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81.
The infrared spectra of 4-Cl 2-Me, 4-Cl 3-Me and 6-Cl 3-Me phenols have been recorded. The vibrational spectrum has been analysed assuming that the molecules belong toC s point group and a tentative assignment of the observed frequencies to various modes of vibration has been proposed. The near ultraviolet absorption spectrum of these compounds has also been recorded. Assuming the transition to be electronically allowed the strongest band on the longer wavelength side has been assigned as the (0, 0) band in each case. The spectrum has been analysed in terms of several excited state frequencies which have been correlated with the ground state frequencies observed in the infrared spectrum.  相似文献   
82.
Diethylenetetra-ammonium sulphatocerate has been used as an oxidising agent in hydrochloric acid medium for the volumetric determination of semicarbazide hydrochloride, benzalazine, benzalsemicarbazone, aminoguanidme hydrochloride, chloralhydrazinc, P-methoxybcnzalsemicarbazonc, o-chlorobenzalsemicarbazone and acetonesemicarbazone, using iodine monochloride as a catalyst and preoxidiser Chloroform was used as an indicator. It was coloured violet owing to the liberation of iodine during the titration and became very pale yellow at the end-point owing to the formation of iodine monochloride Each hydrazino group in these compounds was oxidised quantitatively with a four-electron change to nitrogen with diethylenetctra-ammonium sulphatocerate as an Oxidant in hydrochloric acid solution.  相似文献   
83.
Summary Copper has been determined gravimetrically as its bis-salicylaldehyde-ethylenediamine complex of the composition C16H14O2N2 · Cu, dried at 100–120° C. The complex is completely precipitated in theph range of 10.5–13.5, adjusted with ammonia or caustic alkali. It is stable in presence of excess ammonia, 0.1 N alkali, ammonium salts and complexing agents as tartrate, citrate, sodium-thiosulphate, fluoride, thiourea, triethanolamine and EDTA. In presence of tartrate and ammonia the ions of alkali metals, alkaline earths, Ag+, Tl+, Tl3+, Pb2+, Cd2+, Co2+, Mn2+, Pd2+, Al3+, Cr3+, La3+, Ce3+, Au3+, Pt4+, Ti4+, Zr4+, Th4+, UO2 2+ and anions as VO3 , MoO4 2–, WO4 2–, CrO4 2–, PO4 3–, AsO4 3– do not interfere. Ni2+ and Hg2+ are masked by tartrate, EDTA and ammonia; As3+, Sb3+ and Sn2+ are separated using fluoride as the complexing agent; at an alkalinity of 0.1 N caustic alkali in presence of tartrate As3+, Sb3+, Sn2+, Bi3+, Zn2+ and Fe3+ are separated. Fe3+ can also be separated using triethanolamine as the masking agent at aph of about 13.0. Copper can be separated from almost all the ions, thus affording a highly selective method for the determination of copper.
Zusammenfassung Es wird eine gravimetrische Methode zur Bestimmung von Kupfer beschrieben, die auf der Bildung des Bis-salicylaldehyd-äthylendiaminkomplexes beruht. Dieser hat die Zusammensetzung C16H14O2N2 · Cu. Die Fällung wird imph-Bereich 10,5–13,5 (mit Ammoniak oder Alkalilauge eingestellt) vorgenommen und der Niederschlag bei 100°–120° C getrocknet. Der Komplex ist beständig in Gegenwart von überschüssigem Ammoniak, 0,1 n Alkali, Ammoniumsalzen sowie Tartrat, Citrat, Natriumthiosulfat, Fluorid, Thioharnstoff, Triäthanolamin und ÄDTA. In Gegenwart von Tartrat und Ammoniak stören nicht: Alkalien, Erdalkalien, Ag+, Tl+, Tl3+, Pb2+, Cd2+, Co2+, Mn2+, Pd2+, Al3+, Cr3+, La3+, Ce3+, Au3+, Pt4+, Ti4+, Zr4+, Th4+, UO2 2+ sowie VO3 , MoO4 2–, WO4 2–, CrO4 2–, PO4 3– und AsO4 3+. Ni2+ und Hg2+ können mit Tartrat, ÄDTA und Ammoniak maskiert werden, As3+, Sb3+ und Sn2+ mit Fluorid. In 0,1 n ätzalkalischer Lösung in Gegenwart von Tartrat können As3+, Sb3+, Sn2+, Bi3+, Zn2+ und Fe3+ abgetrennt werden. Fe3+ kann ebenfalls mit Triäthanolamin beiph 13,0 maskiert werden. Das beschriebene Verfahren erlaubt somit eine Abtrennung des Kupfers von fast allen anderen Ionen.


Part I: Singh, B. R., and S. Kumar: Z. analyt. Chem. 185, 211 (1962).  相似文献   
84.
Khosla MM  Singh SR  Rao SP 《Talanta》1974,21(6):411-415
A simple and rapid method is proposed for the separation of tervalent gallium, indium and thallium by solvent extraction with N-benzylaniline in chloroform from different concentrations of hydrochloric acid. Thallium and gallium are extracted from 1M and 7.0-7.5M hydrochloric acid respectively. Indium is finally extracted from hydriodic acid. These metals in the final extracts are determined complexometrically. Interference from some cations can easily be eliminated by reduction with sulphite, followed by selective oxidation of thallium(I) to thallium(III) with saturated bromine water, and from others by the use of thioglycollic acid as a masking agent in the extraction of gallium and indium. Most common anions cause no interference. Log-log plots of distribution coefficients vs. concentration of amine for gallium, indium and thallium indicate a 2:1 limiting mole ratio of amine to these metals.  相似文献   
85.
Summary Organometallic compounds of general formula (SCN)2M(NCSeHgR)2 (M=CoII, NiII, R=n-C5H11,i-C5H11) have been prepared. They behave as Lewis acids, forming complexes with pyridine and 2,2-bipyridyl, characterized by elemental analysis, molecular weight, molar conductance, i.r. spectral (4000–200 cm–1), electronic spectral and magnetic susceptibility measurements. The Lewis acids are monomeric with bridging thiocyanate, or selenocyanate between M2+ and Hg2+. Cobalt and nickel acquire tetrahedral and octahedral configurations respectively through axial bridging, whereas mercury retains its linearity. Pyridine links to the metal in the Lewis acid and forms L2(SCN)2M(NCSeHgR)2 complexes. Bipyridyl ruptures the NCX bridge and forms cationic-anionic [M(bipy)3][(NCS)(NCSe)HgR]2 complexes.  相似文献   
86.
Theoretical expressions for the covalence reduction factors of orbital angular momentum and spin-orbit coupling in pseudo-tetrahedral four-coordinated paramagnetic complexes withD 2d symmetry, denoted ask's andR's respectively, have been derived. p ]The mixing coefficients in the antibonding MO's for the CuCl 4 2- ion in three complexes are estimated using suitable approximations. It is shown thatk's must be less thanR's in Tinkham's approximation. Certain misconceptions existing in the literature regarding the value of the integral 〈p u |???u|s〉 have been clarified.  相似文献   
87.
In flash photolysis of an oxygenated aqueous potassium persulphate solution at pH 12.5 the decay of the ozonide radical has been found to follow 32 order kinetics which has been explained by reactions O?3 + O? ? 2 O?2 and O?3 + HO2 → 2 O2 + OH?  相似文献   
88.
We describe the fabrication of metallic Cu spiral/helical nanostructures prepared via selective electroless metallization of a phospholipid microtubule template. The metallization template is created through selective, sequential adsorption of the oppositely charged polyelectrolytes, sodium poly(styrenesulfonate) (PSS) and poly(ethyleneimine) (PEI), onto nanoscale seams naturally occurring on the microtubule surface. A negatively charged Pd(II) nanoparticle catalyst is bound to the terminal cationic PEI layer of the multilayer film and initiates selective template metallization to form the helical Cu nanostructures. Details of the process are presented, and a mechanism and factors affecting the control of the feature critical dimensions are discussed.  相似文献   
89.
Natural products are a major source of biologically active compounds that make promising lead molecules for developing efficacious drug-like molecules. Natural withanolides are found in many flora and fauna, including plants, algae, and corals, that traditionally have shown multiple health benefits and are known for their anti-cancer, anti-inflammatory, anti-bacterial, anti-leishmaniasis, and many other medicinal properties. Structures of these withanolides possess a few reactive sites that can be exploited to design and synthesize more potent and safe analogs. In this review, we discuss the literature evidence related to the medicinal implications, particularly anticancer properties of natural withanolides and their synthetic analogs, and provide perspectives on the translational potential of these promising compounds.  相似文献   
90.
Rubidium uranium trisulphate [Rb2U(SO4)3] was prepared as a high purity compound of uranium in different lots of 250 g each. The compound was characterised and evaluated by chemical, atomic spectrosopic, infrared, X-ray diffraction and thermogravimetric methods for its use as a chemical assay standard for uranium. The compound is stoichiometric, pure, homogeneous and stable in atmospheric conditions. The solubility studies showed that Rb2U(SO4)3 is easily soluble in mineral acids. An experiment based on Randomised Block Design was carried out to assign a value to the uranium content in Rb2U(SO4)3 from the statistically analysed chemical data. The assigned value of [34.167±0.042]% to the uranium content is in close agreement with the theoretical value of 34.152%. Based on these studies, Rb2U(SO4)3 is recommended as a chemical assay standard for uranium.  相似文献   
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