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11.
Coadsorption of H2 and CO on Pd has been studied using TDS and ESD techniques. It has been observed that the presence of 10% CO in the H2 dosing gas during exposure gives rise to a drastic change in the TDS spectra of H2 compared to the case when only H2 is separately adsorbed. Furthermore, significant modifications occur in the ESD energy distribution of CO+ and H+ as a result of coadsorption of H2 and CO. These observations are taken as evidence of adsorbate interaction possibly resulting in formation of an HCO surface complex.  相似文献   
12.
New second-order accurate monotone difference schemes on nonuniform spatial grids for two-dimensional stationary and nonstationary convection–diffusion equations are proposed. The monotonicity and stability of the solutions of the computational methods with respect to the boundary conditions, the initial condition, and the right-hand side are proved. Two-sided and corresponding a priori estimates are obtained in the grid norm of C. The convergence of the proposed algorithms to the solution of the original differential problem with the second order is proved.  相似文献   
13.
Numerical Algorithms - In this paper, basing on the subgradient extragradient method and inertial method with line-search process, we introduce two new algorithms for finding a common element of...  相似文献   
14.
We study a quasilinear elliptic equation in the unit ball of m . Using this result we get the existence of graphs with prescribed curvature on hyperbolic spaces m in m ×.  相似文献   
15.
    
Defluorinative manipulation of polyfluorinated molecules has shown great promise due to its granting of synthetic versatility to inert C−F bonds. The development of chemo-, stereo- and regioselective strategies to realize highly efficient formation of either the linear/branched or E/Z products from gem-difluorocyclopropanes (gem-F2CPs) is a challenging task. Herein, we have realized palladium/NHC-catalyzed fluoroallylation/annulation of hydrazones with gem-F2CPs that incorporate the hydrazone N2 moiety into the products. The thermodynamically unstable fluorinated E-allylation products with aryl ketone hydrazones were obtained for the first time, while the di-alkyl ketone hydrazones yielded the monofluorinated products with branched selectivity under similar reaction conditions. With aldehyde hydrazones, two kinds of pyrazoles were obtained via a defluorinative allylation/annulation cascade, in which different carbon atoms of gem-F2CPs could be incorporated into the pyrazole rings regiospecifically. DFT calculations revealed that the divergent selectivity was kinetically controlled and the final C−C bond formation proceeded through a 7-membered TS.  相似文献   
16.
    
Platinum/reduced graphene oxide (Pt/rGO) composite materials with different mass ratios were fabricated by thermal decomposition method from H2PtCl6 and reduce graphene oxide (rGO) as precursors. Pt/rGO composites were used to fabricate Pt/rGO thin film cathodes by using the screen printing technology. The electrochemical properties of the fabricated cathodes were measured using the cyclic voltammetry method. Dye‐sensitized solar cells (DSSCs) were assembled from fabricated cathodes and were measured the performances by current density‐voltage (J‐V) curves and electrochemical impedance spectroscopy (EIS). The results showed the appropriate replacement amount rGO with Pt was 40 %, with the efficiency of 4.73 %, which was higher than that of commercial Pt cathode. The characterizations of the appropriate Pt/rGO composite were investigated by Fourier‐transform infrared spectroscopy (FTIR) and Raman spectroscopy. X‐ray diffraction (XRD) patterns indicated that the interlayer distance between the rGO was 0.35 nm while the transmission electron microscopy (TEM) image showed the Pt nanoparticles with size of 10‐20 nm were evenly distributed on the rGO sheets. These results indicated that Pt/rGO could be appropriated material to replace Pt in DSSCs to reduce the produce cost and enhance the efficiency.  相似文献   
17.
    
Eight compounds, 2,4‐dichloro phenyl 2,4‐dichloro benzoate ( 1 ), cyclo‐(Pro‐Trp) ( 2 ), cyclo‐(Pro‐Leu) ( 3 ), cyclo (Trp‐Ser) ( 4 ), cyclo (Trp‐Ala) ( 5 ), indol 3‐acetic acid ( 6 ), 3‐hydroxyacetylindol ( 7 ) and indol‐3‐carboxylic acid ( 8 ) were isolated and characterized from the culture broth of the marine actinomycete Streptomyces sp. G330 strain. Their structures were determined by spectroscopic analysis including MS, 1D and 2D NMR, as well as by comparison with reported data in literature.  相似文献   
18.
    
The subgradient extragradient method can be considered as an improvement of the extragradient method for variational inequality problems for the class of monotone and Lipschitz continuous mappings. In this paper, we propose two new algorithms as combination between the subgradient extragradient method and Mann-like method for finding a common element of the solution set of a variational inequality and the fixed point set of a demicontractive mapping.  相似文献   
19.
    
Based on the extended extragradient‐like method and the linesearch technique, we propose three projection methods for finding a common solution of a finite family of equilibrium problems. The linesearch used in the proposed algorithms has allowed to reduce some conditions imposed on equilibrium bifunctions. The strongly convergent theorems are established without the Lipschitz‐type condition of bifunctions. The paper also helps in the design and analysis of practical algorithms and gives us a generalization of some previously known problems. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
20.
We expand the picture of plasmon hybridization in metamagnetic structure via numerically studying the electromagnetic coupling in the metallic cut-wire-pair super cells. It is shown that a triple negative permeability band can be achieved by systematically controlling the plasmon hybridization in such the structure. The corresponding transmission properties as well as the electromagnetic responses of the plasmon-hybridized structures were presented by using the finite integration technique simulations. Our results would reveal a promising design to obtain the multiple negative refractions based on the combination of hybridized cut-wire-pairs and continuous wires.  相似文献   
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