Organotellurides as a source of organometallics: application in the synthesis of (+/−)-frontalin

A masked lithium homoenolate, generated by tellurium/lithium exchange, was reacted with epoxides. The lithium compound was also converted into other organometallics such as Grignard, and cuprates and the reactivity of those organometallics with epoxides was evaluated. The same building block was employed in the synthesis of (+/−)-frontalin.     

Gauge-Related Deformations of Ordinary Linear Differential Operators with Constant Coefficients

Relations between the coefficients of gauge-related deformations and the solutions of a certain system of ordinary nonlinear differential equations are studied. These coefficients are found in an explicit form. Bibliography: 14 titles. Dedicated to P. V. Krauklis on the occasion of his seventieth birthday __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 308, 2004, pp. 235–251.     

On the distribution of the number of real zeros of a random polynomial

In this note, we find the distibution of the number of real zeros of a random polynomial. We also derive a formula for the expected number of complex zeros lying in a given domain of the complex plane. Bibliography: 7 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 320, 2004, pp. 69–79.     

The matrix equation AX-YB=C and related problems

The main result of the paper is a theorem, using which a new proof of Roth’s theorem is obtained, a new solvability criterion for the matrix equation AX-YB = C is proved, a formula for a particular solution of the latter is derived, and the least of the orders of square nonsingular matrices containing a given rectangular matrix as a submatrix is determined. Bibliography: 5 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 323, 2005, pp. 15–23.     

Scattering of surface plasmon polaritons by a nanoparticle with the inclusion of the magnetic dipole contribution

Using the method of the tensor Green’s function of the wave equation, the differential and total cross sections for the scattering of surface optical electromagnetic waves (surface plasmon polaritons) by a spherical nanoparticle into surface plasmon polaritons and light have been obtained with the inclusion of the magnetic dipole contribution. Using the example of noble metal systems, it has been shown that the magnetic dipole contribution may significantly affect the angular dependence of the differential cross sections and increase their anisotropy as the plasmon wavelength increases.     

Onset of crater formation during short pulse laser ablation

We report morphologic changes of metallic surfaces at the onset of ablation, starting from gentle ablation to the emergence of ablation craters. The evolution of both observed melting zones and of ablation craters therein are investigated in dependence of the ablation laser fluence for nanosecond ultraviolet laser pulses. Further, consequences of crater formation for cluster synthesis within the released atomic vapor are pointed out. PACS 52.38.Mf; 79.20.Ds; 65.40.De     

Duality for Finite Hopf Algebras Explained by Corings

We give a coring version for the duality theorem for actions and coactions of a finitely generated projective Hopf algebra. We also provide a coring analogue for a theorem of H.-J. Schneider, which generalizes and unifies the duality theorem for finite Hopf algebras and its refinements. This paper was written while the first author visited the Mathematics Departments of Syracuse University and California State University Dominguez Hills. He would like to thank both departments for their hospitality.     

Energy relaxation of hot carriers in single-wall carbon nanotubes by surface optical phonons of the substrate

A new mechanism is proposed for the energy relaxation of hot carriers in single-wall carbon nanotubes: scattering with the emission of surface optical phonons into the semiconductor substrate. The theory involves intrasubband and intersubband forward and backward scattering. The analytical result and numerical data indicate that intrasubband forward scattering is the main process: the corresponding lifetime comprises several femtoseconds for a quartz substrate, which allows this mechanism of energy relaxation to be considered dominating for a nanotube on the surface of a polar semiconductor or a dielectric.     

Definition and properties of characteristic frequencies of a linear equation

The definition of the characteristic frequencies of zeroes and changes of sign for solutions is given. It is equal to the upper medium (with respect to the time half-axis) of their number on the half-interval of length π. We also define the main frequencies for a linear homogeneous equation of order n. These main frequencies for an equation with constant coefficients coincide with the absolute values of the imaginary parts of the roots of the corresponding characteristic polynomial. It is proved that for the second-order equation the main frequencies are the same for all solutions and that they are stable with respect to uniformly small and infinitely small perturbations of the coefficients. For the third-order equation they can be different, and for any of the main frequencies an example of nonstability is given. __________ Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 25, pp. 249–294, 2005.     

Electrochemical Recovery of Silver from Lead Alloys in Chloride Melts

Electrochemical separation of lead-silver alloys into the constituents by thin-layer electrolysis in molten electrolytes, with bismuth as metal separator, is studied. It is proposed to determine the extent of component recovery by potentiometry.