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Hafiz T.Ali MRamzan M Imran Arshad Nicola A.Morley M.Hassan Abbas Mohammad Yusuf Atta Ur Rehman Khalid Mahmood Adnan Ali Nasir Amin MAjaz-un-Nabi 《中国物理 B》2022,31(2):27502-027502
We investigate the impact of Ni insertion on the structural,optical,and magnetic properties of Ba0.8La0.2Fe12-xNixO19hexaferrites(Ni substituted La-BaM hexaferrites).Samples were prepared using the conventional co-precipitation method and sintered at 1000℃for 4 hours to assist the crystallization process.An analysis of the structure of the samples was carried out using an x-ray diffraction(XRD)spectrometer.The M-type hexagonal structure of all the samples was confirmed using XRD spectra.The lattice parameters a and c were found to be in the ranges of 5.8925±0.001 nm–5.8952±0.001 nm and 23.2123±0.001 nm–23.2219±0.001 nm,respectively.The M-type hexagonal nature of the prepared samples was also indicated by the presence of corresponding FT-IR bands and Raman modes in the FT-IR and Raman spectra,respectively.EDX results confirmed the successful synthesis of the samples according to the required stoichiometric ratio.A UV-vis spectrometer was used to record the absorption spectra of the prepared samples in the wavelength range of 200 nm–1100 nm.The optical energy bandgap of the samples was found to be in the range of 1.21 eV–3.39 eV.The M–H loops of the samples were measured at room temperature at an applied magnetic field range of 0 kOe–60 kOe.A high saturation magnetization of 99.92 emu/g was recorded in the sample with x=0 at a microwave operating frequency of 22.2 GHz.This high value of saturation magnetization is due to the substitution of La3+ions at the spin-up(12k,2a,and 2b)sites.The Ni substitution is proven to be a potential candidate for the tuning of the optical and magnetic parameters of M-type hexaferrites.Therefore,we suggest that the prepared samples are suitable for use in magneto-optic applications. 相似文献
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The present work is concerned with the synthesis and coordination compounds of 2-amino-N(2-aminobezoyl) benzohydrazide (ABH). The ligand was synthesized by the reaction of methylanthranilate and hydrazine in 2:1
molar ratio. It can be viewed as a modified form of hydrazide. The ligand was characterized by 1H-NMR, 13C-NMR, mass spectrometry, elemental analysis, and infrared studies. The ligand has got -NH2 moeity, the site for chelation. The complexes of Co(II), Ni(II), and Cu(II) chlorides and bromides were prepared. These complexes
were characterized by elemental analysis, infrared, conductance, and magnetic susceptibility studies. Infrared spectra studies
confirmed the formation of complexes, while elemental studies suggested the complexation of [M(ABH)X2] (where X = Cl− or Br−) composition. 相似文献
25.
Inês R. Ramos Fiona M. Lyng Ihtesham Ur Rehman Basil Sharrack M. Nicola Woodroofe 《应用光谱学评论》2017,52(10):868-882
Spectroscopy techniques are valuable tools in biomedical research and have been used extensively in the study of disease. However, neurological conditions such as multiple sclerosis (MS) have received little attention and the available spectroscopy studies are limited, both in overall numbers of patients studied and the disease samples considered. MS is a complex immune-mediated disease, with variable clinical courses and limited therapeutic options. This review aims to summarize current literature in the area, demonstrating how spectroscopy techniques can provide valuable information to inform and advance research into the most common neurological condition affecting young adults. 相似文献
26.
Nuzhat Jabeen Ejaz ur Rehman Shafaat Ahmed 《Journal of Radioanalytical and Nuclear Chemistry》2003,258(2):427-430
The isotopic composition of lithium in seawater has been determined by thermal ionization mass spectrometry (TIMS) based on the use of lithium hydroxide as the ion source. Isotopic measurements in a reference material supplied by IAEA (L-SVEC Li2CO3) were made to check the reproducibility of the method and 6Li indicates mobilization of light isotope of lithium form the sediment. 相似文献
27.
We consider solution methods for large systems of linear equations that arise from the finite element discretization of the incompressible Navier–Stokes equations. These systems are of the so‐called saddle point type, which means that there is a large block of zeros on the main diagonal. To solve these types of systems efficiently, several block preconditioners have been published. These types of preconditioners require adaptation of standard finite element packages. The alternative is to apply a standard ILU preconditioner in combination with a suitable renumbering of unknowns. We introduce a reordering technique for the degrees of freedom that makes the application of ILU relatively fast. We compare the performance of this technique with some block preconditioners. The performance appears to depend on grid size, Reynolds number and quality of the mesh. For medium‐sized problems, which are of practical interest, we show that the reordering technique is competitive with the block preconditioners. Its simple implementation makes it worthwhile to implement it in the standard finite element method software. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
28.
In this work, we investigate existence and uniqueness of solutions for a class of nonlinear multi-point boundary value problems for fractional differential equations. Our analysis relies on the Schauder fixed point theorem and the Banach contraction principle. 相似文献
29.
Nadeem ur Rehman Öznur Gölbaşı Emine Koç 《Rendiconti del Circolo Matematico di Palermo》1938,62(2):245-251
Let \((R,*)\) be a \(2\)-torsion free \(*\)-prime ring with involution \(*\), \(L\ne \{0\}\) be a \(*\)-Lie ideal of \(R\). An additive mapping \(d:R\rightarrow R\) is called an \((\alpha ,\beta )\)-derivation of \(R\) such that \(d(xy)=d(x)\alpha (y)+\beta (x)d(y)\). In the present paper, we shall show that when \(L\) satisfies any of several identities involving \(d\), then \(L\) is central. 相似文献
30.
Abdul Rehman Khan Johnson MathewKhawla Al-Shayji Majed Sari 《European Polymer Journal》2002,38(5):1013-1023
The synthesis of copolyesteramides using para-acetamido benzoic acid (PABA) and polyethylene terephthalate (PET) by melt polymerization has been studied in detail. The performance of three transesterification catalysts are assessed for three different initial compositions, PABA 60 mol%/PET 40%, PABA 50 mol%/PET 50% and PABA 40 mol%/PET 60%. The polycondensations are found to obey second order kinetics, irrespective of whether the reaction was catalysed or not. The mechanism of initial stage polymerization kinetics of the copolymers has been fully explained.It is suggested that acetic acid is evolved only by the homopolymerization of PABA and that the insertion of a monomer of homopolymer of PABA into PET does not yield any acetic acid. A set of differential equations containing three different rate constants, k1 for homopolymerization of PABA, k2 for PET reaction with dimer of PABA and k3 for PABA reaction with copolymer of PABA and PET has been developed and numerically solved, to study the initial stage kinetics. The computed values of acetic acid are compared with the experimentally collected amount and the three rate constants are optimized using a differential algebraic optimization technique. The present model represents the data with an acceptable accuracy with an average % error of less than 5% between experimental and computed values for the entire experimental range. The correlation coefficient values range between 0.988 and 0.999.Differential scanning analysis of the copolyestermides indicates that 40 mol% PABA and 60% PET had the highest enthalpy values of the order of 18 kJ/mol. It is found that within the copolyesteramide series the degree of crystallinity increased with the increase of PET contents in the feed mixture to the batch reactor. 相似文献