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21.
22.
The review summarizes the results of the recent author’s research on the synthesis of triple-decker complexes with bridging
borole ligand. Electrophilic stacking of sandwich compounds with [(ring)M]
n+ (n = 1, (ring)M = (C5R5)Ru, (C4Me4)Co; n = 2, (ring)M = Cp*Co, Cp*Rh, etc.) cationic fragments were used as a general method of synthesis of the complexes. The influence of the substituent at the
boron atom on the course of stacking reactions is discussed. The spectral, structural, and electrochemical properties of the
complexes synthesized are also considered.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 1–7, January, 2008. 相似文献
23.
D. G. Muratov L. V. Kozhitov A. V. Popkova 《Russian Journal of Inorganic Chemistry》2016,61(10):1312-1320
Metal–carbon nanocomposites that represent FeCo alloy nanoparticles uniformly distributed over the carbon matrix, were prepared by the IR pyrolysis of precursors comprising polyacrylonitrile (PAN), iron acetylacetonate, and cobalt acetate (the metal ratio in the precursors was Fe: Co = 1: 1, 3: 1). The composition of FeCo alloy nanoparticles satisfies the tailored ratio Fe: Co. The FeCo phase is formed at synthesis temperatures in the range 500–600°С; at T ≤ 500°С only FCC-Co-base solid solutions are observed. The nanocomposites prepared at T ≥ 600°С simultaneously contain FeCo intermetallic nanoparticles and an insignificant amount of a FCC-Co phase or a cobalt-base solid solution phase. The saturation magnetization of FeCo/C metal–carbon nanocomposites is determined by the mean nanoparticle size and the alloy composition, and ranges from 36 to 64 (A m2)/kg (when Fe: Co = 1: 1) and from 35 to 52 (A m2)/kg (when Fe: Co = 3: 1) at synthesis temperatures in the range 600–800°С. 相似文献
24.
E. A. Azizov S. S. Ananyev V. A. Belyakov E. N. Bondarchuk A. A. Voronova A. A. Golikov P. R. Goncharov A. Yu. Dnestrovskij E. R. Zapretilina D. P. Ivanov A. A. Kavin I. V. Kedrov A. V. Klischenko B. N. Kolbasov S. V. Krasnov A. I. Krylov V. A. Krylov E. G. Kuzmin B. V. Kuteev A. N. Labusov V. E. Lukash I. I. Maximova S. Yu. Medvedev A. B. Mineev V. P. Muratov V. S. Petrov I. Yu. Rodin V. Yu. Sergeev A. V. Spitsyn V. N. Tanchuk V. A. Trofimov R. R. Khayrutdinov M. V. Khokhlov Yu. S. Shpanskiy 《Physics of Atomic Nuclei》2016,79(7):1125-1136
The level of knowledge accumulated to date in the physics and technologies of controlled thermonuclear fusion (CTF) makes it possible to begin designing fusion—fission hybrid systems that would involve a fusion neutron source (FNS) and which would admit employment for the production of fissile materials and for the transmutation of spent nuclear fuel. Modern Russian strategies for CTF development plan the construction to 2023 of tokamak-based demonstration hybrid FNS for implementing steady-state plasma burning, testing hybrid blankets, and evolving nuclear technologies. Work on designing the DEMO-FNS facility is still in its infancy. The Efremov Institute began designing its magnet system and vacuum chamber, while the Kurchatov Institute developed plasma-physics design aspects and determined basic parameters of the facility. The major radius of the plasma in the DEMO-FNS facility is R = 2.75 m, while its minor radius is a = 1 m; the plasma elongation is k 95 = 2. The fusion power is P FUS = 40 MW. The toroidal magnetic field on the plasma-filament axis is B t0 = 5 T. The plasma current is I p = 5 MA. The application of superconductors in the magnet system permits drastically reducing the power consumed by its magnets but requires arranging a thick radiation shield between the plasma and magnet system. The central solenoid, toroidal-field coils, and poloidal-field coils are manufactured from, respectively, Nb3Sn, NbTi and Nb3Sn, and NbTi. The vacuum chamber is a double-wall vessel. The space between the walls manufactured from 316L austenitic steel is filled with an iron—water radiation shield (70% of stainless steel and 30% of water). 相似文献
25.
Recently, it was shown that the neutral shadowing force can have a strong impact on the structural properties of the charged dust particles in cryogenic dusty plasmas. Therefore, in this work, we have investigated the impact of the neutral shadowing force on the dynamical properties by means of molecular dynamics simulations. By computing the velocity auto‐correlation function of particles and their spectrum, we found that the neutral shadowing force has a strong impact on the dust particle dynamics if the mean free path of neutrals exceeds the mean inter‐dust particle distance. 相似文献
26.
A. S. Romanov D. V. Muratov P. V. Petrovskii M. Yu. Antipin W. Siebert A. R. Kudinov 《Russian Chemical Bulletin》2009,58(3):594-599
The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]- (1) with the halide complexes [CpMI2]2 or [Cp*MCl2]2 (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal—diborolyl bond in these complexes was analyzed using the energy
decomposition scheme. 相似文献
27.
D. V. Muratov A. S. Romanov P. V. Petrovskii M. Yu. Antipin A. R. Kudinov 《Russian Chemical Bulletin》2009,58(5):964-967
Cationic triple-decker complexes [CpCo(1,3-C3B2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sand-wich anion [CpCo(1,3-C3B2Me5)]− (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis. 相似文献
28.
A general mechanism is proposed by which small intrinsic fluctuations in a system far from equilibrium can result in nearly deterministic dynamical behaviors which are markedly distinct from those realized in the meanfield limit. The mechanism is demonstrated for the kinetic Monte Carlo version of the Schnakenberg reaction where we identified a scaling limit in which the global deterministic bifurcation picture is fundamentally altered by fluctuations. Numerical simulations of the model are found to be in quantitative agreement with theoretical predictions. 相似文献
29.
Yu. A. Aleshchenko A. V. Muratov V. V. Pavlova Yu. G. Selivanov E. G. Chizhevskii 《JETP Letters》2014,99(4):187-190
The infrared reflection and transmission spectra of Bi2Te2Se single crystals grown by the modified Bridgeman method have been studied in the spectral range of 30–10000 cm?1 at temperatures of 5–300 K. The bandgap and its temperature dependence, optical function spectra, and concentration of free charge carriers in Bi2Te2Se have been determined. 相似文献
30.
D. V. Leybo D. V. Kuznetsov D. S. Muratov A. G. Yudin 《Moscow University Chemistry Bulletin》2012,67(6):270-274
Ni-Mo powders produced by ultrasonic spray pyrolysis and chemical deposition are comparing in this study. Specimens were investigated by low-temperature nitrogen adsorption, x-ray diffraction, x-ray fluorescence, scanning and transmission electron microscopy methods. It was shown that the composition of the two-phase material, produced by ultrasonic spray pyrolysis method, is easy to control. Powders have spherical shape and high specific surface area. 相似文献