禽肉中克球酚气相色谱微量快速测定法

对禽肉样品中克球酚药物残留采用微量化学法技术，以甲醇提取，氧化铝、阴离子树脂交换柱净化，乙酰化后，进行ＧＣ－ＥＣＤ毛细管色谱测定。经对肉鸡、填鸭、饲养山鸡进行添加回收率试验，方法回收率为８５．７％～９４．４％，变异系数为３．８％～７．７％，最低检出限为２．０ｎｇ／ｇ。     

175Er的衰变纲图

用14MeV中子照射天然Yb靶,通过¹⁷⁶Yb(n,2p)¹⁷⁵Er反应产生了新的重丰中子同位素¹⁷⁵Er,借助X-γ,γ-γ符合测量方法,首次鉴别出了¹⁷⁵Er,并测得其半衰期为(1.2±0.3)min.同时还观察到了¹⁷⁵Er衰变所发射的8条新γ射线,建立了¹⁷⁵Er的部分γ衰变纲图,从中指定了¹⁷⁵Tm的一个基态转动带.     

金水六君煎胶囊多指标成分分析

采用薄层扫描法、紫外分光光度法分别对金水六君煎胶囊中有祛痰作用的β-谷甾醇和总生物碱进行含量测定。 β-谷甾醇平均回收率为 10 0 .6 % (n=5 ) ,RSD为 2 .77% ;总生物碱平均回收率为 98.4 %(n=5 ) ,RSD为 2 .16 %。该方法简单快速、结果准确、精密度较高 ,可用于该制剂的质量控制。     

Thermal Diffusion with Chemical Reaction: A Carrier System

The heat of transport of oxygen across a membrane mediated by hemoglobin (Hb) as a carrier is iuvestigated by the method of irreversible thermodynamics. It is assumed that oxygen combines with hemoglobin molecules to form oxyhemoglobin according to the reaction nO₂ + Hb=HbO_zn. The oxyhemoglobin molecule HbO_zn then migrates to a new position and is reconverted to Hb by releasing oxygen. It is shown that the heat of transport of oxygen consists of two contributions; one due to the reaction and the other from thermal diffusion of individual species present. Total oxygen flux across the membrane is also calculated in terms of temperature and the chemical potential difference of oxygen across the membrane. The use of the heat of transport as a measure of the efficiency of the heat pump for the carrier-mediated transport process is investigated.     

Coherent structures of the turbulent round jet in different focal lengths

Graphical abstract  

     

The number of nonseparable maps on the projective plane

In this paper, we study the rooted nonseparable maps on the sphere and the projective plane with the valency of root-face and the number of edges as parameters. Explicit expression of enumerating functions are obtained for such maps on the sphere and the projective plane. A parametric expression of the generating function is obtained for such maps on the projective plane, from which asymptotic evaluations are derived. Moreover, if the number of edges is sufficiently large, then almost all nonseparable maps on the projective plane are not triangulation.     

Spin-dependent negative differential conductance in transport through single-molecule magnets

Transport properties are theoretically studied through an anisotropy single-molecule magnet symmetrically connected to two identical ferromagnetic leads. It is found that even though in parallel configuration of leads’ magnetizations, the total current still greatly depends on the spin polarization of leads at certain particular bias region, and thus for large polarization a prominent negative differential conductance (NDC) emerges. This originates from the joint effect of single-direction transitions and spin polarization, which removes the symmetry between spin-up and spin-down transitions. The present mechanism of NDC is remarkably different from the previously reported mechanisms. To clarify the physics of the NDC, we further monitored the shot noise spectroscopy and found that the appearance of the NDC is accompanied by the rapid decrease of Fano factor.     

Carbene‐Catalyzed Desymmetrization and Direct Construction of Arenes with All‐Carbon Quaternary Chiral Center

Multisubstituted arenes such as indanes with attached all‐carbon quaternary centers are unique scaffolds in synthetic functional molecules and sophisticated natural products. A key challenge in preparing such molecules lies in the enantioselective installation of the quaternary carbon centers. Conventional methods in this direction include asymmetric substitution reactions and substrate‐controlled cyclization reactions. These reactions lead to poor stereoselectivities and/or require long and tedious synthetic steps. Disclosed here is a one‐step organic catalytic strategy for enantioselective access to this class of molecules. The reaction involves an N‐heterocyclic carbene catalyzed process for direct benzene construction, indane formation, remote‐carbon desymmetrization, and excellent chirality control. This approach will enable the concise synthesis of arene‐containing molecules, including those with complex structures and challenging chiral centers.     

A Crosslinked Nucleic Acid Nanogel for Effective siRNA Delivery and Antitumor Therapy

Functional siRNAs are employed as cross‐linkers to direct the self‐assembly of DNA‐grafted polycaprolactone (DNA‐g‐PCL) brushes to form spherical and nanosized hydrogels via nucleic acid hybridization in which small interfering RNAs (siRNAs) are fully embedded and protected for systemic delivery. Owing to the existence of multivalent mutual crosslinking events inside, the crosslinked nanogels with tunable size exhibit not only good thermostability, but also remarkable physiological stability that can resist the enzymatic degradation. As a novel siRNA delivery system with spherical nucleic acid (SNA) architecture, the crosslinked nanogels can assist the delivery of siRNAs into different cells without any transfection agents and achieve the gene silencing effectively both in vitro and in vivo, through which a significant inhibition of tumor growth is realized in the anticancer treatment.