Atomic force microscopy investigation of surface roughness generated between SiO2 micro-pits in CHF3/Ar plasma

The present paper investigates the surface roughness generated by reactive ion etching (RIE) on the location between silicon dioxide (SiO₂) micro-pits structures. The micro-pit pattern on polymethyl methacrylate (PMMA) mask was created by an electron beam lithography tool. By using PMMA as a polymer resist mask layer for pattern transfer in RIE process, the carbon (C) content in etching process is increased, which leads to decrease of F/C ratio and causes domination of polymerization reactions. This leads to high surface roughness via self-organized nanostructure features generated on SiO₂ surface which was analyzed using atomic force microscopy (AFM) technique. The etching chemistry of CHF₃ plasma on PMMA masking layer and SiO₂ is analyzed to explain the polymerization. The surface root-mean-square (RMS) roughness below 1 nm was achieved by decreasing the RF power to 150 W and process pressure lower than 10 mTorr.     

Path integral quantization corresponding to the deformed Heisenberg algebra

In this paper, the deformation of the Heisenberg algebra, consistent with both the generalized uncertainty principle and doubly special relativity, has been analyzed. It has been observed that, though this algebra can give rise to fractional derivative terms in the corresponding quantum mechanical Hamiltonian, a formal meaning can be given to them by using the theory of harmonic extensions of function. Depending on this argument, the expression of the propagator of the path integral corresponding to the deformed Heisenberg algebra, has been obtained. In particular, the consistent expression of the one dimensional free particle propagator has been evaluated explicitly. With this propagator in hand, it has been shown that, even in free particle case, normal generalized uncertainty principle and doubly special relativity show very much different result.     

Utility of Silver-nanoparticles for Nano-fluorimetric Determination of Vancomycin Hydrochloride in Pharmaceutical Formulation and Biological Fluids: Greenness Assessment

Journal of Fluorescence - Vancomycin hydrochloride (VANH) is a glycopeptide antibiotic commonly employed in the prophylaxis and therapy of various gram-positive bacterial life-threatening...     

Impact of composition ratio on the structure and optical properties of (1-x)MnFe2O4/(x)ZnMn2O4 nanocomposite

($1-x$)MnFe$_{2}$O$_{4}$ (MFO)/$x$ZnMn$_{2}$O$_{4}$ (ZMO) ($x=0$, 0.2, 0.5, 0.8, and 1.0) nanocomposite samples were prepared using co-precipitation procedure. The phase percentage, cell parameters, and crystallite size of MFO and ZMO phases in each nanocomposite sample were calculated using Rietveld refinement procedure. The x-ray diffraction (XRD) analysis and Fourier-transform infrared spectroscopy techniques established the variation in the lattice parameters of each phase are due to permutation of all cations among the octahedral and tetrahedral sites of MFO and ZMO. The different oxidation states of different ions in all samples were determined using x-ray photoelectron spectroscopy (XPS) technique. The variation in absorbance of the nanocomposite samples with composition parameter ($x$) is dependent on the wavelength region. The optical bandgap of the nanocomposite samples is decreased as the content of ZMO phase increased. The effect of alloying on the refractive index, extinction coefficient, dielectric constant, optical conductivity, and the nonlinear optical behaviors of all samples were studied in detail. The nanocomposite sample $x=0.5$ disclosed upgraded optical parameters with the highest refractive index, optical conductivity, and PL intensity, which nominate it to be functional in various application fields.     

Bistable and self-tunable negative-index metamaterial at optical frequencies

We introduce a metamaterial design composed of square plasmonic loops loaded by Kerr nonlinearities that combines enhanced nonlinear response with strong artificial magnetism, ensuring a negative refractive index with bistable and self-tunable response. We verify with full-wave simulations that positive-to-negative switching of refractive index may be obtained with moderate loss. The design of a finite-size metamaterial prism is also presented, supporting at the same frequency, and for the same light intensity, positive or inverted Snell refraction as a function of its previous excitation history.     

Short-range order and F ion diffusion inside the Pb1 − xAlxF2 + x solid solution Part II: Al NMR investigation and proposal of clustering process

A ²⁷Al nuclear magnetic resonance (NMR) investigation at room temperature of the Pb_{1 − x}Al_xF_{2 + x} (0 ≤ x ≤ 0.12) solid solution and of the ordered Pb₉Al₂F₂₄ phase is carried out. Two different types of aluminium ions are identified and their ratio is determined as a function of x. A clustering process based on the formation of column clusters, more and more extended when x increases, is proposed on the basis of results issued from the ¹⁹F (Part I) and ²⁷Al NMR investigations.     

Efficient coupling and relaxed alignment tolerances in pigtailing of a laser diode using dual ball lenses

In this paper, we report an efficient coupling scheme with relaxed misalignment tolerances. The proposed coupling scheme consists of two ball lenses of same diameter (1 mm) and different refractive indices. The second ball lens which is facing the fiber tip has a higher refractive index (1.833), whereas the first one which faces the laser diode has a refractive index of 1.5. Employing Gaussian and ABCD ray tracing optics, the theoretically obtained coupling efficiency can reach a unity with relaxed working distance (separation of the coupling system from the fiber tip) in the range between 1 and 4 mm at some optimum positions of the coupling lenses with regard to each other and to the facet of the laser diode. It has been found that if the distance between the first ball lens and the laser diode (d₁) is fixed at 1.1 mm, which is twice its focal length, the coupling efficiency and the working distance as well as the misalignment tolerances are greatly affected by variation of the separation between the two ball lenses (s), and for this proposed coupling scheme the highest coupling efficiency and largest working distance are obtained when s is in the range of 0.3-0.35 mm. Above and below this range there is a significant reduction in the values of the above-mentioned parameters. Experimentally, the Nd:YAG laser welding system has been used for the alignment and welding of the coupling components in a butterfly configuration; the experimentally obtained coupling efficiency of the proposed coupling system was around 75% with relaxed working distance. From the effect of lateral and angular offsets on coupling efficiency, it is clearly noticed that the mode field of laser diode is transformed from elliptical into circular and hence effectively matched with that of the single-mode fiber.