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61.
Associative version of Henderson-Abraham-Barker theory is applied for the study of Mercedes-Benz model of water near hydrophobic surface. We calculated density profiles and adsorption coefficients using Percus-Yevick and soft mean spherical associative approximations. The results are compared with Monte Carlo simulation data. It is shown that at higher temperatures both approximations satisfactory reproduce the simulation data. For lower temperatures, soft mean spherical approximation gives good agreement at low and at high densities while in at mid range densities, the prediction is only qualitative. The formation of a depletion layer between water and hydrophobic surface was also demonstrated and studied. 相似文献
62.
Y. V. Kalyuzhnyi C. R. Iacovella H. Docherty M. Holovko P. T. Cummings 《Journal of statistical physics》2011,145(2):481-506
Thermal and connectivity properties of the Yukawa square-well m-point (YSWmP) model of the network forming fluid are studied using solution of the multidensity Ornstein-Zernike and connectedness
Ornstein-Zernike equations supplemented by the associative mean spherical approximation (AMSA). The model is represented by
the multicomponent mixture of Yukawa hard spheres with msam_{s}^{a} square-well sites, located on the surface of each hard sphere. To validate the accuracy of the theory, computer simulation
is used to calculate the structure, thermodynamic and connectivity properties of the one-component YSW4P version of the model
which is compared against corresponding theoretical data. In addition, connectivity properties of the model were studied using
Flory-Stockmayer (FS) theory. Predictions of the AMSA for the thermal properties of the model (radial distribution functions
(RDF), internal energy, pressure, fractions of the particles in different bonding states) are in good agreement with computer
simulation predictions. Similarly, good agreement was found for the connectedness RDF (CRDF), except for the statepoints located
close to the percolation threshold, where the theory fails to reproduce the long-range behavior of the CRDF. Results of both
theories (AMSA and FS) for the mean cluster size are reasonably accurate only at low degrees of association. Predictions of
the FS theory for the percolation lines are in a good agreement with computer simulation predictions. AMSA predictions of
percolation are much less accurate, where corresponding percolation lines are located at a temperatures approximately 25%
lower then those calculated using computer simulation. 相似文献
63.
Bogdan A Rudzevich Y Vysotsky MO Böhmer V 《Chemical communications (Cambridge, England)》2006,(28):2941-2952
Calix[4]arenes bearing at their wide rim four urea residues easily form hydrogen bonded dimeric capsules. This has been used to preorganise alkenyl functions attached to these urea groups for their controlled connection via metathesis reaction. Multimacrocyclic tetraurea derivatives are thus obtained in excellent yields via heterodimers which are formed exclusively with tetratosylurea derivatives. Heterodimerisation of such bis- and tetraloop tetraureas leads analogously to multicatenanes, or to rotaxanes by stoppering. Huge macrocycles are detached from tetraloop derivatives by cleavage of the urea function. 相似文献
64.
Petro Zoriy Reinhold Flucht Mechthild Burow Peter Ostapczuk Reinhard Lennartz Myroslav Zoriy 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(1):211-216
A robust analytical method has been developed in our laboratory for the separation of radionuclides by means of extraction chromatography using an automated separation system. The proposed method is both cheap and simple and provides the advantageous, rapid and accurate separation of the element of interest. The automated separation system enables a shorter separation time by maintaining a constant flow rate of solution and by avoiding clogging or bubbling in the chromatographic column. The present separation method was tested with two types of samples (water and urine) using UTEVA-, TRU- and Sr-specific resins for the separation of U, Th, Am, Pu and Sr. The total separation time for one radionuclide ranged from 60 to 100 min with the separation yield ranging from 68 to 98% depending on the elements separated. We used ICP-QMS, multi-low-level counter and alpha spectroscopy to measure the corresponding elements. 相似文献
65.
In this paper, from the Born-Green-Yvon equations of the liquid-state theory, we derive a general expression for the charge-density contact value at charged interfaces. This relation is discussed, in particular, for symmetrical electrolytes. We emphasize an essential coupling between the electric properties and the density profile. Limiting behavior at small and large charges at the interface is discussed. 相似文献