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排序方式: 共有229条查询结果,搜索用时 281 毫秒
21.
Xiaodi Wang Ying Ma Abhilash Sugunan Jian Qin Muhammet S. Toprak Bin Zhu Mamoun Muhammed 《Journal of nanoparticle research》2011,13(11):5879-5885
A facile surfactant-free nonaqueous method is presented to prepare uniform quasi-octahedral ceria, CeO2, mesocrystals, in which only Ce(NO3)3 and octanol were used as the reactants at a reaction temperature of 150 °C. CeO2 sample synthesized using this technique consists of well-dispersed quasi-octahedrons and exhibits an uniform size and morphology.
Based on structural characterization, it is proposed that the CeO2 mesostructure was formed by self-assembly of primary nanocrystals based on unique 3D oriented-attachment mechanism. Optical
characterization exhibited a strong quantum confinement, revealing small size of primary nanocrystals. The thermal stability
and UV–Vis study reveal CeO2 mesocrystal has various potential for high temperature applications and optical apparatus applications. 相似文献
22.
We give a classification of sphere quadrangulations satisfying a condition of non‐negative curvature, following Thurston's classification of sphere triangulations under the same condition. The generic family of quadrangulations is parametrized by the points of positive square‐norm of an integral Gaußian lattice in the six‐dimensional complex Lorentz space. There is a subgroup of automorphisms of acting on this lattice whose orbits parametrize sphere quadrangulations in a one‐to‐one manner. This group acts discretely on the corresponding five‐dimensional complex hyperbolic space; is of finite co‐volume; its ball quotient is the moduli space of unordered 8 points on the Riemann sphere, and also appears in Picard‐Terada‐Deligne‐Mostow list. Both Thurston's lattice and our lattice may be thought of as parametrizations of certain families of subgroups of the modular group; equivalently, of certain families of dessins. These families also parametrize points of a moduli space. 相似文献
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24.
Cover Picture: Intracellular Modulation of Excited‐State Dynamics in a Chromophore Dyad: Differential Enhancement of Photocytotoxicity Targeting Cancer Cells (Angew. Chem. Int. Ed. 18/2015)
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Muhammed Üçüncü Erman Karakuş Prof. Dr. Mustafa Emrullahoğlu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(38):13201-13205
A fluorescent probe that displays a ratiometric fluorescence response towards gold and mercury ions has been devised. Emitting at a relatively longer wavelength, the conjugated form of the fluorescent dye transforms in the presence of the gold or mercury ions into a new dye, the molecular structure of which lacks the conjugation and consequently emits at a distinctly shorter wavelength. 相似文献
27.
Dias HV Flores JA Pellei M Morresi B Lobbia GG Singh S Kobayashi Y Yousufuddin M Santini C 《Dalton transactions (Cambridge, England : 2003)》2011,40(34):8569-8580
Synthesis of the perfluorinated 1,3,5-triazapentadiene [N{(CF(3))C(C(6)F(5))N}(2)]H and the use of its conjugate base as a supporting ligand for the isolation of silver(i) and copper(i) complexes are reported. Some of the related chemistry involving [N{(C(3)F(7))C(C(6)F(5))N}(2)](-) (that has bulkier -C(3)F(7) groups on the 1,3,5-triazapentadienyl ligand backbone) is also presented. X-ray crystallographic data show a wide variety of structures ranging from intermolecular, hydrogen-bonded chain structure for [N{(CF(3))C(C(6)F(5))N}(2)]H with a twisted W-shaped N(3)C(2) core, monomeric [N{(CF(3))C(C(6)F(5))N}(2)]Ag(CN(t)Bu)(2) and [N{(C(3)F(7))C(C(6)F(5))N}(2)]Ag(CN(t)Bu)(2) where the κ(1)-bonded triazapentadienyl ligand bonding to the metal fragment via the central nitrogen atom, monomeric [N{(CF(3))C(C(6)F(5))N}(2)]Ag(PPh(3))(2) and [N{(C(3)F(7))C(C(6)F(5))N}(2)]Ag(PPh(3))(2) that feature κ(1)-bonded triazapentadienyl ligand bonding to the metal fragment via one of the terminal nitrogen atoms, to that of the monomeric [N{(CF(3))C(C(6)F(5))N}(2)]Cu(CN(t)Bu)(2) containing a κ(2)-bonded triazapentadienyl ligand and a U-shaped NCNCN ligand backbone. The isocyanide adducts show relatively high ν(CN) values in the IR spectra. 相似文献
28.
An exploration of imidazolylpropargyl amides as linchpin synthons for the construction of a diverse array of heterocyclic frameworks, many of which are related to those found in the oroidin derived alkaloids, is described. One such intermediate has been used in a formal total synthesis of cyclooroidin. 相似文献
29.
A cationic gold carbonyl complex has been synthesized and characterized using several techniques including X-ray crystallography. [(Mes(3)P)Au(CO)][SbF(6)] (Mes = 2,4,6-Me(3)C(6)H(2)) has a linear, two-coordinate gold atom. This compound displays the CO stretching frequency at 2185 cm(-1). The (13)C NMR signal of the gold-bound (13)CO appears as a doublet centered at δ 182.6 ((2)J(C,P) = 115 Hz). A computational study shows that the Au-CO bond consists of electrostatic attraction, Au ← CO donation, and significant Au → CO π-back-bonding components. Polarization of the CO bond caused by the electrostatic effect of the cationic gold center is mainly responsible for the large blue shift in the CO stretching frequency. 相似文献
30.
Üçüncü M Karakuş E Kuş M Akpınar GE Aksın-Artok Ö Krause N Karaca S Elmacı N Artok L 《The Journal of organic chemistry》2011,76(15):5959-5971
Two methods involving the rhodium-catalyzed reaction of 2-en-4-yne acetates and the palladium-catalyzed reaction of 2-en-4-yne carbonates with organoboronic acids were investigated; both afforded exclusively the (E)-configured vinylallenes. The coordinative interaction of the rhodium with the acetate group promoted the δ-elimination of Rh(I)-OAc from the alkenylrhodium intermediate II in both syn and anti modes, with the syn-elimination being the major path. DFT calculations revealed that a conformer of this intermediate (II), which can lead to the (E)-configured vinylallene product via the syn-elimination mode, is energetically the most favorable conformer. The rhodium-catalyzed procedure is not applicable to reactions involving (E)-configured enyne acetates, because the geometry of the alkenylrhodium intermediate that is derived from the corresponding (E)-enyne acetate would not allow such coordinative interaction to occur. The palladium-catalyzed method, which proceeds through formation of the σ-vinylallenylpalladium intermediate, B, is suitable for both the (E)- and (Z)-configured enyne carbonates and appears to have a wider scope for both organoboronic acids and enyne substrates. The palladium-catalyzed reaction of an enantiomerically enriched enyne carbonate proceeded with racemization. 相似文献