Effect of frequency on sonochemical reactions. I: Oxidation of iodide

The effect of continuous sonication on the kinetics of iodine formation in aqueous iodide solutions was studied in the presence of air and argon at two frequencies, 20 and 900 kHz. Most workers in this area assume that frequency has a negligible effect on sonochemical reactions. The present results indicate, however, that there is a significant effect in the above solutions. The rate of sonochemical oxidation of iodide in aqueous solution is 3.1 times greater in presence of air than argon at 900 kHz, in contrast to the situation at 20 kHz, where the ratio is 0.9 A 900 kHz apparatus was specially designed to make it possible to measure the absolute acoustic power delivered into the solution. The rate of oxidation per unit power in this new 900 kHz apparatus can be more than 30 times greater than that at 20 kHz for the oxidation of iodide in the presence of air.     

Preparation,surface state and band structure studies of SrTi(1 − x)Fe(x)O(3 − δ) (x = 0–1) perovskite-type nano structure by X-ray and ultraviolet photoelectron spectroscopy

In this report, SrTi_(1 ? x)Fe_(x)O_(3 ? δ) photocatalyst powder was synthesized by a high temperature solid state reaction method. The morphology, crystalline structures of obtained samples, was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscopy (TEM), respectively. The electronic properties and local structure of the perovskite STF_x (0 ≤ x ≤ 1) systems have been probed by extended X-ray absorption fine structure (EXAFS) spectroscopy. The effects of iron doping level x (x = 0–1) on the crystal structure and chemical state of the STF_x have been investigated by X-ray photoelectron spectroscopy and the valence band edges for electronic band gaps were obtained for STF_x by ultraviolet photoelectron spectroscopy (UPS). A single cubic perovskite phase of STF_x oxide was successfully obtained at 1200 °C for 24 h by the solid state reaction method. The XPS results showed that the iron present in the STF_x perovskite structure is composed of a mixture of Fe³⁺ and Fe⁴⁺ (SrTi_(1 ? x)[Fe³⁺, Fe⁴⁺]_(x)O_(3 ? δ)). When the content x of iron doping was increased, the amount of Fe³⁺ and Fe⁴⁺ increased significantly and the oxygen lattice decreased on the surface of STF_x oxide. The UPS data has confirmed that with more substitution of iron, the position of the valence band decreased.     

Sensitive determination of adenosine disodium triphosphate in soil,milk, and pharmaceutical formulation by enoxacin–europium (III) fluorescence complex in solution

A new spectroflurometric method for the determination of adenosine disodium triphosphate (ATP) is developed. Fluorometric interaction between ATP and enoxacin (ENX)–Eu³⁺ complex was studied using UV–vis and fluorescence spectroscopy. Weak luminescence spectra of Eu³⁺ were enhanced after complexation with ENX at 589 nm and 614 nm upon excitation at 395 nm due to energy transfer from the ligand to the lanthanide ion. It was observed that luminescence spectrum of Eu³⁺ was strongly enhanced further at 614 nm after incorporation of ATP into the ENX–Eu³⁺ complex. Under optimal conditions, the enhancement of luminescence at 614 nm was responded linearly with the concentration of ATP. The linearity was maintained in the range of 1.5×10^?10–1.15×10^?8 M (R=0.9973) with the limit of detection (3σ) of 4.71×10^?11 M. The relative standard deviation (RSD) for 9 repeated measurements of 1×10^?9  M ATP was 1.25%. Successful determinations of ATP in soil, milk, and a pharmaceutical formulation with the proposed method were demonstrated.     

The numerical and experimental study of photon diffusion inside biological tissue using boundary integral method

In this study, the diffusion of photons in turbid media, like biological tissue has been studied. Due to scattering and absorption of photons in such media, the study of photon propagation in biological tissue is complicated. The several numerical methods have been presented to simulate the behavior of diffused photons. Recently, Boundary Integral Method (BIM) has been offered to simulate photon migration inside biological tissues. This method has advantage, e.g. lower computational time in compared with other numerical methods. In this study, the accuracy and precision of BIM compares with another numerical method like Monte Carlo technique and finite difference method, and also the calculated results obtained by BIM and Monte Carlo method evaluate with measured results. Furthermore, the effects of scattering and absorption coefficient of tissue on the measured signal are studied.     

The effect of anodising time on the electrochemical behaviour of the Ti/TiO<Subscript>2</Subscript> NTs/IrO<Subscript>2</Subscript>-RuO<Subscript>2</Subscript>-Ta<Subscript>2</Subscript>O<Subscript>5</Subscript> anode

Nowadays, mixed metal oxide (MMO) anodes are a superior alternative to lead alloys in electrowinning processes. Passivation of titanium substrate is the most common mechanism of deactivation in these anodes. In this research, titanium oxide nanotubes have been utilised as an interlayer between the substrate and a mixed metal oxide coating in order to improve the anode electrochemical behaviour and life via retardation of titanium passivation. Anodising of the substrate was done in 0.5 wt% hydrofluoric acid for 30, 60 and 240 min. The samples were subsequently coated with a coating composed of IrO₂-RuO₂-Ta₂O₅. The microstructure of different samples was observed by scanning with an electron microscope, and the electrochemical behaviour of the samples was studied by accelerated life test, cyclic voltammetry and electrochemical impedance spectroscopy. The studies showed that formation of titanium oxide nanotubes with anodising times of 60 and 240 min increases the life of the anode through the provision of a compact coating. The life of the anode which was anodised for 240 min lasted about 20% longer than the sample which had a substrate without any anodised layer.     

Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction

Time-resolved single-crystal diffraction performed with synchrotron radiation shows that the 53(1) micros phosphorescent state, generated in the crystalline phase of trimeric {[3,5-(CF3)(2)Pyrazolate]Cu}(3) molecules by exposure to 355 nm of light at 17 K, is due to the formation of an excimer rather than the shortening of the intramolecular Cu...Cu distances within the trimeric units, or the formation of a continuous chain of interacting molecules. One of the intermolecular Cu...Cu distances contracts by 0.56 Angstroms from 4.018(1) to 3.46(1) Angstroms;, whereas the interplanar spacing of the trimers is reduced by 0.65 Angstroms; from 3.952(1) to 3.33(1) Angstroms. Density-functional theory calculations support the formation of a Cu...Cu bond through the intermetallic transfer of a Cu 3d electron to a molecular orbital with a large 4p contribution on the reacting Cu atoms.     

Novel model of FM-noise conversion in a UMZI using RF external phase modulation of lasers: Theoretical and experimental results

In this paper, we propose and demonstrate a new and original model for theoretical calculation and experimental measurement of the noise power spectral density (NPSD) in phase-modulated optical links. The phase modulation is operated in the RF frequency range by an external phase modulator. The NPSD is derived for the first time in interferometric systems, by considering all effects such as the 1/f FM noise of the laser and white noise applied to light from a 1550 nm DFB laser, with phase modulation. The results show for the first time the influence of the phase modulation index, modulation frequency and interferometric delay in the phase-to-intensity noise conversion. The experimental and simulation results of conversion of FM-noise to intensity noise in an optical link by considering the external RF phase modulation are shown with good agreement.     

Influence of ultrasound on cadmium ion removal by sorption process

This study presents the removal of Cd(II) from aqueous solution by the sorption process in the presence (sono-sorption) and absence (conventional method) of ultrasound. Batch experiments were conducted to study the main parameters such as sorbate concentration, amount of sorbent, contact time, and ultrasound intensity. In addition, the sorbate/sorbent concentration ratios were studied in two different ways: (a) in a constant sorbate concentration and variable amount of sorbent, (b) in a constant amount of sorbent and variable sorbate concentration. The results indicated that under proper conditions, there was a possibility to remove cadmium ion very fast and efficiently from aqueous solution. In addition, the intensity of ultrasound and the sorbate/sorbent concentration ratio were two important factors for the removal of this pollutant and therefore, this study was focused mostly on these two variables.     

Effect of operational parameters on degradation of Malachite Green by ultrasonic irradiation

The aim of the present study was to apply ultrasonic technique to remove Malachite Oxalate Green (MG) from aqueous solution. An ultrasonic bath with frequency of 35 kHz was used to investigate the effect of different operational parameters such as MG concentration, power density, temperature, mechanical agitation and addition of EtOH, 2-PrOH and iso-BuOH. Decolorization of MG follows a first order kinetics and hydroxyl radicals have an important role in degradation of MG. The apparent reaction rate constant (k(ap)) was influenced by variation of operational parameters. The activation energy was 30.95 kJ/mol in temperature range of 21-34 degrees C, suggesting a diffusion-controlled reaction. Alcohols act as hydroxyl radicals scavengers having undesirable contribution. UV-vis spectral change of MG showed hypsochromic shift occurred with increasing sonication time, proposing N-demethylation process of MG.     

Fragmentation of chitosan by ultrasonic irradiation

Kinetics of chitosan fragmentation by ultrasonic irradiation at frequency of 20 kHz, and the effects of experimental variables (power of ultrasound, chitosan concentration and solution temperature) on fragmentation were investigated. The kinetics studies were followed by measuring solution viscosity of the original and its fragments, and determining average number of chain scission of the fragments. The effects of ultrasonic power, chitosan concentration and solution temperature on fragmentation process were followed by viscometry and size exclusion chromatography. The chemical structure of the original chitosan and its fragments were examined by (1)H NMR spectroscopy and elemental analysis. The experimental results showed that the rate of fragmentation increased with an increase in power of ultrasound. Chain scission increased with an increase in power of ultrasound; and solution temperature, but a decrease in chitosan concentration. The chemical structure and polydispersity of the original and the fragments were nearly identical. A model based on experimental data to describe the relationship between chain scission and experimental variables (power of ultrasound; irradiation time; reduced concentration, c[eta]; and solution temperature) was proposed. It was concluded that ultrasonic irradiation is a suitable method to perform partial depolymerization and to obtain moderate macromolecules from large ones.