Curcumin: A naturally occurring long‐wavelength photosensitizer for diaryliodonium salts

Curcumin, a naturally occurring, intensely yellow dye extracted from the spice turmeric, is an efficient photosensitizer for diaryliodonium salt photoinitiators at wavelengths ranging from 340 to 535 nm. With curcumin as a photosensitizer, it is possible to carry out the cationic photopolymerization of a wide variety of epoxide, oxetane, and vinyl monomers with long‐wavelength UV and visible light. An example of the photopolymerization of an epoxide monomer with ambient solar irradiation is provided. Several other curcumin analogues were synthesized, and their use as photosensitizers is examined. With such photosensitizers, the range of spectral sensitivity can be extended well into the visible region of the electromagnetic spectrum. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5217–5231, 2005     

Synthesis,dynamic light scattering,and luminescence properties of copolymers containing iridium(III) bisterpyridine in the side chain

Supramolecular block‐random copolymers containing [Ir(terpy)₂]³⁺ in the side chain were synthesized via postfunctionalization of a P(S‐b‐AC_terpy) block copolymer. Absorbance and emission spectra compared to a model compound show that the polymer backbone has a minor effect on the polymer absorbance but produces a larger shift for the phosphorescence signals to higher wavelength. Dynamic light scattering of the metal complex containing copolymer studied in various solvents showed monomodal aggregation with decreasing aggregate size as the solvent dielectric constant increased. The copolymer precursor P(S‐b‐AC_terpy) shows multimodal aggregation in different solvents with the major population consisting of single chains. This difference in behavior between the two polymers is attributed to the electrolytic nature of the complex and the amphiphilicity induced by the charged metal complex. Supramolecular copolymers like these will continue to have interesting self‐organizational properties and may find applications in multicomponent systems for photoinduced charge separation processes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1109–1121, 2007     

Degradative chain transfer in vinyl acetate polymerizations using toluene as solvent

In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (C_trs) determined using the Mayo method is equal to 3.8 × 10^?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10^?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the M_n data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007     

Control of a liquid–liquid heat exchanger

 The analytical solutions of equations describing the dynamics of distributed parameter systems are usually complicated in form and derivations and inconvenient to use for simulation and control system design. The liquid–liquid counter flow heat exchanger is an example of these disturbed parameter systems. An analytical solution of the dynamics of a symmetrically operated counter flow heat exchanger in the form of transfer function matrix is investigated in open-loop and close-loop conditions. The resulting non-linear model was linearized using perturbation approach. A feed-forward path controller to counteract at any disturbances in the boundary temperature and a non-interactive controller to decouple the outputs were implemented. Received on 22 February 2001 / Published online: 29 November 2001     

Unified approach to best unbiased estimation in control problems and linear models

An analog of a sufficient statistic is proposed in the finite-dimensional linear space of statistics. It is shown that the unbiased estimator of the linear function of a parameter closest to a given function, expressed in terms of a minimal linearly sufficient statistic, is potentially unbiased and optimal.Translated from Statisticheskie Metody Otsenivaniya i Proverki Gipotez, pp. 51–58, 1986.     

Asymptotic integration of a problem of convection

Rostov-on-Don. Translated from Sibirskii Matematicheskii Zhurnal, Vol. 30, No. 4, pp. 69–75, July–August, 1989.     

Self-broadening in the millimeter-wave spectrum of ozone

Self broadened widths of seven lines of ozone between 75 and 120 GHz have been measured at room temperature. The variation with temperature of the self-broadening parameter for three of these lines has been studied in the range 245–292°K.     

Method of linear prediction in the ultrasonic spectroscopy of rock

The possibility of using the resonant acoustic spectroscopy method for testing the internal state of rock is considered. This method can be used for the determination of the concentration of defects and their spatial distribution. A rock specimen with defects is characterized by a high loss of vibrational energy, which leads to the overlapping of the resonant responses. In this case, the complex resonant frequencies are determined as the parameters of a model that describes the measured transfer function of the response of the mechanical system. The linearity of the vibratory system is used as the a priori information for presetting the functional dependences of the model. An algorithm is developed for the determination of the parameters of the resonances in conditions of their partial overlapping. Examples are presented to demonstrate the possibility of analyzing the complex elastic constant tensor of rock by the acoustic spectroscopy method. The proposed method of experimental data processing provides the possibility for the determination of the weak anisotropy that occurs in the velocity of sound because of a partial fracture of rock.