Effect of the storage tank thermal insulation on the thermal performance of an integrated collector storage solar water heater (ICSSWH)

The thermal behavior of an integrated collector storage solar water heater (ICSSWH) is numerically studied using CFD simulations. Based on the good agreement between the numerical results and the experimental data from literature, we propose a geometrical change allowing limiting the main disadvantage of this solar system which is its high night losses due to the non-insulated storage tank surface. A second 3D CFD model of an ICSSWH in which the storage tank is partially insulated is developed and three values of this tank thermal insulated fraction are studied. Numerical results show that the partially insulated tank based ICSSWH presents lower thermal losses during the night and this night thermal losses coefficient is reduced from 14.6 to 11.64 W K^?1 for the tank thermal insulation fraction τ = 1/4. Similarly, the modified system presents the advantage of its lower thermal losses even during the day. Regarding the thermal production, it is seen that the modified system presents higher water temperature at night and that for all the tank thermal insulation fractions. Concerning the operation of this modified system during the day, the water temperature is lower during the day and that up to 16 h but the water temperature which achieves 324 K for the storage tank thermal insulation fraction τ = 1/8 still sufficiently high to satisfy a family hot water needs.     

Conformation-specific spectroscopy and photodissociation of cold, protonated tyrosine and phenylalanine

We present here ultraviolet and infrared spectra of protonated aromatic amino acids in a cold, 22-pole ion trap. Ultraviolet photofragmentation spectra of protonated tyrosine and phenylalanine show vibronically resolved bands corresponding to different stable conformers: two for PheH+ and four in the case of TyrH+. We subsequently use the resolved UV spectra to perform conformer-specific infrared depletion spectroscopy. Comparison of the measured infrared spectra to density functional theory calculations helps assign the geometry of the various conformers, all of which exhibit NH...pi hydrogen bonds and NH...O=C interactions, with the COOH group oriented either anti or gauche to the aromatic ring. In both molecules the majority of the observed fragments result from dissociation on an excited electronic state. In TyrH+, different conformers excited with practically the same energy exhibit different fragmentation patterns, suggesting that the excited-state dynamics depend upon conformation.     

Determination of benzoylurea insecticides in food by pressurized liquid extraction and LC‐MS

A method based on pressurized liquid extraction and LC‐MS/MS has been developed for determining nine benzoylureas (BUs) in fruit, vegetable, cereals, and animal products. Samples (5 g) were homogenized with diatomaceous earth and extracted in a 22 mL cell with 22 mL of ethyl acetate at 80°C and 1500 psi. After solvent concentration and exchange to methanol, BUs were analyzed by LC‐MS/MS using an IT mass analyzer, which achieved several transitions of precursor ions that increase selectivity providing identification. LOQs were between 0.002 and 0.01 mg/kg, which are equal or lower than maximum residue limits established by the Codex Alimentarius. Excellent linearity was achieved over a range of concentrations from 0.01 to 1 mg/kg with correlation coefficients 0.995–0.999 (n=7). Validation of the total method was performed by analyzing in quintuplicate seven different commodities (milk, eggs, meat, rice, lettuce, avocado, and lemon) at three concentration levels (0.01, 0.1, and 1 mg/kg). The recoveries ranged from 58 to 97% and the RSDs from 5 to 19% depending on the compound and the commodity. The combination of pressurized liquid extraction with LC‐MS/MS provides a sensitive and selective method for the determination of BUs in food.     

Using Benders Decomposition to Implicitly Model Tour Scheduling

This paper introduces a new integrated model for the combined days-off and shift scheduling problem (the tour scheduling problem). This model generalizes the forward and backward constraints, previously introduced by Bechtold and Jacobs for the shift scheduling problem, to the tour scheduling problem. This results in a general and compact formulation that can handle several types of scheduling flexibility. We also provide a new proof of the correctness of forward and backward constraints based on Benders decomposition. The latter approach is interesting in itself because it can be used to solve the problem when extraordinary overlap of break windows or start-time bands is present. A discussion of model size for a set of hypothetical test problems is presented to show the merits of the new formulation.     

Polyphenolic Profile of Tunisian Thyme (Thymbra capitata L.) Post-Distilled Residues: Evaluation of Total Phenolic Content and Phenolic Compounds and Their Contribution to Antioxidant Activity

During the last decade there has been growing interest in the formulation of new cosmetic, food and pharmaceutical products containing natural compounds with antioxidant activity and other beneficial properties. Aromatic and medicinal plants have always been the major source of bioactive compounds, especially, wild thyme (Thymbra capitata L.), which has been used since ancient times for its valuable health benefits that could be attributed to the richness of polyphenolic compounds. This study was undertaken with the following aims: to estimate the total polyphenolic content (TPC); to evaluate the antioxidant activity; to identify and quantify the phenolic compounds of post-distilled residues of Tunisian thyme, and their contribution to the antioxidant activity. The TPC, as determined by the Folin–Ciocalteu method, was found to reach the values of 126.7 and 107.84 mg gallic acid equivalent/g plant dry weight (mg GAE/g PDW). The antioxidant activity, which is assessed by DPPH and FRAP assays, reached the values of 42.97–45.64 μg/mL and 42.22–50.21 mMFe²⁺/mg PDW, respectively. HPLC analysis revealed the presence of fourteen polyphenolic compounds, of which diosmin and rosmarinic acid were found to be the most abundant (24.26 to 33.80 and 22.0.1 to 26.29 mg/g PDW, respectively). An important correlation was found between the antioxidant activity and several identified phenolic compounds (p < 0.05). The findings revealed that thyme post-distilled residues have an effective natural antioxidant potential due to their high concentration of bioactive molecules, and they appear to be useful in the pharmaceutical, cosmetic, and food industries, with beneficial effects on human health. Therefore, supplementing a balanced diet with herbs may have beneficial health effects.