Effect of selective interactions of ionic acrylamide copolymers on flocculation properties with respect to titanium oxide in aqueous salt solutions

The kinetics of unhindered sedimentation of a titanium dioxide suspension (as model dispersed system) was studied, and the effect of the concentration and mode of addition of various formulations based on anionic and cationic acrylamide copolymers on their flocculation properties in aqueous salt (NaCl) solutions was evaluated.     

Thermodynamic parameters of urethane formation reactions and concomitant processes

Thermodynamic parameters of reactions of methyl and phenyl isocyanates with a series of compounds were determined by quantum-chemical calculations. The products of these reactions model for various functional groups present in commercial polyurethanes. The thermodynamic stability series for compounds formed from aliphatic and aromatic isocyanates were constructed.     

4-Functionally-substituted 3-heterylpyrazoles: XIX. 3-aryl-4-(5-isoxazolyl)pyrazoles

Oximes of 4-(4-pyrazolyl)-3-buten-2-onees obtained by successive reaction of 3-aryl-4-formylpyrazoles with acetone and hydroxylamine at the treatment with iodine suffered an oxidative cyclization yielding 3-aryl-4-(5-isoxazolyl)pyrazoles.     

New approach to processing of chlorine-containing wastes: Synthesis of 2,3-dichloropropene from 1,2,3-trichloropropane

Possibilities of utilization of by-products formed in manufacture of epichlorohydrin are considered. A promising way to utilize wastes from production of epichlorohydrin by synthesis of 2,3-dichloropropene from 1,2,3-trichloropropane is suggested.     

Influence of the composition of the polymer matrix on the electrooptical properties of films with a dispersed liquid crystal

Polymer films with a dispersed liquid crystal were prepared by photopolymerization of (meth)acrylic monomers. The electrooptical properties of these films were studied. The influence exerted by the composition of the monomer mixture, cross-linking agents, and chain-transfer agent on the liquid crystal drop size and on the transmission of the polymer-liquid crystal films was examined.     

Influence of transition metal ions on the textural properties of alumina and aluminasilicates

Accelerated phase transformations and chemical reactions of metastable aluminas and kaolinite, doped with Cu^{2 +}, Mn^{3 +}/Mn^{2 +} and Fe^{3 +}/Fe^{2 +} ions, are accompanied with accelerated decrease of surface area and pore volume values. The phenomena in metal ion doped samples are explained by a catalytic mechanism, in terms of the Jahn-Teller effect. This revised version was published online in June 2006 with corrections to the Cover Date.