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481.
Barsu C Fortrie R Nowika K Baldeck PL Vial JC Barsella A Fort A Hissler M Bretonnière Y Maury O Andraud C 《Chemical communications (Cambridge, England)》2006,(45):4744-4746
The design of new chromophores presenting simultaneous SHG and TPEF properties is reported. 相似文献
482.
Su HC Fadhel O Yang CJ Cho TY Fave C Hissler M Wu CC Réau R 《Journal of the American Chemical Society》2006,128(3):983-995
The photophysical, electrochemical, and optoelectronic properties of conjugated systems incorporating dibenzophosphole or phosphole moieties are described. Dibenzophosphole derivatives are not suitable materials for OLEDs due to their weak photoluminescence (PL) in the solid state and the instability of the devices. Variation of the substitution pattern of phospholes and chemical modification of their P atoms afford thermally stable derivatives, which are photo- and electroluminescent. Comparison of the optical properties of solution and thin film of thioxophospholes shows that these compounds do not form aggregates in the solid state. This property, which is also supported by an X-ray diffraction study of three novel derivatives, results in an enhancement of the fluorescence quantum yields in the solid state. In contrast, (phosphole)gold(I) complexes exhibit a broad emission in thin film, which is due to the formation of aggregates. Single- and multilayer OLEDs using these P derivatives as the emissive layer have been fabricated. The emission color of these devices and their performances vary with the nature of the P material. Interestingly, di(2-thienyl)thiooxophosphole is an efficient host for the red dopant DCJTB, and devices using the gold complexes have broad emission spectra. 相似文献
483.
Herman Gershon Donald D. Clarke Muriel Gershon 《Monatshefte für Chemie / Chemical Monthly》2001,158(1):1075-1080
3,5,6-, 3,5,7-, 4,5,7-, and 5,6,7-trichloro- and -tribromo-8-quinolinols as well as 3,5,6,7-tetrachloro- and -tetrabromo-8-quinolinols were prepared and tested against six fungi (Aspergillus niger, Aspergillus oryzae, Myrothecium verrucaria, Trichoderma viride, Mucor cirinelloides, and Trichophyton mentagrophytes) in Sabouraud dextrose broth. The compounds strongly inhibit five fungi but not M. cirinelloides. They are less active than the related dichloro-8-quinolinols which is attributed to steric hindrance. 相似文献
484.
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487.
Alain Le Borgne Valrie Vincens Muriel Jouglard Nicolas Spassky 《Macromolecular Symposia》1993,73(1):37-46
Bifunctional telechelics with defined structure can be prepared by oligomerization of oxiranes, β-butyrolactone and L-lactide using aluminium Schiff's base complexes as initiators. Chiral initiator (SALCENAlCl) shows a stereoelective character leading to preferential oligomerization of one enantiomer from a racemic monomer mixture. The reaction with β-butyrolactone proceeds through O-alkyl cleavage. Alkoxy Schiff's bases aluminium complexes are used for oligomerization of L-lactide. All the prepared oligomers were fully characterized by IR, elemental analysis, 1H and 13C NMR and GPC. 相似文献
488.
Darinka Christova Rumiana Velichkova Eric J. Goethals 《Macromolecular rapid communications》1997,18(12):1067-1073
Poly(2-alkyl-2-oxazoline)s having an acrylate group at both chain ends were synthesized by terminating living bifunctional poly(2-methyl-2-oxazoline) or poly(2-ethyl-2-oxazoline) with acrylic acid. These macromonomers have been polymerized to the corresponding polyoxazoline networks. Thermal as well as UV-initiated free radical polymerization were applied and the influence of the polymerization conditions and molecular weight of the prepolymer used on the properties of the networks were investigated. Both methods of polymerization produced high fractions of soluble material, probably due to the low concentration of the acrylate end groups. 相似文献
489.
Nicolas Spassky Christian Pluta Vesna Simic Mohamedou Thiam Muriel Wisniewski 《Macromolecular Symposia》1998,128(1):39-51
The stereochemical aspects of controlled polymerization of lactide and β-butyrolactone are discussed. The physicochemical and thermal properties of these polymers are shown to be depending on the stereochemical structure of the macromolecular chain. Different types of processes involving change of enantiomeric composition in the course of the polymerization reaction are examined in function of different initiators used. The formation of stereocomplexes from stereocopolymers of various enantiomeric compositions is reported. 相似文献
490.
Swapan K. Chowdhury Muriel Doleman David Johnston 《Journal of the American Society for Mass Spectrometry》1995,6(6):478-487
Matrix-assisted laser desorption-ionization (MALDI) mass spectrometry was investigated as a method for the rapid determination of the extent of polymer coupling in polyethylene glycol- (PEG) conjugated superoxide dismutase (SOD). PEG-conjugated SOD, an antioxidant with an extended in vivo circulation lifetime compared to that of superoxide dismutase, is being evaluated as an effective therapeutic agent for the treatment of injuries and arthritis. The mass spectra of a standard batch of PEG-conjugated bovine SOD showed the presence of identifiable and well resolved peaks that correspond to 0–7 PEG molecules attached to bovine SOD. The area of each of the peaks provides a determination of the amount of PEG-conjugated SOD with a given number of bound PEG groups. SOD is a noncovalent dimer of two identical subunits that dissociates in MALDI. The information obtained in the mass spectra thus corresponds to a monomer of SOD. Each SOD monomer contains 10 lysines, which are the sites of PEG-conjugation. Multiple MALDI determinations of two batches of samples indicated good reproducibility for routine determination of the extent of polymer content. The amount of PEG-conjugated SOD that contained a given number of PEG molecules, determined by MALDI, was compared with the value deduced from the amount of PEG-conjugation at each attachment site measured by a peptide mapping method. Agreement between the data obtained in the two techniques (MALDI and peptide mapping) indicates that MALDI may be used to obtain quantitative information on PEG-conjugated SOD to determine the amounts of PEG-conjugated protein each with a different number of PEG groups attached. Measurement of several batches of samples stored at a higher temperature showed a lower extent of PEG-conjugation in PEG-conjugated SOD. This reduction in the PEG content resulted from the PEG-deconjugation of PEG-conjugated SOD at a higher temperature. Thus, MALDI can be used to examine the stability of PEG-conjugated SOD. The high sensitivity, relatively straightforward data interpretation, speed of analyses, and good reproducibility in measurements make this technique a useful analytical tool for fingerprinting PEG-conjugated SOD as well as potentially other polymer-conjugated proteins. 相似文献