全文获取类型
收费全文 | 261篇 |
免费 | 19篇 |
国内免费 | 4篇 |
专业分类
化学 | 173篇 |
力学 | 2篇 |
综合类 | 1篇 |
数学 | 61篇 |
物理学 | 47篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 14篇 |
2020年 | 9篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2017年 | 4篇 |
2016年 | 16篇 |
2015年 | 11篇 |
2014年 | 11篇 |
2013年 | 32篇 |
2012年 | 17篇 |
2011年 | 17篇 |
2010年 | 7篇 |
2009年 | 16篇 |
2008年 | 11篇 |
2007年 | 16篇 |
2006年 | 10篇 |
2005年 | 4篇 |
2004年 | 2篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有284条查询结果,搜索用时 18 毫秒
41.
Touraj?NikazadEmail author Mokhtar?Abbasi 《Computational Optimization and Applications》2013,54(1):77-91
An algorithm for solving convex feasibility problem for a finite family of convex sets is considered. The acceleration scheme of De Pierro (em Methodos de projeção para a resolução de sistemas gerais de equações algébricas lineares. Thesis (tese de Doutoramento), Instituto de Matemática da UFRJ, Cidade Universitária, Rio de Janeiro, Brasil, 1981), which is designed for simultaneous algorithms, is used in the algorithm to speed up the fully sequential cyclic subgradient projections method. A convergence proof is presented. The advantage of using this strategy is demonstrated with some examples. 相似文献
42.
Trujillo C Lamsabhi AM Mó O Yáñez M Salpin JY 《Organic & biomolecular chemistry》2008,6(20):3695-3702
The structures and relative stabilities of the complexes formed by uracil and its sulfur derivatives, namely, 2-thio-, 4-thio, and 2,4-dithio-uracil when interacting with Ca(2+) in the gas phase have been analyzed by means of density functional theory (DFT) calculations carried out at the B3LYP/6-311++G(3df,2p)//B3LYP/6-31+G(d,p) level. For uracil and 2,4-dithiouracil, where the two basic sites are the same, Ca(2+) attachment to the heteroatom at position 4 is preferred. However, for the systems where both types of basic centers, a carbonyl or a thiocarbonyl group, are present, Ca(2+)-oxygen association is favored. The most stable complexes correspond to structures with Ca(2+) bridging between the heteroatom at position 2 of the 4-enol (or the 4-enethiol) tautomer and the dehydrogenated ring nitrogen, N3. The enhanced stability of these enolic forms is two-fold, on the one hand Ca(2+) interacts with two basic sites and on the other triggers a significant aromatization of the ring. Besides, Ca(2+) association has a clear catalytic effect on the tautomerization processes which connect the oxo-thione forms with the enol-enethiol tautomers. Hence, although the enol-enethiol tautomers of uracil and its thio derivatives should not be observed in the gas phase, the corresponding Ca(2+) complexes are the most stable species and should be accessible, because the tautomerization barriers are smaller than the Ca(2+) binding energies. 相似文献
43.
Aissa Guesmia Mokhtar Kirane 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(5):124
In this paper, we consider one-dimensional linear Bresse systems in a bounded open domain under Dirichlet–Neumann–Neumann boundary conditions with two infinite memories acting only on two equations. First, we establish the well-posedness in the sense of semigroup theory. Then, we prove two (uniform and weak) decay estimates depending on the speeds of wave propagations, the smoothness of initial data and the arbitrarily growth at infinity of the two relaxation functions. 相似文献
44.
The gas-phase interactions of 2,7-dimethyl-[1,2,4]-triazepine and its thio derivatives with Cu+ were studied through the use of high-level density functional theory (DFT) calculations. The structure of all possible tautomers and their conformers was optimized at the B3LYP/6-31G(d) level of theory. Final energies were obtained at the B3LYP/6-311+G(2df,2p) level. It has been found that the direct association of Cu+ occurs at the oxygen atom attached to position 3 in the case of the dioxo derivative and at the sulfur atom in all other cases. For the dithio derivatives, the global minimum of the PES corresponds to the structure in which the metal ion bridges between the heteroatom at position 3 and the nitrogen atom at position 4 of the corresponding enolic tautomer, forming a four-membered ring structure; for the dioxo derivative, this conformer competes with the ketone tautomer. Moreover, the isomerization processes leading from the most stable adduct to the other stable conformers were investigated. Among all the considered compounds, the 3,5-dithiotriazepines-Cu+ is found to be the one that associates Cu+ more tightly in the gas phase. The calculated Cu+ binding energies show a good correlation with the experimental proton affinities. 相似文献
45.
46.
Lamsabhi AM Mó O Gutiérrez-Oliva S Pérez P Toro-Labbé A Yáñez M 《Journal of computational chemistry》2009,30(3):389-398
The intermolecular double proton transfer in dimers of uracil and 2-thiouracil is studied through density functional theory calculations. The reaction force framework provides the basis for characterizing the mechanism that in all cases has been associated to a dynamic balance between polarization and charge transfer effects. It has been found that the barriers for proton transfer depend upon the nature of the acceptor atoms and its position within the seminal monomer. Actually, the change in the nature of the hydrogen bonds connecting the two monomers along the reaction coordinate may favor or disfavor the double-proton transfer. 相似文献
47.
Ahmed Ait Mokhtar 《Comptes Rendus Mathematique》2009,347(21-22):1227-1230
48.
The clonal analysis of a diverse collection of Salmonella Enteritidis indicates that most strains belong to a single multilocus genotype (i.e., ET-3) regardless of phage type, geographic origin, or time of isolation that spanned over 2 decades (1978 to 2004). Attachment and invasion assays, however, indicate that, among ET-3 isolates, there is a distinct invasive bacterial subpopulation that is more readily recovered from eggs and clinical cases in humans than from chicken cecal samples. These observations support the hypothesis that the specialized ability of S. Enteritidis to infect the avian reproductive tract and contaminate eggs has been critical in its emergence as a frequent cause of human illness. 相似文献
49.
The impact of lens aberrations becomes severe when the critical dimensions (CDs) shrink. The accurate measurement of both low- and high-order Zernike aberrations is important during a photolithographic process. Based on the multi-illumination settings and principal component analysis of aerial images, a novel in situ aberration measurement technique that can accurately measure all the Zernike aberrations, except for the sinusoidal 2-θ and sinusoidal 4-θ terms (under polar coordinates, and Z 1 to Z 4 are not considered) is proposed in this letter. The estimated maximum error of the Zernike aberrations ranges from 0.43 to 0.78 mλ when the amplitudes of the Zernike coefficients range from -20 to 20 mλ. The standard and root mean square errors are both in the range from 0.14 to 0.4 mλ. 相似文献
50.
Khalil Al Mamari Hamid Ennajih Hafid Zouihri Rachid Bouhfid Seik Weng Ng El Mokhtar Essassi 《Tetrahedron letters》2012,53(18):2328-2331
The 1,3-dipolar cycloaddition of 1-allyl-5-haloisatin derivatives as dipolarophiles with the azomethine ylides generated in situ from N-allylisatin and l-proline to furnish novel dispiro-oxindoles has been investigated. The structures and relative stereochemistry of both types of cycloadducts were confirmed by single crystal X-ray diffraction, 1H and 13C NMR spectroscopy and mass spectrometry. 相似文献