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581.
This article is concerned with in?nite depth gravity water waves in two space dimensions. We consider this system expressed in position-velocity potential holomorphic coordinates. Our goal is to study this problem with small wave packet data, and to show that this is well approximated by the cubic nonlinear Schr¨odinger equation(NLS) on the natural cubic time scale. 相似文献
582.
An almost quaternion-Hermitian structure on a Riemannian manifold $(M^{4n},g)$ is a reduction of the structure group of $M$ to $\mathrm{Sp}(n)\mathrm{Sp}(1)\subset \text{ SO }(4n)$ . In this paper we show that a compact simply connected homogeneous almost quaternion-Hermitian manifold of non-vanishing Euler characteristic is either a Wolf space, or $\mathbb{S }^2\times \mathbb{S }^2$ , or the complex quadric $\text{ SO }(7)/\mathrm{U}(3)$ . 相似文献
583.
A remarkably versatile synthesis of cis-stilbenoid hydrocarbons containing highly functionalized phenyl groups is developed via an efficient palladium-catalyzed coupling of aryl Grignard reagents with trans-1,2-dibromoalkenes (generally obtained via bromination of the corresponding dialkylacetylenes) in tetrahydrofuran. 相似文献
584.
L. Miu I. Ivan P. Badica G. Jakob D. Miu P. Mele K. Matsumoto M. Mukaida Y. Yoshida T. Horide A. Ichinose S. Horii 《Physica C: Superconductivity and its Applications》2010,470(20):1126-1129
The temperature T variation of the normalized magnetization relaxation rate S in high-temperature superconductors (HTS) with strong vortex pinning exhibits a maximum in the low-T range. This was reported for various HTS, and the origin of the faster relaxation at low T appearing in standard magnetization relaxation measurements was usually related to specific pinning properties of the investigated specimens. Since the observed behaviour seems to be characteristic to all HTS with enhanced pinning (generated by random and/or correlated disorder), we show that the S(T) maximum can be explained in terms of classic collective vortex creep. The influence of thermo-magnetic instabilities in the low-T range is also evidenced. The collective (elastic) creep regime is generated by the T dependent macroscopic currents induced in the sample during standard magnetization measurements. 相似文献
585.
Radu A. Gropeanu Mihaela L. Ţînţaş Catherine Pilon Mario Morin Livain Breau Raluca Turdean Ion Grosu 《Journal of heterocyclic chemistry》2007,44(3):521-527
The synthesis and stereochemistry of a series of new cyclic disulfides containing (poly)spirane 1,2‐dithiolane units are reported. Also included is a study of the self‐assembled monolayers (SAMs) of these compounds on a gold surface. The characteristics of the resultant SAMs were determined by IR spectroscopy using molecular mechanics calculations. 相似文献
586.
The purpose of this paper is to present a new proof of Branson?s classification (Branson, 1997 [3]), of minimal elliptic sums of generalized gradients. The advantage of this proof is that it is local, being mainly based on representation theory and on the relationship between ellipticity and refined Kato inequalities. This approach is promising for the classification of elliptic generalized gradients of G-structures, for other subgroups G of the special orthogonal group. 相似文献
587.
Ionela Alan Angela Kriza Rodica Olar Nicolae Stanica Mihaela Badea 《Journal of Thermal Analysis and Calorimetry》2013,111(2):1163-1171
Starting from 5-bromo-N,N′-bis-(salicylidene)-o-tolidine (H2L) new complexes with Co(II), Ni(II) and Cu(II) were synthesised and characterised. The features of complexes have been assigned from microanalytical, IR, UV–Vis–NIR and EPR spectra, magnetic data at room temperature as well as thermal analysis. IR data are in accordance with bischelate nature of the deprotonated ligand that coordinates through azomethinic nitrogen and phenolic oxygen. The electronic spectra display the characteristic pattern of tetrahedral stereochemistry for [CoL]·H2O complex and octahedral one for [NiL(OH2)2]·H2O complex. The electronic spectra correlated with magnetic susceptibility measurements indicate a square-planar surrounding for [ML] (M:Ni, Cu) species, while the EPR spectrum of copper complex sustains the proposed stereochemistry. The thermal analysis evidenced that thermal transformations are complex processes according to TG, DTA and DTG curves including (crystallization or coordination) water elimination, thermolyses and oxidative degradation of Schiff base. All these processes lead to the most stable metallic oxides as final product. 相似文献
588.
Larisa Calu Mihaela Badea Denisa Falcescu Daria Duca Dana Marinescu Rodica Olar 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1725-1730
In order to develop new metallo-antimicrobials the complexes of type MLCl·nH2O ((1) M: Co, n = 0; (2) M: Ni, n = 2; (3) M: Cu, n = 2.5; (4) M: Zn, n = 0, HL: Schiff base derived from acetylacetone and 3-amino-4H-1,2,4-triazole) were synthesized by template condensation. The features of complexes have been assigned from microanalytical, IR and UV–Vis-NIR data. The species heating in air evidenced processes as melting, water and hydrochloride endothermic elimination as well as oxidative degradation of the Schiff base. The temperature ranges as well as modification in the electronic spectra of dehydrated intermediates indicate the presence of both coordination and crystallisation water molecules. The final product of decomposition was the most stable metal oxide as powder X-ray diffraction indicated. 相似文献
589.
Mihaela Badea Ana-Maria Crasanda Mariana Carmen Chifiriuc Luminita Marutescu Veronica Lazar Dana Marinescu Rodica Olar 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1743-1751
New complexes [FeO(DMBG)]2 and [Fe(DMBG)2]Cl·0.5H2O (HDMBG: N,N-dimethylbiguanide) have been synthesized and characterized by microanalytical, IR and UV–Vis data. Electronic spectra of the complexes are characteristic for a tetrahedral stereochemistry, whilst the modifications in the IR spectra indicate the presence of the DMBG anion as chelate. The thermal decomposition investigated in air by thermal analysis confirmed the proposed formulas for the complexes and provided information concerning the modifications during heating and also the thermodynamic effects accompanying them. The thermal transformations are complex, according to TG and DTG curves including dehydration, hydrochloric acid elimination, oxidative degradation and condensation of –C=N– unit. The final product of decomposition was iron (III) oxide as powder XRD indicates. Complexes were screened for their antimicrobial properties against Gram-positive, Gram-negative bacterial, as well as fungal pathogenic strains. The results indicate that Fe(III) complexes exhibit an improved antibacterial activity against S. aureus and E. coli strains in comparison with free biguanide. The Fe(III) complexes also inhibit the ability of S. aureus, B. subtilis, P. aeruginosa and E. coli strains to colonize the inert substratum, accounting for their possible use as anti-biofilm agents. 相似文献
590.
Ioana Dorina Vlaicu Rodica Olar Dana Marinescu Veronica Lazar Mihaela Badea 《Journal of Thermal Analysis and Calorimetry》2013,113(3):1337-1343
Four new complexes having general formula [CoL2(acr)2] (L: 1H-pyrazole (Hpz) (1); 3-methyl-1H-pyrazole (3-Me-Hpz) (2); 4-methyl-1H-pyrazole (4-Me-Hpz) (3); 3,5-dimethyl-1H-pyrazole (Hdmpz) (4); acr: acrylato ion) were synthesised and characterised. The infrared and UV–vis spectral data indicate that these pyrazole derivatives act as unidentate while acrylato ions act as bidentate chelate ligands generating Co(II) complexes with octahedral stereochemistry. TG experiments revealed the nature of complex species as anhydrous and confirmed those compositions. The biological assays revealed a good activity against Bacillus subtilis for all complexes. 相似文献