a convenient one-step preparation of substituted carboxylic acid amides containing an 1-adamantyl substituent and a pharmacophoric group in the amide moiety. 相似文献
134.
Olivier Gicque Dominique Thévenin Nasser Darabiha 《Flow, Turbulence and Combustion》2005,73(3-4):307-321
In this paper we wish to investigate the occurrence of super-equilibrium temperature values, observed in many experimental
configurations. We would like to understand the origin of this phenomenon. Previous authors have already shown that differential
diffusion can lead to considerable changes in the temperature field and we would like to build on top of this observation.
We investigate numerically super-equilibrium combustion by considering both laminar counter-flow and turbulent diluted hydrogen/air
diffusion flames. These turbulent flames are computed using direct numerical simulations (DNS). A detailed reaction mechanism
is employed and the transport properties are modeled using multicomponent diffusion velocities, including the Soret effect.
Analyzing these results we introduce three complementary parameters (dilution-free mixture fraction, dilution excess and local
enthalpy) to describe the local combustion conditions. Introducing a measure of dilution separately from the mixture fraction
is necessary for a proper analysis. Using this set of parameters it becomes possible to explain super-equilibrium temperature
levels as a consequence of differential diffusion. 相似文献
135.
136.
A. S. Hanafi Saad A. El-Sayed M. E. Mostafa 《Experimental Thermal and Fluid Science》2002,25(8):631-649
Experimental studies were carried out to investigate the fluid flow and heat transfer around a heated circular cylinder which was placed at various distances of a wall boundary with different geometries (flat or curved plate) with subcritical Reynolds number ranging from 3.5×103 to 104. The effects of plate geometry (aspect ratio: W|H=1.0,1.5 and 2.0, and rim angle, φ=0°,60°,90°, and 120°) and gap ratio, (G|D=0.0,0.86,2.0,7.0,10.0) on the fluid flow and heat transfer characteristics (static pressure around cylinder surface, wake width, base pressure, pressure drag coefficients, velocity distribution, and both local and mean Nusselt numbers) were presented. Also flow visualization was carried out to illustrate the flow patterns around the cylinder at various gap ratios (G|D). It was found that the heat transfer and fluid flow characteristics are dependent on the plate geometry at all tested gap ratios, except for G|D=7.0 and 10.0, they are independent of the plate geometry. 相似文献
137.
Soghra Farzipour Mina Saeedi Mohammad Mahdavi Hossein Yavari Mohammadreza Mirzahekmati Nasser Ghaemi 《合成通讯》2014,44(4):481-487
Clean and easy preparation of quinazolin-4(3H)-one derivatives using 2-aminobenzamides and Vilsmeier reagent is described. 2-Aminobenzamides were converted into the corresponding quinazolinones under mild and efficient conditions, in good yields without undesirable by-products.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
138.
Considering the thermodynamic aspects and reaction pathways of chemical adsorption of NH3 molecule at the open ends of boron nitride nanotubes (BNNTs), theoretically, it was found that the open-ended BNNTs are able
to cleave the N–H bond of NH3 via a one- or two-stepwise mechanism. The N-enriched and B-enriched open-ended BNNTs show a nucleophilic and electrophilic
behavior toward the NH3, respectively. Besides, some effects of this chemical adsorption on the electronic properties of BNNTs were explored. 相似文献
139.
A series of S-glycosyl and S-alkyl derivatives of 4-amino-3-mercapto-6-(2-(2-thienyl)vinyl)-1,2,4-triazin-5(4H)-one (1) were synthesized using different halo compounds such as preacetylated sugar bromide, 4-bromobutylacetate, 2-acetoxyethoxy-methyl bromide, 3-chloropropanol, 1,3-dichloro-2-propanol, epichlorohydrin, allyl bromide, propargyl bromide, phthalic and succinic acids in POCl3. The structures of the synthesized compounds have been deduced from their elemental analysis and spectral (IR, 1H-NMR, and 13C-NMR) data. Some of the synthesized compounds were screened as anticancer agents. Significant anticancer activities were observed in vitro for some members of the series, and compounds 4-Amino-3-(3-hydroxypropylthio)-6-(2-(2-thienyl)vinyl)-1,2,4-triazin-5(4H)-one (12) and 3-(4-Oxo-3-(2-(2-thienyl)vinyl)-4H-[1,3,4]thiadiazolo-[2,3-c][1,2,4]tr-iazin-7-yl)propanoic acid (18) are active cytotoxic agents against different cancer cell lines. 相似文献
140.
Abedi A Safari N Amani V Khavasi HR 《Dalton transactions (Cambridge, England : 2003)》2011,40(26):6877-6885
The complexes [Fe(dm4bt)(3)][FeCl(4)](2) (1) and [Fe(dm4bt)(3)][FeBr(4)](2) (2) were prepared from the reaction of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) with FeCl(3)·6H(2)O and FeBr(3), respectively, in methanol. Both complexes were characterized by IR, UV-Vis and (1)H NMR spectroscopy and their structures were studied by single-crystal diffraction. The methylated bithiazole led to high spin Fe(II) centers in the octahedral cation part of complexes 1 and 2 with Fe-N distance of 2.220 ?, in spite of the low spin octahedral Fe(II) complexes with unsubstituted bithiazole ligands. Crystal structure determination of 2 was performed at 90, 120 and 298 K. Temperature reduction to 90 K resulted in a decrease in the Fe-N bond length to 2.206 ? which is still in the range of high spin Fe(II). Complex 1 shows a reversible mechanochromic effect from the crystalline phase to powder form from red to yellow; it also displays reversible photochromism from yellow to green in solution under sunlight. The magnetic behaviour of the complexes was also studied at 2-300 K. The temperature dependence of χ(m)T curves for the two forms of 1, crystal and powder, demands some changes in their magnetic behavior, causing different colors i.e. red and yellow. At low temperatures, χ(m)T decreases where the decrease starts at around 65 K for compound 1, and at around 100 K for compound 2, due to different counterions. The two complexes exhibit antiferromagnetism at around 4 K. 相似文献