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51.
M.A. Nasser M.M. Gazzaly J.V. Geaga B. Höistad G. Igo J.B. McClelland A.L. Sagle H. Spinka J.B. Carroll V. Perez-Mendez E.T.B. Whipple 《Nuclear Physics A》1978,312(3):209-216
The p-4He elastic differential cross section has been measured at a kinetic energy of 2.68 GeV. The momentum transfer region studied is t = 0.15–0.66 (GeV/c)2. The cross section displays a shallow first minimum and shape very similar to recent data at 1 GeV. 相似文献
52.
Nasser?Mohammed?HosnyEmail author Abdel-Hamid?M.?Shallaby 《Transition Metal Chemistry》2007,32(8):1085-1090
Coordination compounds of MnII, CuII, FeIII and ZnII ions with 4-acetylpyridine nicotinoylhydrazone (4-APNH) were synthesized and characterized by elemental analyses, molar conductivity,
magnetic moments, i.r., u.v./vis., m.s., 1H-n.m.r. and thermal analyses. I.r. spectra show that the ligand can act either in the enol form as monovalent bidentate or
in the keto form as neutral bidentate depending on the metal salt used. Octahedral structures are proposed for Fe complex
and square – planar for the Cu complex, while tetrahedral structures were suggested for Zn and Mn complexes on the basis of
magnetic and spectral evidences. Semi-empirical calculations ZINDO/1 have been used to study the molecular geometry and the
harmonic vibrational spectra with the purpose to assist the experimental assignment of the complexes.
In memory of the late Professor Dr. Abdel Hamid M. Shallaby 2/5/2006 相似文献
53.
54.
This article describes the preconcentration of methyl methacrylate in produced water by the dispersive liquid–liquid microextraction using extraction solvents lighter than water followed by gas chromatography. In the present experiments, 0.4 mL dispersive solvent (ethanol) containing 15.0 μL extraction solvent (toluene) was rapidly injected into the samples and followed by centrifuging and direct injection into the gas chromatograph equipped with flame ionization detector. The parameters affecting the extraction efficiency were evaluated and optimized including toluene (as extraction solvent), ethanol (as dispersive solvent), 15 μL and 0.4 mL (as the volume of extraction and dispersive solvents, respectively), pH 7, 20% ionic strength, and extraction's temperature and time of 20°C and 10 min, respectively. Under the optimum conditions, the figures of merits were determined to be LOD = 10 μg/L, dynamic range = 20–180 μg/L, RSD = 11% (n = 6). The maximum recovery under the optimized condition was determined to be 79.4%. 相似文献
55.
Preparation and coordination complex of the first imine-bridged tetrathiafulvalene-pyridine donor ligand 总被引:1,自引:0,他引:1
Chahma M Hassan N Alberola A Stoeckli-Evans H Pilkington M 《Inorganic chemistry》2007,46(10):3807-3809
The first imine-bridged pyridyltetrathiafulvalene building block (TTF-CH=N-Py, 1) has been synthesized via the Schiff base condensation of formyltetrathiafulvalene and 2-aminopyridine. The preparation, X-ray crystal structure, electrochemical and magnetic characterization of a 1:1 copper complex [CuII(hfac)2(TTF-CH=N-Py)] (2) are reported. The crystal structure reveals that the imine N atom participates in chelation to the paramagnetic center, thus making this ligand an attractive precursor for the assembly of pi-d systems. 相似文献
56.
Nouri Amrah Marjani Ahmad Poursattar Khalafy Jabbar Etivand Nasser 《Research on Chemical Intermediates》2020,46(6):3025-3036
Research on Chemical Intermediates - New 3-(2-aryl-6-nitro-1H-indol-3-yl)quinoline-2,4(1H,3H)-diones were synthesized, and good-to-excellent yields were achieved through one-pot, three-component... 相似文献
57.
Yahia Nasser Mabkhot Nahed Ahmed Kaal Seham Alterary Mohammad S. Mubarak Abdulrhman Alsayari Abdullatif Bin Muhsinah 《Journal of heterocyclic chemistry》2019,56(10):2845-2953
Phenacylbromide derivatives constitute a multilateral group of precursors for the synthesis of numerous heterocycles of organic compounds. Briefly, 5‐(2‐bromo‐acetyl)‐substituted‐thiophene derivative has been used as a synthon for synthesis of new thiophene‐containing compounds through the reaction with nucleophilic nitrogen compounds and thioamides. The suggested structures of the newly synthesized thiophene compounds were confirmed and assured with different spectroscopic tools and with CHN elemental analysis. Additionally, the antimicrobial activity of these thiophene compounds was recorded to investigate their potency against various types of bacteria and fungi. Results showed that these compounds exhibit significant inhibitory activity against the growth of tested bacterial and fungal strains and that some derivatives were more potent than the employed reference drugs. 相似文献
58.
Here, we present a method to synthesize expandable spherical polystyrene beads containing well-dispersed water microdroplets. The beads, 2–3 mm in diameter, were prepared through surfactant-free Pickering emulsion polymerization in water-in-oil-in-water (w/o/w) system using cross-linked starch nanoparticles (CSTN) as emulsifier. The CSTNs were in situ surface-modified by styrene maleic anhydride copolymer as confirmed by infrared spectroscopy and contact angle analysis. The entrapped water microdroplets with the average size of 3–4 μm were shown to be surrounded by a dense layer of the CSTN. The number droplet density as well as water encapsulation efficiency in the polystyrene beads increased with the CSTN concentration. Furthermore, regardless of CSTN content, all samples exhibited high encapsulation stability of over 68 % after 3 months. These characteristics along with good expansion behavior suggest the synthesized beads as expandable polystyrene containing water as a green blowing agent. 相似文献
59.
Nasser Metwally 《International Journal of Theoretical Physics》2008,47(3):623-633
A model of two 2-level atoms interacts with a single quantized electromagnetic field is considered. We study the effect of
the mean photon number and the structure of the initial states of the two atoms on the dynamics of the atomic system from
the separability point of view. It is found that, if we start from a product mixed atomic state, the probability of generating
long living entangled states is increased as the mean photon number increases. Starting from excited atomic system in product
state, one generates a more stable entangled states with high degree of entanglement. Also, the effect of the mean photon
number on atomic system prepared initially in entangled states is investigated. It is found that the entangled state generated
from the initially partial entangled states are more robust than those obtained from a maximum entangled state. The Pancharatnam
phase for the separable and entangled states is studied under the effect of the mean photon number and the structure of the
initial state. We find that for the separable states, the collapses decrease and the amplitude of the revivals is smaller
than that for the entangled state, so there are long-living entangled phases. This property give us a great chances to store
safely information in entangled state. 相似文献
60.
Nasser E. Bastani Thomas E. Gundersen Rune Blomhoff 《Rapid communications in mass spectrometry : RCM》2009,23(18):2885-2890
F2‐isoprostanes are a family of prostaglandin F2‐like compounds that are formed by free‐radical‐catalyzed peroxidation of arachidonic acid. Several F2‐isoprostanes, but in particular 8‐epi PGF2α, are widely used as oxidative stress biomarkers. An analytical method based on liquid chromatography with negative electrospray ionization (ESI) coupled to tandem mass spectrometric detection (LC/MS/MS) was developed for the determination of 8‐epi PGF2α concentrations in human plasma, whole blood, erythrocytes and urine. 8‐epi PGF2α‐d4, a stable isotope derivative of 8‐epi PGF2α, was used as an internal standard (IS). A 50 µL sample was focused on‐column and separated on two 3 µm particle size SUPELCOSIL? ABZ+Plus HPLC columns (15 cm × 4.6 mm and 7.5 cm × 4.6 mm) connected in series. An Applied Biosystems 4000 Q TRAP LC/MS/MS system with ESI was operated in multiple reaction monitoring (MRM) mode with the precursor‐to‐product ion transitions m/z 353.4 → 193.1 (8‐epi PGF2α), 357.4 → 197.1 (8‐epi PGF2α‐d4), used for quantification. The assay was fully validated and found to have adequate accuracy, precision, linearity, sensitivity and selectivity. The mass limit of detection (mLOD) was 1 pg of analyte eluting from the column. The assay has been successfully applied to the analysis of human plasma, whole blood, erythrocytes and urine samples. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献