全文获取类型
收费全文 | 2224篇 |
免费 | 91篇 |
国内免费 | 16篇 |
专业分类
化学 | 1394篇 |
晶体学 | 21篇 |
力学 | 111篇 |
数学 | 210篇 |
物理学 | 595篇 |
出版年
2023年 | 17篇 |
2022年 | 24篇 |
2021年 | 33篇 |
2020年 | 29篇 |
2019年 | 26篇 |
2018年 | 33篇 |
2017年 | 28篇 |
2016年 | 54篇 |
2015年 | 66篇 |
2014年 | 91篇 |
2013年 | 101篇 |
2012年 | 171篇 |
2011年 | 195篇 |
2010年 | 125篇 |
2009年 | 125篇 |
2008年 | 132篇 |
2007年 | 125篇 |
2006年 | 122篇 |
2005年 | 102篇 |
2004年 | 74篇 |
2003年 | 79篇 |
2002年 | 49篇 |
2001年 | 47篇 |
2000年 | 45篇 |
1999年 | 28篇 |
1998年 | 25篇 |
1997年 | 22篇 |
1996年 | 29篇 |
1995年 | 31篇 |
1994年 | 16篇 |
1993年 | 26篇 |
1992年 | 29篇 |
1991年 | 24篇 |
1990年 | 15篇 |
1989年 | 23篇 |
1988年 | 23篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 13篇 |
1984年 | 10篇 |
1983年 | 13篇 |
1982年 | 8篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 10篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 11篇 |
1973年 | 10篇 |
排序方式: 共有2331条查询结果,搜索用时 15 毫秒
951.
952.
953.
Yang Tsung-Yeh Wu Chung-Yi Tsai Meng-Hung Lin Hong-Ming Tsai Wen-Li Hwu Yeukuang 《Journal of nanoparticle research》2004,6(2):171-179
Tungsten oxide nanoparticles are prepared by evaporating and oxidizing the tungsten boat in helium and oxygen atmosphere and then quenched to the liquid nitrogen temperature. The as-prepared tungsten oxide nanoparticles are porous-free with uniform size. The morphology and particle size distribution of the as-prepared and after sinter treatments tungsten oxide nanoparticles are revealed by TEM and AFM. The long-range order of these nanoparticles can be examined by X-ray diffraction technique. The as-prepared nanoparticles exhibit a mixture structure of monoclinic and hexagonal crystals. Preliminary X-ray diffraction results indicate that the hexagonal structure is transformed to monoclinic structure after annealing to above 600°C. In order to better distinguish the structural properties of the tungsten oxide (WO3−
x) nanoparticles before and after annealing, the X-ray absorption spectrum technique is utilized; thus, the detailed local atomic arrangement of oxygen and/or tungsten can be determined. According to the XAS result, the shape of the W L3-edge undergoes no considerable changes. This infers that structural transformation of tungsten oxide nanoparticle may be caused by the migration of oxygen after sintering. From the O K-edge of absorption spectrum, it suggests that a mixture phase structure is obtained when sintered below 300°C. And this result indicates that heat treatment to approximately 600°C produces a stable structure of a monoclinic crystal of WO3. 相似文献
954.
T. S. Argunova L. M. Sorokin B. Z. Pevzner V. S. Balitskii M. A. Gannibal J. H. Je Y. Hwu W. -L. Tsai 《Physics of the Solid State》2003,45(10):1910-1917
The solubility and diffusion of helium in quartz crystals are investigated as functions of the distribution and density of structural defects. The types of defects in the crystals are identified and their distribution over growth sectors is determined by x-ray diffraction topography and phase radiography with a synchrotron radiation source. The effective solubility and effective diffusion coefficients for helium in quartz are estimated from the experimental data on the amount of helium extracted from samples with different contents of defects. It is revealed that the effective diffusion coefficient of helium depends on the number of dislocations. 相似文献
955.
Complexation between vanadium(V) and citrate: spectroscopic and structural characterization of a dinuclear vanadium(V) complex 总被引:1,自引:0,他引:1
Zhou Zhao-Hui Zhang Hui Jiang Ya-Qi Lin Dong-Hai Wan Hui-Lin Tsai Khi-Rui 《Transition Metal Chemistry》1999,24(5):605-609
Investigation of the aqueous coordination chemistry for citrate and vanadium(V) resulted in the isolation and characterization of a dinuclear vanadium(V) citrato complex (1) Na2K2[VO2(Hcit)]2 · 9H2O. Complex (1) is an intermediate between the fully deprotonated and diprotonated citrate vanadate. It may represent an early mobilized precursor in the biosynthesis of FeV-co, as well as a relevant model in the proton transport relay process between P-cluster pair to M-cluster pair. The complex has been characterized by elemental analyses and i.r. spectroscopy. Its i.r. spectra are consistent with a oxo-bridged dinuclear structure as revealed by a single crystal X-ray diffraction study. 相似文献
956.
Kelly-Wintenberg K. Sherman D.M. Tsai P.P.-Y. Gadri R.B. Karakaya F. Zhiyu Chen Roth J.R. Montie T.C. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2000,28(1):64-71
Two characteristics of microorganisms-extremely small size (0.01 to a few micrometers) and the ability to reproduce-hinder the effective filtration of bacteria and viruses from indoor air. The microorganisms captured by a filter in spite of their small size can reproduce in situ and be released into the airstream, giving rise to the “sick building syndrome”. The application of the One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) to a filter can address both these issues. At University of Tennessee at Knoxville, we have recently developed the “Volfilter”, a planar version of the OAUGDP produced by attaching strip electrodes to both sides of a sheet of dielectric filter material and energizing the electrodes with a high-voltage, low-frequency RF source. After the filter material removes microorganisms from the airstream, the OAUGD plasma kills the captured microorganisms. The combination of an appropriate filter material and periodic application of the OAUGDP results in an effective capture and sterilization device even for the smallest microorganisms and requires minimum maintenance. This paper will describe results obtained during the operation of a laboratory-scale “Volfilter” challenged by two kinds of microorganisms, S. aureus and the bacterial virus Phi X 174. An objective of this work is to demonstrate that a “Volfilter” exposed to a OAUGDP will have the number of captured microorganisms on its surface reduced by a factor of one million 相似文献
957.
Polyaniline has been synthesized by the chemical and electrochemical oxidation of aniline. The conductivities increase by seven order of magnitude upon protonation. The IR absorption band near 1590 cm?1 shifts to a lower frequency upon protonation. Visible spectra vary with the degree of protonation and the applied potential. Cyclic voltammetry indicates that polyaniline exists in several forms. 相似文献
958.
Owing to a recent controversy over the importance of the second-order quantum corrections to the power spectrum of synchrotron radiation, we here reexamine this question by using a proper time method to calculate the forward Compton scattering of a real photon on a spin-0 charged particle in external magnetic fields. This approach, aside from being the simplest method found so far, has the feature that it resembles the classical procedure so that the quantum corrections can be identified at every stage of the computation. The option of being able to perform first the angular integration before doing the proper time integral enables us to simplify the calculation and to obtain the quantum corrections unambiguously. We find that the criterion for the quantum corrections to be important is the same as that found more than two decades ago. 相似文献
959.
Twenty three compounds were isolated from the bark of Pinus armandii. These compounds include nine serratenes (1-9), a norserratenone 10, eight phenols 11-18, two flavonoids 19-20, one lignan 21, a diterpene 22 and a novel triterpendiol acetonide 23. Their structures were determined from their physical and spectral properties. 相似文献
960.
The effect of ultrasonic waves propagating at an angle ? relative to the direction of a magnetic field in nondegenerate semiconductors such as n-type InSb has been studied by using a quantum treatment which is valid at high frequencies and in strong magnetic fields. Numerical results show that both the absorption coefficient and the change in the sound velocity depend on the direction of the propagation of ultrasonic waves relative to the magnetic field. 相似文献