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51.
Joel M. Kauffman Ali Khalaj Peter T. Litak John A. Novinski Gurdip S. Bajwa 《Journal of heterocyclic chemistry》1994,31(4):957-965
To improve the solubility, photostability and fluorescence quantum yield (Φ) of 2-arylbenzimidazolium ions the N-1 hydrogen was replaced by an alkyl group before N-3 was quatemized; this substitution did not reduce Φ, proving the absence of steric inhibition to attainment of coplanarity in the excited state. A related symmetrical 2,2′-arylenebis(1,3-dimethyldibenzimidazolium ion) had Φ = 0.86. The related 2,5-bis(1-methyl-2-benzimidazolyl)phenol had Φ = 0.38 at 22° as well as a very large Stokes' shift due to proton-transfer. These findings supported a new insight into the electron distribution of the first excited singlet state of oligophenylenes. The compounds are of interest as laser dyes and scintillation fluors. 相似文献
52.
53.
Basing on the formalism established by Markovich, we show the completeness of wave operators for the Wigner equation in L2. In the second part, using estimations proved by Castella and Perthame on the one hand, and the Lp→Lq estimations for the Schrödinger group on the other hand, we prove the existence of the wave operators in L2,p spaces. To cite this article: H. Emamirad, P. Rogeon, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 811–816. 相似文献
54.
55.
K. Adu-Wusu N. M. Hassan C. A. Nash J. C. Marra 《Journal of Radioanalytical and Nuclear Chemistry》2006,267(2):381-388
Summary The removal of cesium from aqueous waste solution was investigated in a column setup using a relatively coarse SuperLigò644 resin. The bed volume (BV=140) at the onset of breakthrough surpassed the design requirement of 100 BV at 50% breakthrough,
and also corresponds to 99.96% cesium removal. Cesium elution with 0.5M HNO3was satisfactory with a peak BV of 2.5. The elution BV for C/C0=0.01 was 10, which is less than the target of 15 BV. The percent of sorbed cesium eluted was 99.88%. Further, the BV of the
various solutions used for the supporting process steps was sufficient. 相似文献
56.
Herein we describe the synthesis and characterization of compounds having the formulae R2SnL2 and R3SnL, where R = Me, n-Bu, Ph and n-Oct and L = 2-[N-(2,4,6-tribromophenylamido]propanoic acid. All the complexes have been characterized by various spectroscopic methods (IR and 1H, 13C, 119Sn NMR), elemental analysis, mass spectrometry and physical data. These compounds were also screened for their biological activity and found some encouraging results. 相似文献
57.
Trichloroisocyanuric acid is used as an effective oxidizing agent for the oxidation of 1,3,5-trisubstituted pyrazolines to their corresponding pyrazoles under both heterogeneous and also solvent free conditions with good yields at room temperature. 相似文献
58.
The reactions of bis(trimethylstannyl)ethyne, Me3Sn–C?C–SnMe3 ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by 29Si and 119Sn NMR, and the products were characterized by an extensive NMR data set (1H, 11B, 13C, 29Si, 119Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
59.
István E. MarkóJean-Christophe Vanherck Ali AtesBernard Tinant Jean-Paul Declercq 《Tetrahedron letters》2003,44(16):3333-3336
Upon treatment with tBuOK/H2O, a variety of ω-halo-β-keto-ketals undergo smooth cyclisation, affording in excellent yields mono-protected [n,m] spiro bicyclic diketones. This transformation is highly stereoselective producing, in all cases, the diastereoisomerically pure spiro derivatives. 相似文献
60.