降噪阵列参数对次声降噪系统性能的影响分析

次声降噪系统对提高次声监测能力具有重要作用,为分析次声降噪系统阵列结构参数变化对其降噪性能的影响规律,构建玫瑰型(rosette)管道滤波器降噪系统声电等效模型,进而利用风噪声模型和仿真数据对该模型的单进气口传递函数和系统降噪性能进行了定量分析,总结了不同阵列结构参数对该系统降噪性能的影响规律,最后对国际监测系统(International Monitoring System,IMS)玫瑰型管道滤波器的降噪性能进行了评估。仿真实验及分析结果表明:(1)进气口数量约取96,阵列尺寸约18 m,一、二级管内径取10~20 mm,一、二级合成腔体积不得超过1 L,系统能获得较好的降噪性能;(2)IMS玫瑰型管道滤波器符合最佳阵列参数设置要求;(3)满足最佳阵列参数设置的玫瑰型管道滤波器可大幅度地提高信噪比。该分析结果可为已有次声降噪系统提供性能评估,可对新的次声降噪系统设计提供参考。     

A MALDI-MS sensing chip prepared by non-covalent assembly for quantitation of acid phosphatase

A novel sensing chip was designed for MALDI-MS quantitation of acid phosphatase(ACP).The ACP sensing chip was constructed through non-covalent interaction of streptavidin and biotin for the assembly of biotinylated peptide substrate on biotinylated polyethylene-glycol(PEG)modified indium-tin oxide(ITO)slide.In the presence of ACP,the peptide substrate was dephosphorylated under acidic condition to generate a new mass signal.The quantitative assay of ACP was achieved with the mass signal ratio of product to the sum of product and left peptide substrate.Under optimal detection conditions,the ratio was linearly correlated with the concentration of ACP in the range of 0.05–12 g/L with a detection limit(LOD)of 0.04 g/L.The designed ACP sensing chip has been used to analyze ACP in complex clinical samples,which exhibited high selectivity,good repeatability,and admirably anti-interference ability.This work further demonstrates the concept of MS sensing and the application of MALDI-MS in quantitative analysis,and provides a convenient method for the quantitation of proteases in clinical diagnosis.     

基于VaR的房地产投资组合模型设计与应用

本文以风险和收益的动态刻画为核心,在房地产投资组合中引入基于VaR模型的风险评价,通过资产收益和预提费用在持有期内的现值构造效用函数,建立基于VaR的投资组合优化模型,实现房地产投资的最优组合。对于上海房地产市场两种不同资产进行组合的实证分析表明该模型具有一定的实用性和有效性。     

ICAS-2006——分析科学国际大会(Ⅰ)

这次大会是2006年分析科学界最高级的国际大会,由俄罗斯科学院及其所属地质化学与分析化学、普通化学与无机化学两研究所以及Lom-onosov莫斯科国立大学联合主办;并获得国际纯粹化学与应用化学联合会、欧洲化学与分子科学协会分析化学部、分析化学中数据追溯性国际合作组织等学术团体的合作.     

海藻酸钙-壳聚糖微胶囊组成对BSA通透性能影响的研究

对海藻酸钙-壳聚糖微胶囊的牛血清白蛋白(BSA)双向通透性能进行了定量和定性的初步研究, 并初步考察了微胶囊的组成成分及海藻酸钠、壳聚糖的溶液浓度对BSA通透性能的影响. 结果表明海藻酸钙-壳聚糖微胶囊在pH 1.5～2.0时通透性减弱, pH 6.8时通透性增强, 且海藻酸钙微胶囊通透性大于海藻酸钙-壳聚糖微胶囊; 海藻酸钙-壳聚糖微胶囊中壳聚糖浓度越小, 通透性越好; 海藻酸钠浓度的影响不显著.     

Surface tension of supercooled graphene oxide nanofluids measured with acoustic levitation

Journal of Thermal Analysis and Calorimetry - The surface tensions of graphene oxide nanofluids of five mass concentrations were measured by the oscillation droplet method in an acoustic levitator....     

多棒极型触发真空开关极性效应

基于有限元分析软件ANSOFT对触发真空开关触发极附近的静电场分布进行了仿真,并对其工作在不同的极性配置方式下开展了一系列实验。主要研究触发真空开关极性配置方式与导通时延的大小及其分散性的关系,同时分析了静电场对初始等离子体扩散的影响,从而为触发真空开关的结构优化设计提供理论依据。仿真结果表明：当触发极工作在正极性配置下,可以增强触发极附近阴极表面的电场强度,从而有利于阴极斑点的形成,减小导通时延及其分散性,提高其可靠性。实验验证了触发真空开关在正极性配置下的工作可靠性高、时延小,与仿真分析结果一致。     

Generation of Glycosyl Radicals from Glycosyl Sulfoxides and Its Use in the Synthesis of C‐linked Glycoconjugates

We here report glycosyl sulfoxides appended with an aryl iodide moiety as readily available, air and moisture stable precursors to glycosyl radicals. These glycosyl sulfoxides could be converted to glycosyl radicals by way of a rapid and efficient intramolecular radical substitution event. The use of this type of precursors enabled the synthesis of various complex C‐linked glycoconjugates under mild conditions. This reaction could be performed in aqueous media and is amenable to the synthesis of glycopeptidomimetics and carbohydrate‐DNA conjugates.     

Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Trichloroacetonitrile (CI3CCN) and Sodium Hydride

In the process of preparing α-diazo carbonyl compound 2 by imidation of 1, we unexpectedly observed a direct conversion of the hydroxyl group into trichloroacetylamino group. In this presentation, we report this unprecedented reaction, as well as the Rh2(OAc)4-catalyzed reaction of the resulting β-(trichloroacetyl)amino β-diazo carbonylcompounds 3. [ 1]