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151.
Structural Chemistry - In the present investigation, the feasibility of detecting the bromochlorodifluoromethane (BCF) gas molecule onto the outer surface of pristine single-wall silicon carbide... 相似文献
152.
Molecules that contain polyhydroquinoline structural scaffolds are N-containing heterocycles which are of great interest to organic chemists and biologists. Polyhydroquinoline structural scaffolds which are known as calcium channel blockers have emerged as one of the most important class of drugs used for the treatment of cardiovascular and Alzheimer's diseases. Besides, recovery and reusability of catalysts are important issues to be discussed in modern catalysis research especially in organic synthesis. The concept of magnetically recoverable catalysts has been rapidly developed in recent times. Magnetic separation is an efficient strategy for the rapid separation of catalysts from the reaction medium. Also, an alternative to time-, solvent-, and energy-consuming separation techniques. In this review, we focused on the fabrication, surface-modification and characterization of nanomagnetic materials and their application, as magnetically recoverable catalysts, in the synthesis of polyhydroquinoline structural scaffolds. 相似文献
153.
Mohammadi Masoud Ghorbani-Choghamarani Arash 《Research on Chemical Intermediates》2022,48(6):2641-2663
Research on Chemical Intermediates - In this study, a novel amino acid-based Ni complex was immobilized on SiO2-modified Hercynite magnetic nanoparticles as the support to prepare the... 相似文献
154.
J. Rashidinia R. Mohammadi R. Jalilian 《Numerical Methods for Partial Differential Equations》2007,23(6):1411-1419
In this study, we developed the methods based on nonpolynomial cubic spline for numerical solution of second‐order nonhomogeneous hyperbolic partial differential equation. Using nonpolynomial cubic spline in space and finite difference in time directions, we obtained the implicit three level methods of O(k2 + h2) and O(k2 + h4). The proposed methods are applicable to the problems having singularity at x = 0, too. Stability analysis of the presented methods have been carried out. The presented methods are applied to the nonhomogeneous examples of different types. Numerical comparison with Mohanty's method (Mohanty, Appl Math Comput, 165 (2005), 229–236) shows the superiority of our presented schemes. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007 相似文献
155.
N. Mohammadi J. N. Yoo A. Klein L. H. Sperling 《Journal of Polymer Science.Polymer Physics》1992,30(12):1311-1319
The number of chain scissions per unit area that occur during the fracture of partially annealed latex films from Mn ? 180,000 g/mol polystyrene particles of about 275 Å radius were measured and correlated to annealing times. A curve with four regimes was found. At short annealing times the curve is nearly flat, in what is called the chain pull-out regime. In the second regime, the number of chains broken per unit area increases with a 0.8 power of annealing time as entanglement of the diffusing polymer chains increases in neighboring host particles. This is in good agreement with Wool's theory which predicts a 0.75 power dependence. Then, after reaching a peak, the number of scissions decreases in the third regime, indicating a change in fracture mechanism. The number of chain scissions increases again in the fourth regime, as final healing of the film interface takes place. Fracture surface analysis reveals a rough surface for short annealing times and a smooth surface for longer annealing times. The number of polymer chain scissions per unit area of fracture surface showed no dependence on initial molecular weights for t ? τr where t and τr are annealing and relaxation times, respectively. The number of chain bridges crossing a unit area of interface was suggested as the basic molecular property. © 1992 John Wiley & Sons, Inc. 相似文献
156.
In this work, the onset of asphaltene flocculation for an Iranian crude oil by titration of samples with heptane in the presence and absence of the TiO2/SiO2 nanofluids was obtained by Near-IR spectroscopy. Nanoparticles and nanocomposites were characterized by BET, FESEM, EDX, XRD, and XRF analysis. Modeling and optimization of inhibition of asphaltene flocculation process by TiO2/SiO2 nanofluids were conducted by response surface methodology (RSM). Under optimum conditions (nanocomposite composition = 0.04 wt% (80%TiO2:20%SiO2), salinity = 4.01 wt%, and pH = 3.42), the onset point increased. For nanofluids stability analysis, the optimum nanofluid was compared with the two other nanofluids (SiO2 and TiO2) by visual observation method. The results indicated that high stability and surface area of the 80%TiO2 nanocomposites increase asphaltene adsorption on the particles surface that subsequently increases the onset point. In addition, the optimum nanofluid performance on the carbonate rocks was evaluated by contact angle and core flooding experiments. The 80% TiO2 nanofluid changed the wettability of carbonate rocks from strongly oil-wet to strongly water-wet condition and also decreased the residual oil saturation and enhanced the oil recovery with an increase in the recovery factor of about 15%. 相似文献
157.
Alireza Jahangiri Majid Saidi Farhad Salimi Abolfazl Mohammadi 《Research on Chemical Intermediates》2018,44(3):1755-1773
In this study, nano catalyst LaNiO3 with perovskite structure was synthesized using the citrate sol–gel method in the combined methane reforming with CO2 and O2 (CRM). The effects of increasing the surface area of the LaNiO3 perovskite on the catalytic activity were investigated by changing the method of preparing and creating holes in the surface of the samples. Physical and chemical properties of the samples, before and after the reactor test, were determined through ICP, AA, XRD, TGA, TPR, BET, SEM, EDX and TEM techniques. The results of XRD, ICP, AA, SEM, EDX and TEM tests indicated that the citrate sol–gel method is a good way to prepare a homogeneous perovskite LaNiO3 sample on a scale of nanometers. The results of the TPR test showed using etching in the citrate sol–gel method can produce samples with high stability. The BET results indicated that the surface area of the LaNiO3 sample tripled with the method suggested in this paper. Changes in preparation method lead to induction time decreasing and temperature increasing. Use of etching in the citrate sol gel method had no significant effect in the results of activity tests versus time reaction at a temperature of 800 °C. TGA curves revealed no production of coke over the process for the produced samples. 相似文献
158.
Nosrat Mohammadizadeh Sayed Zia Mohammadi Massoud Kaykhaii 《Journal of Analytical Chemistry》2018,73(7):685-694
A novel carbon paste electrode modified with ZrO2 nanoparticles and an ionic liquid (n-hexyl-3- methylimidazolium hexafluorophosphate) was fabricated. The electrochemical study of the modified electrode, as well as its efficiency for simultaneous voltammetric oxidation of dopamine and uric acid is described. The electrode was also employed to study the electrochemical oxidation of dopamine and uric acid, using cyclic voltammetry, chronoamperometry and square wave voltammetry as diagnostic techniques. Square wave voltammetry exhibits linear dynamic range from 1.0 × 10?6 to 9.0 × 10?4 M for dopamine. Also, square wave voltammetry exhibits linear dynamic range from 9.0 × 10?6–1.0 × 10?3 M for uric acid. The modified electrode displayed strong function for resolving the overlapping voltammetric responses of dopamine and uric acid into two well-defined voltammetric peaks. In the mixture containing dopamine and uric acid, the two compounds can be well separated from each other with potential difference of 155 mV, which is large enough to determine dopamine and uric acid individually and simultaneously. Finally, the modified electrode was used for determination of dopamine and uric acid in real samples. 相似文献
159.
Mohammad Soleiman-Beigi Keivan Mohammadi Fariba Mohammadi 《Journal of the Iranian Chemical Society》2018,15(7):1545-1550
A simple, one-pot, efficient and novel protocol has been developed for direct synthesis of symmetrical organic disulfides by domino reaction of aryl halides and K2S in the presence of magnetic Fe3O4 nanoparticles as a readily available, highly efficient and recyclable catalyst. A variety of diaryl disulfides can be obtained in good-to-excellent yields up to 98%. 相似文献
160.
Honari Mehran Sanaeishoar Haleh Kiasat Ali Reza Mohammadi Mohammad Kazem 《Research on Chemical Intermediates》2021,47(5):1829-1841
A simple and efficient method for the synthesis of pyrazolopyranopyrimidines under solvent-free has been developed. The one-pot multicomponent condensation of arylaldehydes with hydrazine hydrate, ethyl acetoacetate and barbituric acid in the vicinity of a mesoporous basic nanomagnetic catalyst, namely DBU immobilized on Fe3O4@nSiO2@mSiO2 was synthesized in remarkably high yields and in short reaction times. Significantly, this catalyst can be easily separated from the reaction media by applying an external magnet, and can be reused for several cycles.
Graphical abstract 相似文献