全文获取类型
收费全文 | 134篇 |
免费 | 7篇 |
专业分类
化学 | 105篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 6篇 |
物理学 | 26篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 9篇 |
2012年 | 8篇 |
2011年 | 10篇 |
2010年 | 3篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 9篇 |
2006年 | 5篇 |
2005年 | 7篇 |
2004年 | 13篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有141条查询结果,搜索用时 15 毫秒
91.
Hirotoshi Fujie Kazuo Shiraki Tsutomu Miyagawa Noriaki Minamii Bunichiro Yamada Takayuki Otsu 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(9):741-751
Abstract A series of cyclic azoamidinium chlorides as water-soluble initiators were prepared by reactions of the iminoether derived from 2,2′-azobisisobutyronitrile with substituted alkylene diamines. The first-order rate constants for the decomposition of the azoamidinium salts varied from 0.59 × 10?5 to 14.1 × 10?5 s?1 with the ring size and the alkyl substitution of the ring. Decomposition of 2,2′-azobis[2-(imidazoline-2-yl)propane] dihydrochloride was found to be accelerated by alkyl substitution on the imidazolinium ring. However, the azoamidinium compounds having larger rings, 2,2′-azobis[2-(3,4,5-trihydropyrimi-dine-2-yl)propane] dihydrochloride and 2,2′-azobis[2-(4,5,6,7-tetra-hydro-1H-1,3-diazepine-2-yl)propane] dihydrochloride, decomposed at a slower rate than the unsubstituted azobis[2-(imidazoline-2-yl)-propane] dihydrochloride. These new initiators were found to be capable of initiating radical polymerizations of acrylamide and vinyl acetate. 相似文献
92.
Tomoko Miyagawa Takafumi Fukushima Toshiyuki Oyama Takao Iijima Masao Tomoi 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):861-871
The fluorinated polyimide PI(6FDA/HFBAPP) was prepared by the reaction of 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) with 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane (HFBAPP) in 1‐methyl‐2‐pyrrolidone/toluene. A multiblock copolyimide with both fluorinated and rigid‐rod segments, PI(6FDA/HFBAPP)(BPDA/2‐DMB), was prepared by the addition of a second dianhydride, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), and a second diamine, 2,2′‐dimethylbenzidine (2‐DMB), to the polyimide main chain. The potential lithographic performance of photosensitive polyimides composed of nonphotosensitive fluorine‐containing polyimides and photosensitive diazonaphthoquinone (DNQ) was studied on the basis of a new imaging principle recently proposed by our laboratory, that is, reaction development patterning. Neat PI(6FDA/HFBAPP) showed a low dielectric constant (?) of 2.41 and a low dissipation factor (tan δ) of 0.0027 at 20 GHz, and a 10‐μm resolution of the fluorinated polyimide/DNQ system was demonstrated with reactive development with a solution including ethanolamine after ultraviolet exposure. Although slight changes in the dielectric properties were observed in the presence of DNQ residues, these values (? = 2.63 and tan δ = 0.0033 at 20 GHz) were low enough for use in microelectronic applications. However, PI(6FDA/HFBAPP)(BPDA/2‐DMB), having a lower coefficient of thermal expansion (CTE; 33 ppm/°C) than PI(6FDA/HFBAPP) (49 ppm/°C), exhibited good positive photosensitivity, whereas the relatively low‐CTE multiblock copolyimide displayed a much higher ? value (3.48 at 1 MHz) than the highly fluorinated polyimide (2.88 at 1 MHz). A film consisting of PI(6FDA/HFBAPP)(BPDA/2‐DMB) and the remaining DNQ derivatives showed a CTE value comparable to that of the neat polyimide film. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 861–871, 2003 相似文献
93.
Application of a new azo‐polymer as a photo‐alignment material for liquid crystals (LCs) was demonstrated. 4‐(Vinyloxyethyloxy)azobenzene (VAZO), which has thermally reactive vinyl ether groups, reacted with the ? OH groups of poly(4‐hydroxystyrene) (PHS) during the baking process. The azo‐attached polymer (PHS‐VAZO) film showed anisotropic spectra after exposure to 365‐nm linear polarized light (LPL) unlike the VAZO‐doped poly(methylmethacrylate) (PMMA) film. The anisotropy of the film was small at high concentration of the azo‐chromophore because of thermal randomization of the polarized state. In the evaluation of photo‐alignment of the LC, the LC hybrid cell using the PHS‐VAZO film achieved high LC alignment. The azo‐attached polymer using the thermal reaction of vinyl ethers is useful for a photo‐alignment material. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
94.
95.
Hiroaki Miyagawa Michael J. Rich Lawrence T. Drzal 《Journal of Polymer Science.Polymer Physics》2004,42(23):4384-4390
The processing of nanocomposite materials composed of amine‐cured diglycidyl ether of bisphenol A (DGEBA) reinforced with organomontmorillonite clay is reported. A novel sample preparation scheme was used to process the modified clay in the glassy epoxy network, resulting in nanocomposites where the clay was both exfoliated and intercalated by the epoxy network. The processing scheme involves sonication of the constituent materials in a solvent, followed by solvent extraction to generate a composite with homogeneous dispersions of the nanoclay. Fourier transform infrared spectroscopy (FTIR) and Fourier transform (FT‐)Raman spectroscopy confirmed that the chemical structure of the epoxy network was not affected by the use of solvents in this processing scheme. The glass‐transition temperature, Tg, linearly increased with an increased weight ratio of the nanoclay. The microstructure of clay nanoplatelets in the composites was observed with transmission electron microscopy (TEM), wide‐angle X‐ray scattering (WAXS), and small‐angle X‐ray scattering (SAXS). It was found that the clay nanoplatelets were well‐dispersed, and were intercalated as well as exfoliated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4384–4390, 2004 相似文献
96.
Equilibrium Shift in Solution: Molecular Shape Recognition and Precipitation of a Synthetic Double Helix Using Helicene‐Grafted Silica Nanoparticles
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Masamichi Miyagawa Dr. Wataru Ichinose Prof. Dr. Masahiko Yamaguchi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(5):1272-1278
Chiral silica nanoparticles (70 nm) grafted with (P)‐helicene recognized the molecular shape of double helix and random coil (P)‐ethynylhelicene oligomers in solution. A mixture of the (P)‐nanoparticles and double helix precipitated much faster than a mixture of the (P)‐nanoparticles and random coil, and the precipitate contained only the double helix. The mixture of the (P)‐nanoparticles and (P)‐ethynylhelicene pentamer reversibly dispersed in trifluoromethylbenzene upon heating at 70 °C and precipitated upon cooling at 25 °C. When a 10:90 equilibrium mixture of the double helix and random coil in solution was treated with the (P)‐nanoparticles, the double helix was precipitated in 53 % yield and was accompanied by equilibrium shift. 相似文献
97.
Hiroaki Miyagawa Amar K. Mohanty Rigoberto Burgueño Lawrence T. Drzal Manjusri Misra 《Journal of Polymer Science.Polymer Physics》2007,45(6):698-704
Biobased unsaturated polyester (UPE) materials containing epoxidized methyl soyate (EMS) were processed with cobalt naphthenate as a promoter and 2‐butanone peroxide as an initiator. A certain amount of the UPE resin was replaced by EMS. The combination of the UPE and EMS resulted in an excellent combination for a new biobased thermoset material with a relatively high elastic modulus and a constant glass transition temperature with up to 25 wt % replacement with EMS. The Izod impact strength was almost constant while the amount of EMS was changed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 698–704, 2007 相似文献
98.
99.
Using the generalized Pauli principle by adding particle labels to the usual space and spin labels a symmetric Hamiltonian
and a corresponding antisymmetric wave function are constructed for systems of three baryons in the strangeness sectors S = −1 and −2. Applications are the ΞNN-ΛΛN and NNΛ-NNΣ systems. Minimal sets of generalized coupled Faddeev equations for breakup and rearrangement operators as well as (possible)
bound states are derived that have the ordinary Pauli principle for identical particles built in. The equations found confirm
our previous sets of coupled Faddeev equations whose derivation was made for distinguishable particles and not using the generalized
Pauli principle.
Received August 21, 2000; accepted for publication September 29, 2000 相似文献
100.
Bungo Ochiai Tokinori Iwamoto Toyoharu Miyagawa Daisuke Nagai Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4941-4947
We established a self‐catalyst system for solid phase incorporation of gaseous carbon dioxide into terpolymers prepared by polymerization of glycidyl methacrylate, N‐benzyl‐N‐[2‐(methacryrolroxy)ethyl]‐N,N‐dimethylammonium bromide, and methyl methacrylate. Terpolymer composition affected the incorporation behavior where the terpolymer with higher oxirane content exhibited higher efficiency of carbon dioxide incorporation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4941–4947, 2004 相似文献