Dust ion‐acoustic solitons with trapped q‐non‐extensive electrons,dissipative processes,and streaming ions

The characteristics of dust ion‐acoustic waves (DIAWs) that are excited because of streaming ions and hot q‐non‐extensive electrons obeying a vortex‐like distribution are investigated. By exploiting a pseudo‐potential technique, we have derived an energy integral equation. The presence of non‐extensive q‐distributed hot trapped electrons and a streaming ion beam has been shown to influence soliton structure quite significantly. The evolution of the soliton‐like perturbations in complex plasmas, taking into account the dissipation processes, are also investigated, obtained by numerically solving the modified Schamel, equation whose widths are dependant on electron trapping efficiency β. Our illustrations indicate that compressive DIAWs develop in this plasma. As the plasmas in reality have a relative flow, such an analysis can be used to understand the DIA solitary structures observed in the mesospheric noctilucent clouds.     

Lowest-lying tetra-quark hadrons in anisotropic lattice QCD

We present a detailed study of the lowest-lying hadrons in quenched improved anisotropic lattice QCD. Using the π π and diquark–antidiquark local and smeared operators, we attempt to isolate the signal for I(J ^P )=0(0⁺),2(0⁺) and 1(1⁺) states in two flavour QCD. In the chiral limit of the light-quark mass region, the lowest scalar 4q state is found to have a mass, m _4q ^I=0=927(12) MeV, which is slightly lower than the experimentally observed f ₀(980). The results from our variational analysis do not indicate a signature of a tetraquark resonance in I=1 and I=2 channels. After the chiral extrapolation the lowest 1(1⁺) state is found to have a mass m _4q ^I=1=1358(28) MeV. We analysed the static 4q potential extracted from a tetraquark Wilson loop and illustrated the behaviour of the 4q state as a bound state, unbinding at some critical diquark separation. From our analysis we conclude that the scalar 4q system appears as a two-pion scattering state and that there is no spatially-localised 4q state in the light-quark mass region.     

Sinapic Acid Ameliorates Acetic Acid-Induced Ulcerative Colitis in Rats by Suppressing Inflammation,Oxidative Stress,and Apoptosis

Background: Ulcerative colitis (UC) is a long-term condition which results in inflammation and ulcers of the colon and rectum. The key indications of active disease are abdominal pain and diarrhea mixed with blood. Aims: We explore the underlying colon protective mechanism of sinapic acid (SA) against acetic acid (AA) induced ulcerative colitis in rats. The implications of inflammation, oxidative stress, and apoptosis are studied. Methodology: Twenty-four rats were distributed into four categories, normal control (NC), ulcerative colitis (UC), ulcerative Colitis with SA 40 mg/kg (SA 40 mg/kg + AA), and ulcerative colitis with prednisolone (PRDL 10 mg/kg + AA), and were pretreated orally with saline, saline and SA (40 mg/kg/day) or PRDL (10 mg/kg/day) respectively, for 7 days. UC was prompted by trans-rectal administration of 4% AA on the 5th day, colon tissues were surgically removed for gross morphology and histological inspection, oxidative stress, and inflammatory markers and immunoblot analysis of Bax, caspase-3, and Bcl-2. Results: Macroscopic and histological inspection demonstrated that both SA 40 mg/kg and PRDL (10 mg/kg/day) significantly ameliorates colonic injuries. In addition, both pretreatments significantly ameliorates AA-induced UC, oxidative stress, as indicated by suppressed malondialdehyde (MDA), nitric oxide (NO) levels and restoring antioxidant/oxidant balance as indicated by catalase and glutathione levels, suppressed inflammation via inhibiting cytokines TNF-α, IL-6, inflammatory markers MPO, PGE₂, COX-2 and NF-κB and inhibiting the protein expression of Bax and caspase-3 apoptotic protein and increasing the anti-apoptotic protein, Bcl-2 thereby inhibiting apoptosis. Conclusion: Sinapic acid significantly ameliorates AA induced UC in rats by suppressing inflammation, oxidative stress, and apoptosis in colonic tissues which exhibits its potential for the management of UC.     

Formulation Development of Mirtazapine Liquisolid Compacts: Optimization Using Central Composite Design

Mirtazapine is a tetracyclic anti-depressant with poor water solubility. The aim of this study was to improve the dissolution rate of mirtazapine by delivering the drug as a liquisolid compact. Central composite design (CCD) was employed for the preparation of mirtazapine liquisolid compacts. In this, the impacts of two independent factors, i.e., excipient ratio (carrier:coating) and different drug concentration on the response of liquisolid system were optimized. Liquisolid compacts were prepared using propylene glycol as a solvent, microcrystalline cellulose as a carrier, and silicon dioxide (Aerosil) as the coating material. The crystallinity of the formulated drug and the interactions between the excipients were examined using X-ray powder diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR), respectively. The dissolution study for the liquisolid compact was carried out as per FDA guidelines. The results showed loss of crystallinity of the mirtazapine in the formulation and was completely solubilized in non-volatile solvent and equally dispersed throughout the powder system. Moreover, drug dissolution was found to be higher in liquisolid compacts than the direct compressed conventional tablets (of mirtazapine). The liquisolid technique appears to be a promising approach for improving the dissolution of poorly soluble drugs like mirtazapine.     

Biodiesel Production Using Wild Apricot (Prunus aitchisonii) Seed Oil via Heterogeneous Catalysts

We confined the formation and characterization of heterogenous nano-catalysts and then used them to produce biodiesel from the novel non-edible seed oil of Prunus aitchisonii. P. aitchisonii seeds’ oil content was extracted at about 52.4 ± 3% with 0.77% FFA. Three different heterogenous nano-catalysts—calcined (CPC), KPC, and KOH-activated P. aitchisonii cake Titanium Dioxide (TiO₂)—were synthesized using calcination and precipitation methods. The mentioned catalysts were characterized through XRD, SEM, and EDX to inspect their crystallin dimension, shape, and arrangement. Titanium dioxide has morphological dimensions so that the average particle size ranges from 49–60 nm. The result shows that the crystal structure of TiO₂ is tetragonal (Anatase). The surface morphology of CPC illustrated that the roughness of the surface was increased after calcination, many macropores and hollow cavities appeared, and the external structure became very porous. These changes in morphology may increase the catalytic efficiency of CPC than non-calcined Prunus aitchisonii oil cake. The fuel belonging to PAOB stood according to the series suggested by ASTM criteria. All the characterization reports that P. aitchisonii is a novel and efficient potential source of biodiesel as a green energy source.     

Anisotropic stellar structures in the f(T) theory of gravity with quintessence via embedding approach

This work suggests a new model for anisotropic compact stars with quintessence in f(T)gravity by us-ing the off-diagonal tetrad and the power-law as f(T)=βTⁿ,where T is the scalar torsion andβand n are real con-stants.The acquired field equations incorporating the anisotropic matter source along with the quintessence field,in f(T)gravity,are investigated by making use of the specific character of the scalar torsion T for the observed stars PSRJ1614-2230,4U1608-52.CenX-3,EXO1785-248,and SMCX-1.It is suggested that all the stellar struc-tures under examination are advantageously independent of any central singularity and are stable.Comprehensive graphical analysis shows that various physical features which are crucially important for the emergence of the stellar structures are conferred.     

Chemical Constituents of Beilschmiedia maingayi

Chemistry of Natural Compounds -     

Plasmonic Au-Metal Oxide Nanocomposites for High-Temperature and Harsh Environment Sensing Applications

Noble metal nanoparticles like Au have long been admired for their brilliant colour, significantly influenced by plasmon resonance. When embedded in metal oxides, they exhibit unique properties which make them an excellent choice for sensing in high-temperature and harsh environment atmospheres. In this review, the various morphologies of Au nanoparticles (AuNPs) used in combination with metal oxides for sensing gases at temperatures greater than 300 °C are discussed. Theoretical discussions on the plasmon resonance properties of AuNPs as well as computational techniques like finite difference time domain (FDTD), are often used for understanding and correlating their extinction spectra and are briefed initially. The sensing properties of AuNPs embedded on a metal oxide matrix (such as TiO₂, SiO₂, NiO etc) for quantifying multiple analytes are then elucidated. The effect of high temperature as well as gas environments including corrosive atmospheres on such nanocomposites, and the different approaches to comprehend them are presented. Finally, techniques and methods to improve on the challenges associated with the realization and integration such Au-metal oxide plasmonic nanostructures for applications such as combustion monitoring, fuel cells, and other applications are discussed.     

Proton spin conversion of coupled methyl groups in lithium acetate studied by inelastic neutron scattering

The temperature dependence of the tunneling spectrum of methyl groups in lithium acetate dihydrate has been studied in the temperature range between 1.2 and 8.0 K by inelastic neutron scattering. The results unambiguously prove that it is to a first order approximation correct to describe the tunneling motions by a model of coupled CH₃ pairs which are isolated from each other. However, from the fact that the tunneling frequencies shift to higher values with decreasing spin temperature, we conclude that coupling effects are important not only between nearest neighbour CH₃ groups. Quantitatively we can describe the observations by a model of coupled pairs with a fixed value for the interaction potentialW ₃ and a variable single particle potentialV ₃ which depends linearly on the concentration of the spin symmetry species.     

NiFe2O4 as a magnetically recoverable nanocatalyst for odourless C–S bond formation via the cleavage of C–O bond in the presence of S8 under mild and green conditions

We present green methodologies for one‐pot and odourless syntheses of unsymmetric and symmetric diaryl sulfides via C─O bond activation using NiFe₂O₄ magnetic nanoparticles as a reusable heterogeneous nanocatalyst. The synthesis of unsymmetric sulfides is performed using the cross‐coupling reaction of phenolic esters such as acetates, triflates and tosylates with arylboronic acid/S₈ or triphenyltin chloride/S₈ as thiolating agents in the presence of base and NiFe₂O₄ magnetic nanoparticles as a catalyst in poly(ethylene glycol) as solvent at 60–85°C. Also, the synthesis of symmetric diaryl sulfides from phenolic compounds using S₈ as the sulfur source and NiFe₂O₄ as catalyst in dimethylformamide at 120°C is described. Using these protocols, the syntheses of various unsymmetric and symmetric sulfides become easier than using the available protocols due to the use of a magnetically reusable bimetallic nanocatalyst and avoiding the use of thiols and aryl halides.