全文获取类型
收费全文 | 568篇 |
免费 | 17篇 |
国内免费 | 5篇 |
专业分类
化学 | 357篇 |
晶体学 | 7篇 |
力学 | 20篇 |
数学 | 89篇 |
物理学 | 117篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 12篇 |
2021年 | 14篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 20篇 |
2015年 | 13篇 |
2014年 | 11篇 |
2013年 | 37篇 |
2012年 | 25篇 |
2011年 | 45篇 |
2010年 | 28篇 |
2009年 | 21篇 |
2008年 | 37篇 |
2007年 | 38篇 |
2006年 | 39篇 |
2005年 | 30篇 |
2004年 | 22篇 |
2003年 | 21篇 |
2002年 | 21篇 |
2001年 | 18篇 |
2000年 | 9篇 |
1999年 | 8篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1976年 | 4篇 |
1975年 | 3篇 |
排序方式: 共有590条查询结果,搜索用时 15 毫秒
21.
22.
Developing ideal IR probes is essential to understand the structure and dynamics of biomolecules with time-resolved IR spectroscopies and imaging techniques. Especially, nitrile (CN) group has recently been proposed to serve as IR probes of the local environment of proteins. Herein, we investigated the effect of a substituent on the vibrational properties of the benzonitrile. The electron-donating and withdrawing character of p-substituent on benzonitrile are expected to modulate the vibrational frequency, molar extinction coefficient, and vibrational lifetime of CN probe. FT-IR revealed the positive correlation between electron-donating character and the molar extinction coefficient of CN stretch mode. Infrared pump-probe (IR-PP) measurements showed that the vibrational lifetime of CN stretch mode exhibits a relatively weak correlation with the electron-donating strength. Among the investigated samples, 4-dimethylamino benzonitrile with the strongest electron-donating strength shows enhanced absorption and extended vibrational lifetime. Utilizing substituent effects will be a practical strategy to improve the performance of the IR probe. 相似文献
23.
Dongseok Kim Dr. Rosemary L. Calabro Abdullah A. Masud Nadeesha L. Kothalawala Dr. Minsu Gu Dr. Seung-Yeon Kwak Won-Joon Son Dr. Kyu Young Hwang Dr. Hyeonho Choi Prof. Christopher I. Richards Prof. Doo Young Kim Prof. Byeong-Su Kim 《化学:亚洲杂志》2021,16(24):4155-4164
Fluorescent carbon nanodots (CDs) have been highlighted as promising semiconducting materials due to their outstanding chemical and optical properties. However, the intrinsic heterogeneity of CDs has impeded a clear understanding of the mechanisms behind their photophysical properties. In this study, as-prepared CDs are fractionated via chromatography to reduce their structural and chemical heterogeneity and analyzed through ensemble and single-particle spectroscopies. Many single particles reveal fluorescence intensity fluctuations between two or more discrete levels with bi-exponential decays. While the intrinsic τ1 components are uniform among single particles, the τ2 components from molecule-like emissions spans a wider range of lifetimes, reflecting the inhomogeneity of the surface states. Furthermore, it is concluded that the relative population and chemical states of surface functional groups in CDs have a significant impact on emissive states, brightness, blinking, stability, and lifetime distribution of photoluminescence. 相似文献
24.
25.
Sang Sub Kim Sun-Woo Choi Han Gil Na Dong Sub Kwak Yong Jung Kwon Hyoun Woo Kim 《Current Applied Physics》2013,13(3):526-532
ZnO–SnO2 branch–stem nanostructures were realized on a basis of a two-step process. In step 1, SnO2-stem nanowires were synthesized. In step 2, ZnO-branch nanowires were successfully grown on the SnO2-stem nanowires through a simple evaporation technique. We have pre-deposited thin Au layers on the surface of SnO2 nanowire stems and subsequently evaporated Zn powders on the nanowires. The ZnO branches, which sprouted from the SnO2 stems, had diameters in a range of 30–35 nm. As-synthesized branches were of single crystalline hexagonal ZnO structures. Since the branch tips were comprised of Au-containing nanoparticles, the Au-catalyzed vapor–liquid–solid growth mechanism was more likely to control the growth process of the ZnO branches. To test a potential use of ZnO–SnO2 branch–stem nanostructures in chemical gas sensors, their sensing performances with respect to NO2 gas were investigated, showing the promising potential in chemical gas sensors. 相似文献
26.
Chul‐Soon Lee Zhengfei Dai Seong‐Yong Jeong Chang‐Hoon Kwak Bo‐Young Kim Do Hong Kim Prof. Ho Won Jang Joon‐Shik Park Prof. Jong‐Heun Lee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(21):7102-7107
Monolayers of periodic porous Co3O4 inverse opal (IO) thin films for gas‐sensor applications were prepared by transferring cobalt‐solution‐dipped polystyrene (PS) monolayers onto sensor substrates and subsequent removal of the PS template by heat treatment. Monolayer Co3O4 IO thin films having periodic pores (d≈500 nm) showed a high response of 112.9 to 5 ppm C2H5OH at 200 °C with low cross‐responses to other interfering gases. Moreover, the selective detection of xylene and methyl benzenes (xylene+toluene) could be achieved simply by tuning the sensor temperature to 250 and 275 °C, respectively, so that multiple gases can be detected with a single chemiresistor. Unprecedentedly high ethanol response and temperature‐modulated control of selectivity with respect to ethanol, xylene, and methyl benzenes were attributed to the highly chemiresistive IO nanoarchitecture and to the tuned catalytic promotion of different gas‐sensing reactions, respectively. These well‐ordered porous nanostructures could have potential in the field of high‐performance gas sensors based on p‐type oxide semiconductors. 相似文献
27.
Seokgeun Jin Byung Jun Jung Chung Kun Song Jeonghun Kwak 《Current Applied Physics》2014,14(12):1809-1812
We introduce a room temperature and solution-processible vanadium oxide (VOx) buffer layer beneath Au source/drain electrodes for bottom-contact (BC) organic field-effect transistors (OFETs). The OFETs with the VOx buffer layer exhibited higher mobility and lower threshold voltages than the devices without a buffer layer. The hole mobility with VOx was over 0.11 cm2/V with the BC geometry with a short channel length (10 μm), even without a surface treatment on SiO2. The channel width normalized contact resistance was decreased from 98 kΩ cm to 23 kΩ cm with VOx. The improved mobility and the reduced contact resistance were attributed to the enhanced continuity of pentacene grains, and the increased work function and adhesion of the Au electrodes using the VOx buffer layer. 相似文献
28.
TREN (Tris(2-aminoethyl)amine): an effective scaffold for the assembly of triple helical collagen mimetic structures 总被引:1,自引:0,他引:1
Kwak J De Capua A Locardi E Goodman M 《Journal of the American Chemical Society》2002,124(47):14085-14091
A new scaffold, TREN-(suc-OH)(3) where TREN is tris(2-aminoethyl)amine and suc is the succinic acid spacers, was incorporated to assemble triple helices composed of Gly-Nleu-Pro sequences (Nleu denotes N-isobutylglycine). Extensive biophysical studies which include denaturation studies, CD and NMR spectroscopy, and molecular modeling demonstrated that TREN-[suc-(Gly-Nleu-Pro)(n)-NH(2)](3) (n = 5 and 6) form stable triple helical structures in solution. A comparative analysis of TREN-assembled and KTA-assembled collagen mimetics (KTA denotes Kemp triacid, 1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid) indicates that the flexibility of the TREN scaffold is superior to the KTA scaffold in inducing triple helicity. This effect most likely arises from the flexibility of the TREN scaffold which allows the three peptide chains to adjust their register for a tighter triple helical packing. 相似文献
29.
Link JM Reyes M Yager PM Anjos JC Bediaga I Göbel C Magnin J Massafferi A de Miranda JM Pepe IM dos Reis AC Carrillo S Casimiro E Cuautle E Sánchez-Hernández A Uribe C Vazquez F Agostino L Cinquini L Cumalat JP O'Reilly B Ramirez JE Segoni I Butler JN Cheung HW Gaines I Garbincius PH Garren LA Gottschalk E Kasper PH Kreymer AE Kutschke R Bianco S Fabbri FL Zallo A Cawlfield C Kim DY Rahimi A Wiss J Gardner R Kryemadhi A Chung YS Kang JS Ko BR Kwak JW Lee KB Park H Alimonti G Boschini M 《Physical review letters》2002,88(16):161801
A high statistics measurement of the Lambda(+)(c) lifetime from the Fermilab fixed-target FOCUS photoproduction experiment is presented. We describe the analysis technique with particular attention to the determination of the systematic uncertainty. The measured value of 204.6 +/- 3.4 (stat) +/- 2.5 (syst) fs from 8034 +/- 122 Lambda(+)(c)-->pK(-)pi(+) decays represents a significant improvement over the present world average. 相似文献
30.
We introduce a novel simulation method, model hopping, that enhances sampling of low-energy configurations in complex systems. The approach is illustrated for a protein-folding problem. Thermodynamic quantities of proteins with up to 46 residues are evaluated from all-atom simulations with this method. 相似文献