Optical spatial solitons

Optical and Quantum Electronics - It is almost common knowledge now that particles also possess properties of waves. But, can localized wave-packets behave and interact like particles? This article...     

Promotion of the fenton reaction by Cu2+ ions: Evidence for intermediates

The promotion of the Fenton reaction by Cu²⁺ ions has been investigated using a wide range of [Cu²⁺]. Both the disappearance of Fe²⁺ and the evolution of O₂ were followed as a function of time by quenching the reaction mixture with o‐phenanthroline or with excess Fe^{2 +} ions, respectively. Two series of experiments were performed. In one series [H₂O₂] was 5 × 10⁻⁴ mol dm⁻³, and in the other [H₂O₂] was reduced to 5 × 10⁻⁵ mol dm ⁻³. By stopping the reaction with excess Fe²⁺ ions, significant differences in the measured absorbance in the two series were observed. In the higher [H₂O₂] range, the absorbance decreased monotonically in time, due to O₂ formation during the reaction. In the lower range, an initial transient rise of the absorbance was observed, indicating the formation of spectroscopically distinct intermediates in the system. A mechanism involving the intermediates FeOCu⁴⁺ and FeOCu⁵⁺ has been set up. Rate constants of the mechanism have been determined. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 725–736, 2006     

Kinetics of aerobic and anaerobic oxidations of ethanol by Fenton's reagent

For the first time, the time dependence of [H₂O₂] and [Fe²⁺] was followed during the aerobic oxidation of ethanol by Fenton's reagent. It was found that part of the ethanol was oxidized by dissolved O₂ via the transient formation of H₂O₂. A model was set up based on FeO²⁺ as the key intermediate. Both one‐ and two‐equivalent oxidations of ethanol occur, the former producing radical species derived from ethanol. No free radicals derived from H₂O₂ play part in the system. The relevant rate constants or their ratios were determined. The mechanism accounted successfully also for the anaerobic oxidation of ethanol. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 40: 541–553, 2008     

Structure of 74Ge from the 72Ge(t,p) reaction

The reaction ⁷²Ge(t, p)⁷⁴Ge has been investigated with a 15 MeV triton beam. Fifty energy levels of ⁷⁴Ge were identified up to about 4.9 MeV excitation, eighteen of which were previously unreported. Angular distributions were measured and compared with DWBA calculations. Two low-lying states at 1.913 and 2.164 MeV have been assigned as J^π = 0⁺, corresponding to the 0₃⁺ and 0₄⁺ states in ⁷⁴Ge. The 4₂⁺ state has been located at 2.674 MeV, and the 2₄⁺ at 2.836 MeV. Many additional spin and parity assignments have been made. The ⁷⁴Ge nucleus shows a considerably different structure of 0⁺ states compared with the neighboring ⁷⁶Ge and ⁷⁸Ge nuclei, perhaps further evidence for the shape transition suggested recently for the Ge isotopes.     

The background in missing mass experiments

We propose a mechanism whereby one can determine the background in missing mass experiments in the resonance region by extending two component duality to absorptive amplitudes with external regeons. It is shown to explain naturally the very different trend of the background in the reactions p + p → p + X and π⁻ + p → p + X at available energies. The implications and limitations of this mechanism for the analysis of the spectrum are discussed.     

A study of low-lying states of 76As using the 75As(d,p) reaction

The ⁷⁵As(d, p)⁷⁶As reaction was investigated with 11 MeV deuterons. Thirty levels of the residual nucleus were identified up to about 1.8 MeV excitation energy, and angular distributions were measured. Spectroscopic factors and l_n values were obtained for low-lying transitions by means of a distorted-wave analysis of the differential cross sections. The l_n = 4 transition to the ground state of ⁷⁶As and the presence of l_n = 2 transitions to low-lying levels provide a strong support to the assumption that nuclei in this mass region have a large deformation parameter. The results are compared with the ⁷⁵As(n, γ)⁷⁶As data.