Effect of maltodextrins on the surface activity of small-molecule surfactants

We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na⁺), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed.     

Longwave Marangoni convection in an inhomogeneously heated liquid

The supercritical Marangoni convection has been studied in a plane-parallel liquid layer, bounded by a free deformable gas-liquid interface from above and by a low-heat-conductivity wall from below, occurring under conditions of inhomogeneous heating in the horizontal plane. In a longwave approximation with a small inhomogeneity of heat flux, the process is described by a system of two-dimensional nonlinear equations for the temperature perturbations, vorticity, and free surface deformation. The concept of quasiequilibrium, implying stability of long-range flows, is introduced, which allows the inhomogeneous heat flux to be modeled by a step function. The linear stability is analyzed in the cases of planar and axisymmetric heat fluxes. The boundaries of stability of the convection regimes are determined on the plane of parameters characterizing the degree of supercriticity inside a heated spot and the depth of damping outside the spot. For an axisymmetric spot, the domains of stability with respect to perturbations for various azimuthal numbers are established.     

Temperature dependences of the low-frequency internal friction and shear modulus in a bulk amorphous alloy

The logarithmic decrement and shear modulus of a bulk amorphous Zr_52.5Ti₅Cu_17.9Ni_14.6Al₁₀ alloy were studied with an inverse torsion pendulum in the range from room temperature to the crystallization temperature and in the frequency range 5–40 Hz. The activation energy spectra of reversible and irreversible structural relaxation were estimated. The results obtained are discussed in the context of a two-energy-level model.     

Core-shell structure in fullerene-containing molecular complexes

A shell model that describes the formation of molecular complexes around a C₆₀ molecule upon the solid-phase interaction of the powders is considered. From the absorption spectra, it follows that a reacting particle is a fullerene dimer.     

Generation of angular momentum of fission fragments in a cluster model

Based on the dinuclear system concept, the role of bending vibrations in creation of the angular momentum of primary fission fragments is investigated. For ²⁵²Cf spontaneous fission, the angular momenta of the fragments are calculated as a function of the neutron multiplicity and compared with available experimental data. Different cluster compositions of the ²⁵²Cf fission modes at the scission point are considered.     

Intrinsic Fluorescence of Actin

In this work actin is used to illustrate connection of protein fluorescence characteristics with its structure. On one hand, it has been demonstrated what kind of information about the contribution of each tryptophan residues to the bulk fluorescence spectrum can be obtained from the special analysis of protein three-dimensional structure. On the other hand, potentials of intrinsic fluorescence for elucidation of proteins structure, dynamics and processes of folding-unfolding are shown. In particular, using this method a new essentially unfolded kinetic intermediate state of actin was detected and characterized, and the place of inactivated actin and its kinetic predecessor in the process of folding-unfolding was determined. It has been revealed that inactivated actin is not intermediate state between the native and completely unfolded states, as it has been accepted before, but a result of protein misfolding. On the basis of the obtained data a new model of actin folding-unfolding pathway has been proposed.     

Parametric Frequency Converters Based on New Nonlinear Crystals

Results of investigations into the physical properties of a number of new nonlinear crystals are presented. The parameters of frequency converters manufactured on their basis are compared, and second-harmonic generation of CO₂ lasers first excited by frequency conversion in LiInSe₂, AgGa_{1– x} In_xSe₂, Ag_xGa_xGe_xS_{2(1 + x)}, and Hg_1–x Cd_xGa₂S₄ crystals is investigated. The superiority of HgGa₂S₄, Hg_1–x Cd_xGa₂S₄, and AgGa_1–x In_xSe₂ over the well-known crystals has been demonstrated for frequency conversion both within the middle-IR range and from the visible range to the middle-IR range. Advantages of LiInSe₂ and AgGa_1–x In_xSe₂ crystals are demonstrated for the direct frequency conversion of femtosecond laser radiation to the middle-IR range compared to the cascade frequency conversion and direct frequency conversion in LiInS₂ crystals.