Solvent density effects on the solvation behavior and configurational structure of bare and passivated 38-atom gold nanoparticle in supercritical ethane

In exploring the effects of solvent density on the mode and the degree of solvation of the bare and passivated 38-atom gold particle in supercritical ethane, we have extended the molecular dynamics simulations of the system, reported previously,(34) to cover a range of isotherms in the T > T(c) regime, where T(c) is the critical temperature of the solvent. Consonant with our previous observations, the modes of solvation of the bare and the passivated particle, deduced from the radial distribution of the solvent about the metal core center of mass, are found to be vastly different from each other at all solvent densities: while the molecules solvating the bare particle form a well-defined, two-region layer around it, those solvating the passivated particle are loosely dispersed in the passivating layer. For the bare particle, the degree of solvation (vartheta) as a function of solvent density passes through a maximum occurring in the close vicinity of the critical point, consistent with our previous results and in agreement with Debenedetti's theoretical analysis,(22,23) which predicts a solvation enhancement effect in the critical region for systems where the unlike solvent/solute interaction is much stronger than the solvent/solvent interaction. Taking the degree of solvation (vartheta) as a measure of solvent quality, we have investigated how the solvent quality would vary along the solvent-density isotherms. In the solvent-density regime rho > rho(c), the solvent quality is found to be a decreasing function of the density as a result of progressive dominance of the excluded volume effect over the attractive particle/solvent interactions. The particle/solvent affinity is greatly reduced in the presence of the passivating layer, resulting in considerable shrinkage of the good-solvent-quality domain in the supercritical regime. The solvent environment and the presence of the passivating chains produce significant disorder in the equilibrium structure assumed by the nanoparticle core.     

Phase locking and coherent combining of high-order-mode fiber lasers

Efficient free-space configurations for phase locking and coherent addition of two fiber lasers, each operating with a high-order mode, are presented. Experimental results reveal that when the two fiber lasers are coupled, the polarization and modal distribution of one are imposed on the other. Coherent addition with a combining efficiency larger than 90% was achieved.     

Coherent addition of two dimensional array of fiber lasers

Configurations for efficient free space coherent addition of four separate fiber lasers arranged in two dimensional array are presented. They include compact and robust interferometric combiners that can be inserted either inside or outside the cavity of the combined lasers system. The results reveal that over 85% combining efficiency can be obtained.     

Effect of 100 MeV O7+ ion beam irradiation on structural,optical and electronic properties of SnO2 thin films

In this paper, we present the impact of swift heavy ion beam irradiation on the structural, optical and electronic properties of SnO₂ thin films. Thin films were deposited using the pulsed laser deposition technique on Al₂O₃ substrates. Atomic force microscopy, X-ray diffraction, UV–visible absorption and temperature-dependent resistivity measurements were performed to explore the morphological, structural, optical and electronic properties of the as-deposited and irradiated samples. The peak intensity of the (200) peak was found to decrease monotonously with increasing irradiation fluence. The band gap energy of the 1×10¹¹ ion/cm² irradiated sample was found to increase. The electrical resistivity of the samples showed a continuous increase with the irradiation fluence.     

Discrimination of complex synthetic echoes by an echolocating bottlenose dolphin

Bottlenose dolphins (Tursiops truncatus) detect and discriminate underwater objects by interrogating the environment with their native echolocation capabilities. Study of dolphins' ability to detect complex (multihighlight) signals in noise suggest echolocation object detection using an approximate 265-micros energy integration time window sensitive to the echo region of highest energy or containing the highlight with highest energy. Backscatter from many real objects contains multiple highlights, distributed over multiple integration windows and with varying amplitude relationships. This study used synthetic echoes with complex highlight structures to test whether high-amplitude initial highlights would interfere with discrimination of low-amplitude trailing highlights. A dolphin was trained to discriminate two-highlight synthetic echoes using differences in the center frequencies of the second highlights. The energy ratio (delta dB) and the timing relationship (delta T) between the first and second highlights were manipulated. An iso-sensitivity function was derived using a factorial design testing delta dB at -10, -15, -20, and -25 dB and delta T at 10, 20, 40, and 80 micros. The results suggest that the animal processed multiple echo highlights as separable analyzable features in the discrimination task, perhaps perceived through differences in spectral rippling across the duration of the echoes.     

Aerobic oxidation of benzylic alcohols with solid alkaline metal hydroxides

Solid alkaline metal hydroxides displayed high catalytic activity and full selectivity in the aerobic oxidation of benzylic alcohols in a non-polar medium. The activity of the solid bases, in decreasing order of reactivity, was KOH > NaOH ≫ LiOH. Water, which is the only by-product of the reaction, plays a crucial role in KOH deactivation by converting the crystal phase of KOH to KOH · H₂O, as confirmed by XRD measurements.     

On almost precipitous ideals

With less than 0^# two generic extensions ofL are identified: one in which ${\aleph_1}With less than 0^# two generic extensions ofL are identified: one in which à₁{\aleph_1}, and the other à₂{\aleph_2}, is almost precipitous. This improves the consistency strength upper bound of almost precipitousness obtained in Gitik M, Magidor M (On partialy wellfounded generic ultrapowers, in Pillars of Computer Science, 2010), and answers some questions raised there. Also, main results of Gitik (On normal precipitous ideals, 2010), are generalized—assumptions on precipitousness are replaced by those on ∞-semi precipitousness. As an application it is shown that if δ is a Woodin cardinal and there is an f:w₁ ? w₁{f:\omega_1 \to \omega_1} with ||f||=w₂{\|f\|=\omega_2}, then after Col(à₂,d){Col(\aleph_2,\delta)} there is a normal precipitous ideal over à₁{\aleph_1}. The existence of a pseudo-precipitous ideal over a successor cardinal is shown to give an inner model with a strong cardinal.     

Hydrostatic pressure effects on the magnetic susceptibility of ruthenium oxide Sr3Ru2O7: evidence for pressure-enhanced antiferromagnetic instability

Hydrostatic pressure effects on the temperature- and magnetic field dependencies of the in-plane and out-of-plane magnetization of the bi-layered perovskite Sr₃Ru₂O₇ have been studied by SQUID magnetometer measurements under a hydrostatic helium-gas pressure. The anomalously enhanced low-temperature value of the paramagnetic susceptibility has been found to systematically decrease with increasing pressure. The effect is accompanied by an increase of the temperature T_max of a pronounced peak of susceptibility. Thus, magnetization measurements under hydrostatic pressure reveal that the lattice contraction in the structure of Sr₃Ru₂O₇ promotes antiferromagnetism and not ferromagnetism. The effects can be explained by the enhancement of the inter-bi-layer antiferromagnetic spin coupling, driven by the shortening of the superexchange path, and suppression, due to the band-broadening effect, of competing itinerant ferromagnetic correlations.     

The least weakly compact cardinal can be unfoldable,weakly measurable and nearly $${\theta}$$-supercompact

We prove from suitable large cardinal hypotheses that the least weakly compact cardinal can be unfoldable, weakly measurable and even nearly \({\theta}\)-supercompact, for any desired \({\theta}\). In addition, we prove several global results showing how the entire class of weakly compactcardinals, a proper class, can be made to coincide with the class of unfoldable cardinals, with the class of weakly measurable cardinals or with the class of nearly \({\theta_\kappa}\)-supercompact cardinals \({\kappa}\), for nearly any desired function \({\kappa\mapsto\theta_\kappa}\). These results answer several questions that had been open in the literature and extend to these large cardinals the identity-crises phenomenon, first identified by Magidor with the strongly compact cardinals.     

Total Synthesis of (+)‐6‐epi‐Ophiobolin A

The ophiobolin sesterterpenes are notable plant pathogens which have recently elicited significant chemical and biological attention because of their intriguing carbogenic frameworks, reactive functionalities, and emerging anticancer profiles. Reported herein is a total synthesis of (+)‐6‐epi‐ophiobolin A in 14 steps, a task which addresses construction of the synthetically challenging spirocyclic tetrahydrofuran motif as well as several other key stereochemical problems. This work demonstrates a streamlined synthetic platform to complex ophiobolins leveraging disparate termination modes of a radical polycyclization cascade for divergent elaboration and functionalization.