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451.
Sanzharov N. A. Yarovoi A. T. Bekhtereva E. S. Ulenikov O. N. 《Russian Physics Journal》2002,45(10):1024-1031
Analytical formulas are derived that describe the dependences of the transition probabilities in vibrational-rotational spectra of XY3-type molecules with C
3v
symmetry on the rotational quantum numbers. 相似文献
452.
The circular dichroism (CD) method has been used to study the stereochemistry of the bisbenzyltetrahydroisoquinoline alkaloids. A relationship has been established between the absolute configurations of the asymmetric centers and the parameters of the Cotton effects in the CD spectra. The changes in the CD spectra on protonation have been correlated with conformational rearrangements of the molecules due to the different attachment of the oxygen bridges.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 818–823, November–December, 1979. 相似文献
453.
The interaction between azathioprine (AZ) and bovine serum albumin (BSA) is mainly due to hydrophobic binding according to the dependence of the binding constant on the ionic strength obtained by equilibrium dialysis. The binding constant and partition coefficient of AZ were smaller than those of warfarin, phenylbutazone and ibuprofen. Little variation in the proton chemical shift of AZ was observed whether there was an absence or presence of BSA (7.25 x 10(-5) M). The spin-lattice relaxation time (T1) of AZ decreased in the presence of BSA to 6-22%. The spin-spin relaxation rate (1/T2) of AZ increased 16-24 times for the methyl group and the imidazole ring and 8-13 times for the purine ring in the presence of BSA. The ratio of the spin-spin relaxation rate of the free AZ to the bound AZ ((1/T2)b/(1/T2)f) of the methyl group and the imidazole ring was 2-3 times larger than that of the purine ring. The binding of AZ to BSA was concluded to be mainly at the methyl group on the imidazole ring of AZ. 相似文献
454.
N. Euler W. -H. Steeb L. G. S. Duarte I. C. Moreira 《International Journal of Theoretical Physics》1991,30(9):1267-1271
The techniques of invertible point transformations and the Painlevé analysis can be used to construct integrable ordinary differential equations. We compare both techniques for the second Painlevé transcendent. 相似文献
455.
456.
S. A. Vakulenko 《Journal of Mathematical Sciences》1991,57(3):3093-3096
A generalization of Whitham's asymptotic principle for parabolic equations is stated. An application of this principle to Fisher's one-dimensional nonlinear equation is considered.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova, Vol. 179, pp. 46–51, 1989. 相似文献
457.
458.
It is proved that biorthogonal polynomials obey two different kinds of Christoffel-Darboux-type formulae, one linking polynomials with a different parameter and one combining polynomials with different degrees. This is used to produce a mixed recurrence relation, which is valid for all biorthogonal polynomials. This recurrence relation establishes several results on interlacing property of zeros of successive biorthogonal polynomials and leads to a new result on the interlace of zeros of orthogonal polynomials (of equal degrees) with respect to two distributionsdψ(x) andx p dψ(x), 0<p≤1, with support in either [0, 1] or [1, ∞). 相似文献
459.
460.
S. P. Mukherjee A. K. Chattopadhyay 《The Journal of the Operational Research Society》1989,40(5):489-494
Consider an organization with several categories of staff, each having a specified number of members. The age of entry into service and the age of retirement are both specified. Withdrawals occur at time-independent rates. Under this set-up, the authors have computed the maximum ages at which promotions should take place, assuming that the staff members continuing at various ages are random. Some illustrative calculations have been carried out. 相似文献