A Novel Bacterial Route to Synthesize Cu Nanoparticles and Their Antibacterial Activity

Journal of Cluster Science - This report focuses on a facile and one-pot way to synthesize stable Cu nanoparticles (NPs) through a bacterial approach using an inexpensive and non-toxic copper salt...     

Upper bounds for Gaussian stochastic programs

We present a construction which gives deterministic upper bounds for stochastic programs in which the randomness appears on the right–hand–side and has a multivariate Gaussian distribution. Computation of these bounds requires the solution of only as many linear programs as the problem has variables. Received December 2, 1997 / Revised version received January 5, 1999? Published online May 12, 1999     

Chaos analysis in attitude dynamics of a flexible satellite

Nonlinear Dynamics - In this paper, we analytically and numerically investigate chaos in attitude dynamics of a flexible satellite composed of a rigid body and two identical rigid panels attached...     

Matrix‐free thin‐layer chromatography/laser desorption ionization mass spectrometry for facile separation and identification of medicinal alkaloids

Quaternary protoberberine alkaloids belong to a pharmaceutically important class of isoquinoline alkaloids associated with bactericidal, fungicidal, insecticidal and antiviral activities. As traditional medicine gains wider acceptance, quick and robust analytical methods for the screening and analysis of plants containing these compounds attract considerable interest. Thin‐layer chromatography (TLC) combined with matrix‐assisted laser desorption/ionization mass spectrometry (MALDI‐MS) is a powerful technique but suffers from dilution of the TLC bands resulting in decreased sensitivity and masking of signals in the low‐mass region both due to addition of matrix. This study integrates for the first time conventional silica gel TLC and laser desorption ionization mass spectrometry (LDI‐MS) thus eliminating the need for any external matrix. Successful separation of berberine (R_f = 0.56) and palmatine (R_f = 0.46) from Berberis barandana including their identification by MS are demonstrated. Furthermore, a robust electrospray ionization (ESI)‐MS method utilizing residual sample from TLC for quantification of berberine applying selected reaction monitoring and standard addition method is presented. The amount of berberine in the plant root prepared for the study was determined to be 0.70% (w/w). Copyright © 2009 John Wiley & Sons, Ltd.     

Solitons in a generalized space- and time-variable coefficients nonlinear Schrödinger equation with higher-order terms

We introduce an approach that combines a similarity method with several transformations to find analytical solitary wave solutions for a generalized space- and time-variable coefficients of nonlinear Schrödinger equation with higher-order terms with consideration of varying dispersion, higher nonlinearities, gain/loss and external potential. One of these transformations is constructed in such a way that allows study of the width of localized solutions. Solitary-like wave solutions for front, bright and dark are given. The precise expressions of the soliton?s width, peak, and the trajectory of its mass center and the external potential which are symbol of dynamic behavior of these solutions, are investigated analytically. In addition, the dynamical behavior of moving, periodic, quasi-periodic of breathing, and resonant are discussed. Stability of the obtained solutions is analyzed both analytically and numerically.     

Non-thermal Plasma Induced Expression of Heat Shock Factor A4A and Improved Wheat (<Emphasis Type="Italic">Triticum aestivum</Emphasis> L.) Growth and Resistance Against Salt Stress

There is a huge interest in making and applying innovating functional devices based on basic sciences (like physics) to improve plant growth and resistance against various stress conditions. This research was carried out in order to investigate effects of cold plasma on expressions of heat shock factor A4A (HSFA4A), plant growth and post reactions to salt stress. Wheat seedlings were treated with plasma (0.84 W/cm² surface power densities) at different exposure times. In both three and 6 h after plasma, inductions in expressions of HSFA4A were recorded in roots, compared to control. Six hours after treatments, plasma-induced the shoot expressions of HSFA4A in the treated seedlings, contrasted to 3 h. Plasma treatment caused not the only enhancement in shoot fresh and dry mass and total leaf area, but also alleviated adverse impacts of salinity. Destroying impacts of salinity on chlorophyll contents were mitigated by plasma. Peroxidase activity was decreased by 27% for salinity treatment alone over control, while it was increased by 15% for plasma and salinity-treated samples, compared to salinity control. The highest activities of phenylalanine ammonia lyase (PAL) were found in plasma treatment alone. PAL activity was found to be higher in plasma-pretreated seedlings counteracted to salt stress, relative to the salinity control. The plasma treatment may act as an effective elicitor to modify gene expression, thereby improving plant growth and resistance. Plasma technology should be considered as a new functional technology in plant sciences.     

Artificial neural network for quantitative determination of total protein in yogurt by infrared spectrometry

A method has been introduced for quantitative determination of protein content in yogurt samples based on the characteristic absorbance of protein in 1800-1500 cm^− 1 spectral region by mid-FTIR spectroscopy and chemometrics. Successive Projection Algorithm (SPA) wavelength selection procedure, coupled with feed forward Back-Propagation Artificial Neural Network (BP-ANN) model was the benefited chemometric technique. Relative Error of Prediction (REP) in BP-ANN and SPA-BP-ANN methods for training set was 7.25 and 3.70 respectively. Considering the complexity of the sample, the ANN model was found to be reliable, while the proposed method is rapid and simple, without any sample preparation step.     

Dynamic modeling of submerged nanoparticle pushing based on atomic force microscopy in liquid medium

This article introduces a theoretical analysis of submerged nanoparticle manipulation in liquid medium using the atomic force microscopy, and gives a review of the major differences between dry and submerged manipulation processes. In this regard, the manipulation is modeled by adding the influences of the hydrodynamic forces surface forces to the manipulation model in dry air. Then, the pushing of a gold nanoparticle of 50-nm radius on a silicon substrate at a velocity of 100 nm/s is simulated, and the dynamic behaviors of the tip and nanoparticle are investigated. The results show that, in water (as compared to air), the required manipulation force and time for nanoparticle sliding and rolling increase by 3.5 and 6.5%, for sliding and 2 and 4.3% for rolling, respectively. Also, in liquids with different viscosities, the critical values related to sliding and rolling have a maximum variation of 17 and 32% for the manipulation time, and 6 and 22% for the manipulation force, respectively, as compared to the critical values related to particle manipulation in air. Moreover, for various submerged lengths of the cantilever in water, the critical values related to sliding and rolling show a maximum time variation of 9 and 10.5%, and 7 and 7.2% (for the manipulation force), respectively. Qualitative comparisons between the obtained results and those of the existing experimental investigations show the advantages of the liquid medium for the manipulation purposes.     

Thermal and morphological characteristics of solution blended epoxy/NBR compound

Systematic study about the effect of acrylonitrile–butadiene rubber (NBR) concentration on the fracture toughness and thermal behavior of epoxy resin is conducted in this study. NBR is solved in an aromatic hydrocarbon solvent and is added to epoxy resin. We used diethylene-teriamin as the curing agent for epoxy resin. Tensile test results, performed followed by molding procedure, show that the toughness is improved owing to the increase of rubber content. Scanning electron microscopy (SEM) and atomic force microscopy besides thermogravimetric analysis (TG) are used to investigate the epoxy/rubber interface and chemical decomposition of the resultant mixture. The thermal behavior of cured epoxy resin was analyzed via TG instrument at different heating rates. Thermogravimetry curves showed that the thermal decomposition of epoxy system was occurred in only one stage regardless of the rubber content. The apparent activation energies of the rubber/epoxy systems containing 0, 5, and 10 phr of rubber were determined by Flynn–Wall–Ozawa, Kissinger–Akahira–Sunose, and Friedman methods. The results prove that the thermal stability of epoxy resin was decreased with enhancing the rubber content. However, the trend of changing activation energy versus conversions is totally different followed by adding the elastomer to the system compared to neat epoxy resin. Moreover, the results obtained via our proposed facile solution blending method are compared to those of resins modified with nano-powdered elastomer.     

Synthesis and characterization of nanocrystalline α-Al2O3 using Al and Fe2O3 (hematite) through mechanical alloying

In this present work, the synthesis of nanocrystalline α-Al₂O₃ using pure aluminum (Al) and Fe₂O₃ (hematite) as the precursors by mechanical alloying technique has been studied. The formation of α-Al₂O₃ nanocrystallites occurs during the solid-state reaction and through the reduction treatment. Also in this paper, effects of milling time on particle size and the lattice strain nanocrystalline α-Al₂O₃ have been investigated. Obtained powders were evaluated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), differential thermal analysis (DTA), thermal gravimetric analysis (TGA) and X-ray diffraction (XRD). The obtained results indicated that a reduction reaction was completed after 2 h milling in a planetary mill. The crystallite size of obtained α-alumina (α-Al₂O₃) was in general about 12 nm. Finally, the results showed appropriate homogeneity and dispersion of related nanocrystalline.