全文获取类型
收费全文 | 385篇 |
免费 | 3篇 |
国内免费 | 1篇 |
专业分类
化学 | 267篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 19篇 |
物理学 | 98篇 |
出版年
2023年 | 2篇 |
2022年 | 4篇 |
2021年 | 2篇 |
2019年 | 7篇 |
2018年 | 2篇 |
2016年 | 2篇 |
2015年 | 3篇 |
2014年 | 6篇 |
2013年 | 9篇 |
2012年 | 8篇 |
2011年 | 23篇 |
2010年 | 13篇 |
2009年 | 15篇 |
2008年 | 19篇 |
2007年 | 22篇 |
2006年 | 21篇 |
2005年 | 23篇 |
2004年 | 11篇 |
2003年 | 15篇 |
2002年 | 23篇 |
2001年 | 17篇 |
2000年 | 8篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 10篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1972年 | 2篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有389条查询结果,搜索用时 15 毫秒
71.
The electronic and magnetic properties of oxidized zigzag and armchair graphene nanoribbons, with hydrogen passivated edges, have been investigated from ab initio pseudopotential calculations within the density functional scheme. The oxygen molecule in its triplet state is adsorbed most stably at the edge of a zigzag nanoribbon. The Stoner metallic behavior of the ferromagnetic nanoribbons and the Slater insulating (ground state) behavior of the antiferromagnetic nanoribbons remain intact upon oxygen adsorption. The formation of a spin-paired C-O bond drastically reduces the local atomic magnetic moment of carbon at the edge of the ferromagnetic zigzag ribbon. 相似文献
72.
Prof. Takayuki Nakajima Mizuki Takubo Yurika Komura Yuki Maeda Miwa Sato Maki Zouda Prof. Tomoaki Tanase 《欧洲无机化学杂志》2023,26(9):e202200648
A new series of cationic heterodinuclear complexes, [M1M2Cl2(meso-dpmppp)(RNC)2]PF6 (M1=Ni, M2=Rh, R=tBu ( 1 a ); M1=Pd, M2=Rh, R=tBu ( 2 a ), Xyl ( 2 b ); M1=Pt, M2=Rh, R=tBu ( 3 a ), Xyl ( 3 b ); M1=Pd, M2=Ir, R=tBu ( 4 a )), supported by a tetradentate phosphine ligand, meso-Ph2PCH2P(Ph)(CH2)3P(Ph)CH2PPh2 (meso-dpmppp), were synthesized by stepwise reactions of meso-dpmppp with NiCl2 ⋅ 6H2O or MCl2(cod) (M=Pd, Pt), forming mononuclear metalloligands of [M1Cl2(meso-dpmppp)], and with [M2Cl(cod)]2 (M2=Rh, Ir) and RNC (R=tBu, Xyl) in the presence of [NH4][PF6]. The related neutral PdRh complex, [PdRhCl3(meso-dpmppp)(XylNC)] ( 5 ), was also prepared. The structures of 1 – 5 were determined by X-ray analyses to contain two square planar d8 metal centers with face-to-face arrangement, where meso-dpmppp supports M1 and M2 metal ions in cis/trans-P,P coordination mode, combining cis-{M1P2Cl2} and trans-{M2P2(CNR)2} units. Complexes 1 – 4 showed an intence characteristic absorption around 422–464 nm derived from RhI→RNC MLCT transition (HOMO→LUMO+1), which are influenced by changing M1 (NiII, PdII, PtII) metal ions since HOMO composed of dσ* orbitals appreciably destabilized by changing M1 from Ni to Pd, and Pt. The electronic structures of 1 a – 4 a were investigated on the basis of DFT calculations and NBO analyses to show weak but noticeable d8–d8 metallophilic interaction as empirical dispersion energy of 0.9–1.5 kcal/mol without M1–M2 covalent bonding interaction. In addition, 1 – 5 were utilized as catalysts for hydrosilylation of styrene, and the NiRh complex 1 a was found to show higher activity and chemo- and regioselectivity compared with 2 – 5 . 相似文献
73.
Summary Retention behavior of anions and cations on anion-exchangers modified with dextran sulfate has been investigated. Retention
of anions was remarkably reduced by the modification, and the retention factor decreased with decreasing eluent concentration
when sodium sulfate was used as the eluent. Cations were also retained on the modified stationary phase, and alkali and alkaline-earth
metal ions were separated using copper sulfate or tris(2,2′-bipyridyl)ruthenium chloride as eluent. The size of the dextran
sulfate strongly affected the retention behavior of analyte ions. 相似文献
74.
Inorganic anions could be separated on porous graphitic carbon stationary phases in ion chromatography. Ion exchange between eluent anions and sample anions on the stationary phase was confirmed by the retention behavior and the possibility of indirect photometric detection. The elution order of anions was different from that observed for commercially available anion exchangers. Chloride, nitrate, and sulfate contained in tap water could be determined in 7 min. 相似文献
75.
76.
Corrugated paper is produced by gluing three types of papers of the same breadth. Given a set of orders, we first assign each order to one of the standard breadths, and then sequence those assigned to each standard breadth so that they are continuously manufactured from the three rolls of the specified standard breadth equipped in the machine called corrugator. Here we are asked to achieve multi-goals of minimizing total length of roll papers, total loss of papers caused by the differences between standard breadths and real breadths of the orders, and the number of machine stops needed during production. We use integer programming to assign orders to standard breadths, and then develop a special purpose algorithm to sequence the orders assigned to each standard breadth. This is a first attempt to handle scheduling problems of the corrugator machine. 相似文献
77.
78.
79.
Noguchi M Nakamura M Ohno A Tanaka T Kobayashi A Ishihara M Fujita M Tsuchida A Mizuno M Shoda S 《Chemical communications (Cambridge, England)》2012,48(45):5560-5562
An efficient chemo-enzymatic process for construction of the α-linked disaccharide unit (GlcNAcα1-4Gal) found in gastric mucin has been developed. The process consists of a one-step preparation of a novel triazine type glycosyl donor in water and the subsequent transglycosylation to a galactose derivative catalysed by α-N-acetylglucosaminidase. 相似文献
80.
Femtosecond two-photon stereo-lithography 总被引:7,自引:0,他引:7
M. Miwa S. Juodkazis T. Kawakami S. Matsuo H. Misawa 《Applied Physics A: Materials Science & Processing》2001,73(5):561-566
We report herein a method for the three-dimensional (3D) fabrication of microstructures by means of direct fs-beam writing
(scanning) inside a polymerizable resin. Photopolymerization takes place via two-photon absorption (TPA), as indicated by
measurements of transmission power dependence. This concept of fabrication is based on two principles: the use of short, sub-picosecond
pulses and simultaneous tight focusing (numerical aperture, NA>1). This approach creates a unique opportunity for avoiding
self-focusing even at very high intensities, as the power is lower than the self-focusing threshold. Under such conditions,
no filament formation takes place and no thermal convection disturbance occurs in the focal vicinity during photo-polymerization.
This technique requires no sacrificial layers or structures in real 3D micro-stereo-lithography.
Received: 31 May 2001 / Accepted: 6 June 2001 / Published online: 30 August 2001 相似文献