Preparation,characterization and catalytic applications of ZrO<Subscript>2</Subscript> supported on low cost SBA-15

This work presents some applications of ZrO₂ supported over SBA-15 silica as promoter of sulfated zirconia and as support from CuO/CeO₂ catalytic system for preferential oxidation of CO to CO₂ in hydrogen rich streams, used as feed for proton exchange membrane fuel cells (PEMFC). Different amounts of ZrO₂, from 10 to 30 wt.% were incorporated. These prepared materials were characterized by powder XRD, adsorption-desorption of N₂ at 77 K, transmission and scanning electron microscopy (TEM and SEM) and X-rays photoelectron spectroscopy (XPS). The acidity was studied by thermo-programmed desorption of ammonia (NH₃-TPD). These materials were tested, after treatment with H₂SO₄, by 2-propanol dehydration and 1-butene isomerization catalytic tests. The samples were found quite good catalyst with strong acid sites, the sample with 20 wt.% of ZrO₂ being the better performing sample. Finally this material was successfully used as support for a CuO/CeO₂ system, with 6 wt.% of Cu and 20 wt.% of Ce. The resulting catalyst was tested in the preferential oxidation of CO (CO-PROX) attaining conversions close to 100% and high selectivity to CO₂.     

How to embed three-dimensional flexible electrodes in microfluidic devices for cell culture applications

This communication describes a simple, rapid and cost effective method of embedding a conductive and flexible material within microfluidic devices as a means to realize uniform electric fields within cellular microenvironments. Fluidic channels and electrodes are fabricated by traditional soft-lithography in conjunction with chemical etching of PDMS. Devices can be deformable (thus allowing for a combination of electro-mechanical stimulation), they are made from inexpensive materials and easily assembled by hand; this method is thus accessible to a wide range of laboratories and budgets.     

FIR spectroscopy of ethyl bromide and trioxane: New laser transitions and assignments

Eight new optically pumped far infrared laser transitions from ethyl bromide and 22 from trioxane are presented. For each new line we give the wavelength, the polarization relative to that of the pump laser and the absorption offset relative to the CO₂ center frequency. The assignment of the rotovibrational states for the pump and the emission transitions of ethyl bromide are calculated. We also partly assigned the rotational levels of trioxane.     

Erratum to: “Weak corrections to gluon-induced top–antitop hadro-production” [Phys. Lett. B 639 (2006) 513]

This is an Erratum to a Letter of ours [S. Moretti, M.R. Nolten, D.A. Ross, Phys. Lett. B 639 (2006) 513]. After its publication, we have discovered a mistake in a numerical program that affects the results presented therein. We provide here the corrected version.     

Electron microscopic study of dendritic growths on the anode during prebreakdown conditions in an organic residual gas

Anodic growths on tungsten electrodes as a result of an applied electrostatic field with an atmosphere of benzonitrile (from about 5 × 10^?4 to 10^?5 torr) are studied as a function of many parameters. In order to observe the growth phenomena at high resolution in situ, the experiments were performed in an electron microscope. The growth rate of the dendrites is found to be irregular; an expression for dependence on the electric field is proposed to explain the evolution of needle length versus time t: The mechanism of branching is also discussed.     

IR-FIR Transferred lamb-dip spectroscopy in optically pumped molecular lasers

Pump saturation effects are reported for CH₃ and CH₃F optically pumped molecular lasers. The Lamb-dip of the pumping transition is observed directly in the optoacoustic absorption signal and as a transferred Lamb-dip in the emission of various FIR laser lines (CH₃F 496 μm, CH₃OH 119, 70.5 and 96.5 μm) . The offset of the absorbing transitions and their Stark effect are directly investigated. Results are also reported for the unassigned CH₃OH 164 μm line.     

Study on the single crystal growth of concentration gradient Ce:YAP rod and the dopant concentration dependence on the scintillation properties

Micro-pulling down (μ-PD) method allows to prepare single crystals quickly and relatively inexpensively. Since it is a melt growth and taking into account segregation phenomena, the μ-PD method allows also to obtain single crystals characterized by dopant concentration gradients. Especially, taking the advantage of the grown crystal high aspect ratio, it allows to prepare crystalline samples with variable and wide range concentrations of dopants. These samples can help in understanding the correlation between dopant concentration and luminescence properties.     

Pair-produced heavy particle topologies: MSSM neutralino properties at the LHC from gluino/squark cascade decays

Processes of the form pp → anything → X_iX_j → + + notE are studied via a technique that may be viewed as an adaptation of time-honoured Dalitz plot analyses. X_i and X_j are new heavy states (with i, j =1, . . .,n), which may be identical or distinct; and and are necessarily distinct standard model (SM) fermion pairs whose invariant masses can be measured. A Dalitz-like plot of said invariant masses, versus , exhibits a topology connected to the masses and specific decay chains of X_i and X_j. Aside from relatively minor details, observed patterns consist of a collection of box and wedge shapes. This collection is model-dependent: comparison of the observed pattern to the possibilities for a specific model yields information on which new particle pair combinations are actually being produced, information beyond that extractable from conventional one-dimensional invariant mass distributions. The technique is illustrated via application to the minimal supersymmetric standard model (MSSM) process pp → → e⁺e^- + μ⁺μ^- notE. Here the heavy states are neutralinos (i = 2,3,4) - note that is excluded - which are produced in gluino/squark ( / ) cascade decay chains. Even with fairly modest expectations for the LHC performance during the first few years, this method still provides substantial insight into the neutralino mass spectrum and couplings if gluino/squark masses are relatively low (≃ 400 GeV). Arrival of the final proofs: 29 November 2005     

Generalized Complex Spherical Harmonics, Frame Functions, and Gleason Theorem

Consider a finite dimensional complex Hilbert space ${\mathcal{H}}$ , with ${dim(\mathcal{H}) \geq 3}$ , define ${\mathbb{S}(\mathcal{H}):= \{x\in \mathcal{H} \:|\: \|x\|=1\}}$ , and let ${\nu_\mathcal{H}}$ be the unique regular Borel positive measure invariant under the action of the unitary operators in ${\mathcal{H}}$ , with ${\nu_\mathcal{H}(\mathbb{S}(\mathcal{H}))=1}$ . We prove that if a complex frame function ${f : \mathbb{S}(\mathcal{H})\to \mathbb{C}}$ satisfies ${f \in \mathbb{L}^2(\mathbb{S}(\mathcal{H}), \nu_\mathcal{H})}$ , then it verifies Gleason’s statement: there is a unique linear operator ${A: \mathcal{H} \to \mathcal{H}}$ such that ${f(u) = \langle u| A u\rangle}$ for every ${u \in \mathbb{S}(\mathcal{H}).\,A}$ is Hermitean when f is real. No boundedness requirement is thus assumed on f a priori.