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排序方式: 共有473条查询结果,搜索用时 31 毫秒
31.
Prof. Makoto Tadokoro Masaki Itoh Ryota Nishimura Kensuke Sekiguchi Dr. Norihisa Hoshino Dr. Hajime Kamebuchi Prof. Jun Miyazaki Dr. Fumiya Kobayashi Prof. Motohiro Mizuno Prof. Tomoyuki Akutagawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(47):e202201397
A new H-bonded crystal [RuIII(Him)3(Im)3] with three imidazole (Him) and three imidazolate (Im−) groups was prepared to obtain a higher-temperature proton conductor than a Nafion membrane with water driving. The crystal is constructed by complementary N−H⋅⋅⋅N H-bonds between the RuIII complexes and has a rare Icy-c* cubic network topology with a twofold interpenetration without crystal anisotropy. The crystals show a proton conductivity of 3.08×10−5 S cm−1 at 450 K and a faster conductivity than those formed by only HIms. The high proton conductivity is attributed to not only molecular rotations and hopping motions of HIm frameworks that are activated at ∼113 K, but also isotropic whole-molecule rotation of [RuIII(Him)3(Im)3] at temperatures greater than 420 K. The latter rotation was confirmed by solid-state 2H NMR spectroscopy; probable proton conduction routes were predicted and theoretically considered. 相似文献
32.
Susumu Tajima Yukiyoshi Nagai Osamu Sekiguchi Masao Fujishige Nozomu Uchida 《Journal of the American Society for Mass Spectrometry》1995,6(3):202-206
The spontaneous unimolecular dissociation reaction of methyl lactate (1) ionized by electron impact was investigated by a combination of mass-analyzed ion kinetic energy spectrometry and deuterium labeling. The metastable ions 1+· decompose in a variety of ways: four fragment peaks are observed at m/z 89, 76, 61, and 45, which correspond to the losses of ?H3, CO, CH3?O, and ?OOCH3, respectively. Double hydrogen atom transfer occurs in the third reaction. The source-generated m/z 61 ions decompose into oxygen-protonated methanols at m/z 33 ([CH3OH 2 + ]) by the loss of CO with double hydrogen atom migration. Both hydroxyl and methyne hydrogen atoms in 1 +· are present in the resultant protonated methanols. 相似文献
33.
34.
Sekiguchi A Ishida Y Fukaya N Ichinohe M Takagi N Nagase S 《Journal of the American Chemical Society》2002,124(7):1158-1159
Dark red crystals of the halogen-substituted cyclotrigermenes [(tBu3Si)3Ge3X; X = Cl, Br, I] were obtained in good yields by the reaction of [(tBu3Si)3Ge3]+.TTFPB- (TTFPB- = tetrakis(2,3,5,6-tetrafluorophenyl)borate) with potassium halides (KCl, KBr, or KI) in diethyl ether. The crystal structures of the halogen-substituted cyclotrigermenes reveal a cis-bent Ge=Ge double bond, caused by the introduction of the electronegative halogen atom on the sp3 germanium atom of cyclotrigermene. In solution, an intramolecular halogen migration over the three-membered ring skeleton was observed. Facial stereoselectivity in the Diels-Alder reaction of new cyclotrigermenes with 2,3-dimethyl-1,3-butadiene is also reported. 相似文献
35.
Sekiguchi K Sakai H Witała H Glöckle W Golak J Hatanaka K Hatano M Itoh K Kamada H Kuboki H Maeda Y Nogga A Okamura H Saito T Sakamoto N Sakemi Y Sasano M Shimizu Y Suda K Tamii A Uesaka T Wakasa T Yako K 《Physical review letters》2005,95(16):162301
Three precise measurements for elastic pd scattering at 135 MeV/A have been performed with the three different experimental setups. The cross sections are described well by the theoretical predictions based on modern nucleon-nucleon forces combined with three-nucleon forces. Relativistic Faddeev calculations show that relativistic effects are restricted to backward angles. This result supports the two measurements recently reported by RIKEN and contradicts the KVI data. 相似文献
36.
Sekiguchi A Inoue S Ichinohe M Arai Y 《Journal of the American Chemical Society》2004,126(31):9626-9629
The highly twisted tetrakis(di-tert-butylmethylsilyl)disilene 4 was prepared and reacted with (t)BuLi in THF, producing disilene anion radical 5 upon one-electron reduction. The anion radical 5 was isolated in the form of its lithium salt as extremely air- and moisture-sensitive red crystals. The molecular structure of 5 was established by X-ray crystallography, which showed a nearly orthogonal structure (twisting angle of 88 degrees ) along the central Si-Si bond, with a length of 2.341(5) A, which is 3.6% elongated relative to that of 4. The interesting feature of 5 is that one of the central Si atoms has radical character, whereas the other Si atom has silyl anion character. An electron spin resonance (ESR) study of the hyperfine coupling constants of the (29)Si nuclei indicates that rapid spin exchange occurs between these central Si atoms on the ESR time scale. 相似文献
37.
H. Mardanpour H. R. Amir-Ahmadi A. Deltuva K. Itoh N. Kalantar-Nayestanaki T. Kawabata H. Kuboki Y. Maeda J. G. Messchendorp S. Sakaguchi H. Sakai N. Sakamoto Y. Sasamoto M. Sasano K. Sekiguchi K. Suda Y. Takahashi T. Uesaka H. Witała K. Yako 《The European Physical Journal A - Hadrons and Nuclei》2007,31(3):383-391
High-precision vector and tensor analyzing powers of elastic deuteron-proton ( d + p) scattering have been measured at intermediate energies to investigate effects of three-nucleon forces. Angular distributions
in the range of 70°-120° in the center-of mass frame for incident-deuteron energies E
d
lab = 130 and 180 MeV were obtained using the RIKEN facility. The beam polarization was unambiguously determined by measuring
the ^12C (d, α)^10B(2+) reaction at 0°. Results of the measurements are compared with state-of-the-art three-nucleon calculations. The present modeling of nucleon-nucleon
forces and its extension to the three-nucleon system is not sufficient to describe the high-precision data consistently and
requires, therefore, further investigation. 相似文献
38.
We have developed the mechanically controllable break junction setup with an electrochemical cell (EC-MCBJ) to measure the electric conductance of metal nanowires under electrochemical potential control. The electric conductance of Au nanowires was investigated in 0.1 M Na2SO4 solution using EC-MCBJ. The conductance of the Au nanowires was quantized in units of G0 (=2e2/h), showing clear features in the conductance histogram. The atomic contact with a specific conductance value was kept for >5 s, indicating the relatively high stability of the present EC-MCBJ system. 相似文献
39.
40.
T. Suzuki T. Fukasawa H. Sekiguchi T. Kasuya 《Applied physics. B, Lasers and optics》1986,39(4):247-250
A new method for the detection of the optogalvanic (OG) effect in a flame has been developed. In the experimental scheme, the reflected microwave power is measured for the detection of the OG effect inside a microwave resonant cavity. In a preliminary experiment, the OG signal of sodium atom aspirated into a propane/O2 flame was observed at a concentration below 10 ng/ml. 相似文献