Structural Composition of Butadiene–Styrene Copolymers,According to 1Н and 13С NMR Data

Russian Journal of Applied Chemistry - Commercial samples of butadiene–styrene copolymers were studied by NMR spectroscopy in a magnetic field of 16.4 T (protons Larmor frequency 700 MHz). A...     

Chromatography-Free Multicomponent Synthesis of Thioureas Enabled by Aqueous Solution of Elemental Sulfur

The development of a new three-component chromatography-free reaction of isocyanides, amines and elemental sulfur allowed us the straightforward synthesis of thioureas in water. Considering a large pool of organic and inorganic bases, we first optimized the preparation of aqueous polysulfide solution from elemental sulfur. Using polysulfide solution, we were able to omit the otherwise mandatory chromatography, and to isolate the crystalline products directly from the reaction mixture by a simple filtration, retaining the sulfur in the solution phase. A wide range of thioureas synthesized in this way confirmed the reasonable substrate and functional group tolerance of our protocol.     

Ceramic properties of kaolinitic clay with monoaluminum phosphate (Al(H2PO4)3) addition

Journal of Thermal Analysis and Calorimetry - The effect of monoaluminum phosphate (Al(H2PO4)3) addition in the thermochemical process of a kaolinitic clay was studied and compared with the pure...