全文获取类型
收费全文 | 482篇 |
免费 | 12篇 |
国内免费 | 2篇 |
专业分类
化学 | 351篇 |
晶体学 | 15篇 |
力学 | 15篇 |
数学 | 24篇 |
物理学 | 91篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 8篇 |
2020年 | 5篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 11篇 |
2014年 | 9篇 |
2013年 | 25篇 |
2012年 | 22篇 |
2011年 | 31篇 |
2010年 | 17篇 |
2009年 | 31篇 |
2008年 | 21篇 |
2007年 | 25篇 |
2006年 | 28篇 |
2005年 | 14篇 |
2004年 | 24篇 |
2003年 | 12篇 |
2002年 | 17篇 |
2001年 | 15篇 |
2000年 | 19篇 |
1999年 | 4篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1981年 | 5篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1972年 | 6篇 |
1970年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有496条查询结果,搜索用时 14 毫秒
481.
482.
We examine the process B-->X(s)gamma in minimal supersymmetry (SUSY) with general squark flavor mix-ings. We include all relevant next-to-leading order (NLO) QCD corrections and dominant NLO SUSY effects from the gluino. We find that gluino-squark corrections to down-type quark masses induce large NLO corrections to the dominant Wilson coefficients whose size is often similar to those at LO, es-pecially at large tan(beta. For micro>0, destructive interference and suppression by the renormalization group running lead to a "focusing effect" of reducing the size of gluino corrections to the branching ratio, and also of reducing the LO sensitivity to flavor mixings among squarks. Constraints from B(B-->X(s)gamma) on the SUSY-breaking scale can become significantly weakened relative to the minimal flavor violation case, even, at large tan(beta, for small flavor mixings. The case of micro<0 also becomes allowed. 相似文献
483.
Okoshi K Sano N Okumura T Tagaya A Magoshi J Koike Y Fujiki M Watanabe J 《Journal of colloid and interface science》2003,263(2):473-477
A novel coloration phenomenon in a colloidal dispersion with an amphiphilic polymer was found. The dispersion consists of tetrahydrofuran (THF), an aqueous solution of sodium thiosulfate (Na(2)S(2)O(3).5H(2)O), and hydroxypropylcellulose (HPC). The dispersion was emulsified by HPC as an amphiphilic polymer, so that the aqueous phase was confined in droplets in the THF matrix. It typically appeared bluish violet at room temperature and turned into blue with increasing temperature. In this system, the refractive indices of the inside and outside of the droplet coincided at a certain wavelength at which the light passes through without scattering, which is called the Christiansen effect. The color observed was successfully simulated by Mie's scattering theory in combination with the Christiansen effect. 相似文献
484.
M. Okumura L.I-C. Yeh D. Normand J.J.H. van den Biesen S.W. Bustamente Y.T. Lee 《Tetrahedron》1985,41(8):1423-1426
We have observed the presence of vibrationally excited CH2- created in a discharge, by measuring the photodetachment from CH2- as it radiatively relaxes in a high vacuum ion trap. We used a tunable IR laser to produce photons with energies above and below the expected threshold for removing an electron from the ground state. The time dependence of the photodetachment is consistent with the electron affinity of 5250 cm-1 (0.65 eV) obtained by Sears and Bunker for the ground state X?3B1 methylene. We have tentatively assigned radiative lifetimes for the excited bending vibrations of CH2-:600 ±300 msec for v2 = 1,80±40msec for v2 = 2, and 10± 5 msec for v2 = 3. 相似文献
485.
The permeabilities of several water-soluble drugs through excised hairless rat skin from their aqueous suspensions were investigated by using newly designed two-chamber diffusion cells. Disodium cromoglycate, diclofenac sodium, dopamine hydrochloride, isoproterenol hydrochloride, diltiazem hydrochloride and papaverine hydrochloride were selected as water-soluble drugs. Indomethacin, a lipophilic drug, and deuterium oxide (D2O) were used for comparison. The skin permeability coefficients of these water-soluble drugs were 100--1000 times lower than that of indomethacin. Since these drugs have high solubility in the donor solution (distilled water or lactate buffer), however, the skin permeation rates, which are in general proportional to the product of skin permeability coefficient and solubility of drugs in the drug-donor compartment, were comparable to or higher than that of indomethacin (1.7 micrograms/cm2/h): the skin permeation rate of dopamine hydrochloride (458 micrograms/cm2/h) was about 300 times higher than that of indomethacin. The water-soluble drugs with lower molecular weight and higher solubility in water showed higher skin permeation rates. These results suggest that some water-soluble drugs with low molecular weight and high solubility in water might be good candidates for transdermal drug delivery. 相似文献
486.
Prof. Dr. I. A. Okumura 《Archive of Applied Mechanics (Ingenieur Archiv)》1989,59(4):310-324
Summary An axi-symmetric stress analysis of a transversely isotropic, short hollow cylinder subjected to an outer band load is presented in a series form. The generalized Elliott's solution is used for the analysis. The solution consists of five independent potential functions which yield two kinds of elasticity solution. The boundary conditions for the shearing stress on the four surfaces are exactly satisfied. Other boundary conditions are numerically satisfied with the aid of a Fourier series expansion or a Fourier-Bessel series expansion. Numerical results for stresses in magnesium and cadmium crystals, as examples of transversely isotropic materials, and in an isotropic material are illustrated. The effect of anisotropy on the stresses is investigated by comparison with the stresses in the isotropic material.
Spannungen in einem transversal-isotropen, kurzen Hohlzylinder unter einer äußeren Bandlast
Übersicht Vorgestellt wird eine axialsymmetrische Spannungsanalyse mittels Reihen für einen transversalisotropen, kurzen Hohlzylinder unter einer äußeren Bandlast. Für die Analyse wird die verallgemeinerte Elliottsche Lösung benutzt. Die Lösung besteht aus fünf unabhängigen Potentialen, welche zwei Arten der Elastizitätslösung abgeben. Die Randbedingungen der Schubspannung auf den vier Flächen werden genau erfüllt. Die anderen Randbedingungen werden durch eine Fouriersche Reihenentwicklung oder eine Fourier-Besselsche Reihenentwicklung numerisch erfüllt. Die numerischen Resultate der Spannungen in einem Magnesiumkristall und einem Kadmiumkristall als Beispiele transversal-isotroper Materialien und in einem isotropen Material werden illustriert. Der Einfluß der Anisotropie auf die Spannungen wird durch Vergleich mit den Spannungen im isotropen Material untersucht.相似文献
487.
In this study, a homogenization theory based on the Gurtin strain gradient formulation and its finite element discretization are developed for investigating the size effects on macroscopic responses of periodic materials. To derive the homogenization equations consisting of the relation of macroscopic stress, the weak form of stress balance, and the weak form of microforce balance, the Y-periodicity is used as additional, as well as standard, boundary conditions at the boundary of a unit cell. Then, by applying a tangent modulus method, a set of finite element equations is obtained from the homogenization equations. The computational stability and efficiency of this finite element discretization are verified by analyzing a model composite. Furthermore, a model polycrystal is analyzed for investigating the grain size dependence of polycrystal plasticity. In this analysis, the micro-clamped, micro-free, and defect-free conditions are considered as the additional boundary conditions at grain boundaries, and their effects are discussed. 相似文献
488.
The higher-order stress work-conjugate to slip gradient in single crystals at small strains is derived based on the self-energy of geometrically necessary dislocations (GNDs). It is shown that this higher-order stress changes stepwise as a function of in-plane slip gradient and therefore significantly influences the onset of initial yielding in polycrystals. The higher-order stress based on the self-energy of GNDs is then incorporated into the strain gradient plasticity theory of Gurtin [2002. A gradient theory of single-crystal viscoplasticity that accounts for geometrically necessary dislocations. J. Mech. Phys. Solids 50, 5-32] and applied to single-slip-oriented 2D and 3D model crystal grains of size D. It is thus found that the self-energy of GNDs gives a D-1-dependent term for the averaged resolved shear stress in such a model grain under yielding. Using published experimental data for several polycrystalline metals, it is demonstrated that the D-1-dependent term successfully explains the grain size dependence of initial yield stress and the dislocation cell size dependence of flow stress in the submicron to several-micron range of grain and cell sizes. 相似文献
489.
Mitsutaka Okumura Yohei Nishimura Yasutaka Kitagawa Takashi Kawakami Kizashi Yamaguchi 《Polyhedron》2009,28(9-10):1768-1775
Hybrid density functional theory (HDFT) calculations have been carried out for clusters of p-NPNN extracted from the experimental crystal structures of the α-, β-, γ- and δ-phases in order to investigate the weak magnetic interactions between the organic radicals theoretically. From the systematic HDFT calculations for β- and γ-phase p-NPNN clusters, it was found that the magnetic long-range ferromagnetic and antiferromagnetic orderings would be presented in the β- and γ-phase p-NPNN crystals, respectively. 相似文献
490.
S. Nishihara S. Yamanaka K. Nakata Y. Kitagawa Y. Yonezawa M. Okumura H. Nakamura T. Takada K. Yamaguchi 《Polyhedron》2009,28(9-10):1628-1633
We investigated several phenalenyl cationic dimer systems using ab initio methods. First, we examine the through-space cation dimer. The B3LYP method fails to describe the correct dissociation as in the case of usual cation dimers. On the other hand, the resonating broken symmetry configuration interaction (Res-BS CI) method based on unrestricted Hartree–Fock solutions yields the correct potential surface and correct charge distributions. Furthermore, we investigated though-bond interactions of the phenalenyl cationic dimer via acetylene and ethylene bridges. The results are considerably different from those of the though-space case, implying that these bridging units play important roles to determine charge and spin distributions. Judging from these results, different bridges-or-stacks lead to different hole behaviors, indicating the possibility of various electronic functionalities of hole-doped phenalenyl compounds. In particular, the acetylene bridge is expected to enhance the conductivity of the hole-doped phenalenyl compounds. 相似文献