全文获取类型
收费全文 | 1609篇 |
免费 | 58篇 |
国内免费 | 15篇 |
专业分类
化学 | 1019篇 |
晶体学 | 25篇 |
力学 | 58篇 |
数学 | 244篇 |
物理学 | 336篇 |
出版年
2023年 | 10篇 |
2022年 | 50篇 |
2021年 | 47篇 |
2020年 | 45篇 |
2019年 | 54篇 |
2018年 | 55篇 |
2017年 | 56篇 |
2016年 | 75篇 |
2015年 | 56篇 |
2014年 | 70篇 |
2013年 | 163篇 |
2012年 | 101篇 |
2011年 | 139篇 |
2010年 | 82篇 |
2009年 | 87篇 |
2008年 | 99篇 |
2007年 | 97篇 |
2006年 | 68篇 |
2005年 | 60篇 |
2004年 | 47篇 |
2003年 | 43篇 |
2002年 | 33篇 |
2001年 | 12篇 |
2000年 | 12篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 11篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 9篇 |
1992年 | 10篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1682条查询结果,搜索用时 15 毫秒
21.
The Ising model with three alternative layers on the honeycomb and square lattices is studied by using the effective-field theory with correlations. We consider that the nearest-neighbor spins of each layer are coupled ferromagnetically and the adjacent spins of the nearest-neighbor layers are coupled either ferromagnetically or anti-ferromagnetically depending on the sign of the bilinear exchange interactions. We investigate the thermal variations of the magnetizations and present the phase diagrams. The phase diagrams contain the paramagnetic, ferromagnetic and anti-ferromagnetic phases, and the system also exhibits a tricritical behavior. 相似文献
22.
Ghommem Mehdi Najar Fehmi Arabi Mohamed Abdel-Rahman Eihab Yavuz Mustafa 《Nonlinear dynamics》2020,101(1):271-291
Nonlinear Dynamics - We present a unified model of electrostatic sensors comprising cantilever microbeam resonators in fluid media. The model couples Euler–Bernoulli beam equation to the... 相似文献
23.
Abdul Q. Ramle Asli Karakas Abdul K. M. Arof Mustafa Karakaya Mehmet Taser Aysun Gozutok Chee Chin Fei Nurhidayatullaili M. Julkapli Wan J. Basirun 《Journal of heterocyclic chemistry》2020,57(10):3566-3573
Two new macrocyclic dibenzotetraaza[14]annulene (DBTAA) compounds with indolenine ( 5 ) and pyridoindolenine ( 6 ) moieties were synthesized and characterized by spectroscopy. Both DBTAAs exhibit strong UV-Vis absorption properties in the Soret band region. The theoretical second-order nonlinear optical property, electric dipole moment (μ), dispersion-free dipole polarizability (α) and first hyper-polarizability values were calculated by density functional theory and time dependent density functional theory. The ab-initio quantum mechanical calculation by time-dependent Hartree-Fock method was utilized to investigate the dynamic dipole polarizabilities, dynamic second-order, static, and dynamic third-order (γ) hyper-polarizabilities of the DBTAAs. The configuration interaction technique of all doubly occupied molecular orbitals possesses theoretically defined single-photon absorption (OPA) specifications for the examined structures. The computed maximum OPA wavelengths on both macrocyclic compounds coincide with the preceding measurement outcomes. 相似文献
24.
Mustafa A. S. Gouda Mounir A. I. Salem Naglaa F. H. Mahmoud 《Journal of heterocyclic chemistry》2020,57(11):3988-4006
Some poly functionalized heterocyclic-compounds containing pyridine-moieties were readily assembled by combining differently functionalized pyridopyrimidine-6-carbonitrile derivatives 1a,b with different electrophilic and nucleophilic reagents via short synthetic routes. The structures of the prepared derivatives were ascertained from their-spectral-and elemental analyses. Some of the synthesized compounds were tested as plausible antitumor agents. Most of those tested compounds likes 7 , 9 , 10 , 11a showed cytotoxic potencies against different tumor cell lines. In addition, the assessments for their antioxidant activities have also been done and compound 9 exhibited the highest antioxidant activity while compounds 7 and 10 showed moderate activities. Finally, molecular docking studies were carried out which favorably indicated a high support for the experimental-results. 相似文献
25.
In this study, an ITO (indium tin oxide) based biosensor was constructed to detect SOX2. SOX2 helps the regulation of cell pluripotency and is closely related to early embryonic development, neural and sexual differentiation. SOX2 is amplified and overexpressed in some malignant tumors such as squamous cell, lung, prostate, breast, esophageal cell, colon, ovarian, glioblastoma, pancreatic cancer, gastric cancer, head and neck squamous cell carcinoma. To generate a hydroxylated clean electrode surface, ITO electrodes were treated with NH4OH/H2O2/H2O. Later, ITO‐PET electrode surfaces were modified with 3‐glycidoxypropyl trimethoxysilane (3‐GOPS). Then, Anti‐SOX2 was covalently immobilized onto the electrode surfaces. 3‐GOPS concentration, Anti‐SOX2 concentration and incubation time, SOX2 incubation time were optimized. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) were utilized in order to follow up the immobilization processes and the optimization steps of the biosensor. To characterize the analytical properties of constructed immunosensor; linear range, repeatability, reproducibility and regeneration studies were investigated. The linear range of the immunosensor was detected as 0.625 pg/mL–62.5 pg/mL. Square wave voltammetry technique was also applied to the biosensor. Storage life of the biosensor was determined for identifying the possible usability of the biosensor in clinical field. Finally, the designed biosensor was applied to the real human serum samples. The results obtained with the presented biosensor were also compared with ELISA results. 相似文献
26.
The legume lectins are a large family of homologous carbohydrate-binding proteins. Their carbohydrate specificity and quaternary
structure vary widely. The carbohydrate binding activity of legume lectins depends on the simultaneous presence of calcium
and transition-metal ions, especially the Mn2+ ion. In the present work, thermal stabilities of Mn2+ binding sites in pea, lentil, soybean and kidney-bean lectins have been studied by electron spin resonance spectroscopy in
the temperature range of 120–400 K in different atmospheres. The evolution of parameters, such as the line width, peak-to-peak
intensity associated with the hyperfine transition [m
I
(+5/2) → m′
I
(−5/2)] at the lowest magnetic field side of the central electron transition [m
S
(+1/2) → m′
S
(−1/2)] of the Mn+2 ion, g-factor and hyperfine splitting was evaluated. Annealing was also performed at high temperatures (353, 373, 383, 403 and 443
K) and the oxidation activation energy of Mn2+ ions in the indicated legumes was determined. 相似文献
27.
We present a novel design and analysis of two nano-scale plasmonic devices: a directional coupler and a Mach–Zehnder interferometer. The designs of the two devices are based on our recent work on the air-gap coupler that resulted in high coupling efficiency between a dielectric waveguide and a plasmonic waveguide. The two devices are embedded between two dielectric waveguides and operate at optical telecom wavelengths. The overall efficiency was 37% for a 2×2 directional coupler switch and above 50% for the proposed designs for a Mach–Zehnder Interferometer. The efficiency in the proposed devices can be increased using broader plasmonic waveguides. 相似文献
28.
Nazar Mohammed Gabra Bakheit Mustafa Yata Praveen Kumar C. Shobha Devi A. Srishailam P. Venkat Reddy Kotha Laxma Reddy S. Satyanarayana 《Journal of fluorescence》2014,24(1):169-181
A new ligand 3-(1H-imidazo[4,5-f][1,10]phenanthrolin-2yl)phenylboronic acid and its (IPPBA) three ruthenium(II) complexes [Ru(phen)2(IPPBA)](ClO4)2 (1), [Ru(bpy)2(IPPBA)](ClO4)2 (2) and [Ru(dmb)2(IPPBA)](ClO4)2 (3) have been synthesized and characterized by elemental analysis, UV/VIS, IR, 1H-NMR,13C-NMR and mass spectra. The binding behaviors of the three complexes to calf thymus DNA were investigated by absorption spectra, emission spectroscopy, viscosity measurements, thermal denaturation and photoactivated cleavage. The DNA-binding constants for complexes 1, 2 and 3 have been determined to be 7.9?×?105 M?1, 6.7?×?105 M?1 and 2.9?×?105 M?1. The results suggest that these complexes bound to double-stranded DNA in an intercalation mode. Upon irradiation at 365 nm, three ruthenium complexes were found to promote the cleavage of plasmid pBR322 DNA from super coiled form ? to nicked form ??. Further in the presence of Co2+, the emission of DNA–Ru(ΙΙ) complexes can be quenched. And when EDTA was added, the emission was recovered. The experimental results show that all three complexes exhibited the “on–off–on” properties of molecular “light switch”. The highest Cytotoxicity potential of the complex1 was observed on the Human alveolar adenocarcinoma (A549) cell line. Good agreement was generally found between the spectroscopic techniques and molecular docked model which provides further evidence of groove binding. 相似文献
29.
Berna Bülbül Mustafa Gülsu Mehmet Sezer 《Numerical Methods for Partial Differential Equations》2010,26(5):1006-1020
The aim of this article is to present an efficient numerical procedure for solving nonlinear integro‐differential equations. Our method depends mainly on a Taylor expansion approach. This method transforms the integro‐differential equation and the given conditions into the matrix equation which corresponds to a system of nonlinear algebraic equations with unkown Taylor coefficients. The reliability and efficiency of the proposed scheme are demonstrated by some numerical experiments and performed on the computer program written in Maple10. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2010 相似文献
30.
An efficient computational method for a stochastic dynamic lot-sizing problem under service-level constraints 总被引:1,自引:0,他引:1
S. Armagan Tarim Mustafa K. Dogˇru Ula? Özen Roberto Rossi 《European Journal of Operational Research》2011,215(3):563-571
We provide an efficient computational approach to solve the mixed integer programming (MIP) model developed by Tarim and Kingsman [8] for solving a stochastic lot-sizing problem with service level constraints under the static-dynamic uncertainty strategy. The effectiveness of the proposed method hinges on three novelties: (i) the proposed relaxation is computationally efficient and provides an optimal solution most of the time, (ii) if the relaxation produces an infeasible solution, then this solution yields a tight lower bound for the optimal cost, and (iii) it can be modified easily to obtain a feasible solution, which yields an upper bound. In case of infeasibility, the relaxation approach is implemented at each node of the search tree in a branch-and-bound procedure to efficiently search for an optimal solution. Extensive numerical tests show that our method dominates the MIP solution approach and can handle real-life size problems in trivial time. 相似文献