全文获取类型
收费全文 | 67篇 |
免费 | 11篇 |
专业分类
化学 | 48篇 |
晶体学 | 1篇 |
数学 | 9篇 |
物理学 | 20篇 |
出版年
2019年 | 1篇 |
2017年 | 1篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 1篇 |
2013年 | 5篇 |
2012年 | 2篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 1篇 |
2008年 | 6篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 2篇 |
2004年 | 4篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 2篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有78条查询结果,搜索用时 31 毫秒
41.
Kawasaki S Yashima M Mugino Y Mukuda H Kitaoka Y Shishido H Onuki Y 《Physical review letters》2006,96(14):147001
We report on systematic evolutions of antiferromagnetic (AFM) spin fluctuations and unconventional superconductivity (SC) in heavy-fermion (HF) compounds CeRh(1-x)Ir(x)In(5) via an (115)In nuclear-quadrupole-resonance experiment. The nuclear spin-lattice relaxation rate 1/T(1) has revealed the marked development of AFM spin fluctuations as approaching an AFM ordered state. Concomitantly, the superconducting transition temperature T(c) and the energy gap Delta0 increase drastically from T(c)= 0.4K and 2Delta0/k(B)T(c)=5 in CeIrIn(5) up to T(c) =1.2K and 2Delta0/k(B)T(c) =8.3 in CeRh(0.3)Ir(0.7)In5 , respectively. The present work suggests that the AFM spin fluctuations in close proximity to the AFM quantum critical point are indeed responsible for the strong-coupling unconventional SC in HF compounds. 相似文献
42.
Takafumi Hamaoka Takuya Osada Norio Murase Takayuki Sako Hiroyuki Higuchi Yuko Kurosawa Mitsuharu Miwa Toshihito Katsumura Britton Chance 《Optical Review》2003,10(5):493-497
The forearm muscles of five healthy males were monitored for changes in microvessel hemoglobin saturation (SO2-TRS) by near infrared time-resolved spectroscopy (NIRTRS) and changes in phosphorus metabolites by magnetic resonance spectroscopy (31P-MRS) during 12 min of resting arterial occlusion. Muscle oxygenation and phosphorus metabolites were also measured during grip exercises at varying intensities. Upon the initiation of occlusion, SO2-TRS fell progressively until it reached a plateau in the latter half of the occlusion. Phosphocreatine (PCr) began to decrease around 6 min after the initiation of arterial occlusion. The resting O2 store and O2 consumption were 295 μM and 0.95 μM/sec, respectively-values which reasonably agree with the reported results. A significant correlation was observed between the changes in SO2-TRS and PCr during exercise (r2 = 0.80, p < 0.001). These results indicate that NIRTRS is able to provide reliable information about resting metabolism and oxidative rate during exercise. NIRTRS and MRS are useful to monitor oxygenation and energetics noninvasively in the human muscle. 相似文献
43.
Tohru Setoyama Tooru Ookoshi Izumi Ono Mitsuharu Kobayashi Yoshio Kabata Tomohiro Kawai Akio Nakanishi Hiroshi Takeo 《Catalysis Surveys from Asia》2003,7(2-3):183-187
Polymerization of tetrahydrofuran (THF) catalyzed by solid acid in the presence of acetic anhydride was studied. Moderate Lewis acid catalyst produces PTME (PTMG-diacetate) having appropriate molecular number (Mn). Mixed oxide materials show good performance. Mass transfer study suggests the importance of pore size of the support and of the location of active sites. They affect the Mn and the polydispersity (Mw/Mn) strikingly. The commercial technology has established by utilizing these results. 相似文献
44.
Abstract We consider Lévy directed polymers in the Poisson random environment. We give conditions for strong or weak disorder in terms of the Lévy exponent of symmetric Lévy process. 相似文献
45.
In this paper we study the existence of solutions u ∈ \({{W}^{1,p}_{0}}\) (Ω) with △ p u ∈ L 2(Ω) for the Dirichlet problem 1 $$ \left\{ \begin{array} [c]{l}-\triangle_{p}u\left( x\right) \in-\partial{\Phi}\left( u\left( x\right) \right) +G\left( x,u\left( x\right) \right) ,x\in{\Omega},\\ u\mid_{\partial{\Omega}}=0, \end{array} \right. $$ where Ω ? R N is a bounded open set with boundary ?Ω, △ p stands for the p?Laplace differential operator, ?Φ denotes the subdifferential (in the sense of convex analysis) of a proper convex and lower semicontinuous function Φ and G : Ω × R → 2R is a multivalued map. We prove two existence results: the first one deals with the case where the multivalued map u ? G(x, u) is upper semicontinuous with closed convex values and the second one deals with the case when u ? G(x, u) is lower semicontinuous with closed (not necessarily convex) values. 相似文献
46.
47.
Abe T Matsumoto M Hashimoto S 《The Journal of the Acoustical Society of America》2008,124(2):994-1005
This paper introduces noise reduction combining time-frequency epsilon-filter (TF epsilon-filter) and time-frequency M-transform (TF M-transform). Musical noise is an offensive noise generated due to noise reduction in the time-frequency domain such as spectral subtraction and TF epsilon-filter. It has a deleterious effect on speech recognition. To solve the problem, M-transform is introduced. M-transform is a linear transform based on M-sequence. The method combining the time-domain epsilon-filter (TD epsilon-filter) and time-domain M-transform (TD M-transform) can reduce not only white noise but also impulse noise. Musical noise is isolated in the time-frequency domain, which is similar to impulse noise in the time domain. On these prospects, this paper aims to reduce musical noise by improving M-transform for the time-frequency domain. Noise reduction by using TD M-transform and the TD epsilon-filter is first explained to clarify its features. Then, an improved method applying M-transform to the time-frequency domain, namely TF M-transform, is described. Noise reduction combining the TF epsilon-filter and TF M-transform is also proposed. The proposed method can reduce not only high-level nonstationary noise but also musical noise. Experimental results are also given to demonstrate the performance of the proposed method. 相似文献
48.
One of the oldest open questions in semiconductor physics is the origin of the small splittings of the neutral acceptor ground state in silicon which lead to a distribution of doublet splittings rather than the fourfold-degenerate state of Gamma(8) symmetry expected in the absence of perturbations. Here we show that these acceptor ground state splittings are absent in the photoluminescence spectra of acceptor bound excitons in isotopically purified 28Si, demonstrating conclusively the surprising result that the splittings previously observed in natural Si result from the randomness of the Si isotopic composition. 相似文献
49.
Crey-Desbiolles C Lhomme J Dumy P Kotera M 《Journal of the American Chemical Society》2004,126(31):9532-9533
A new photocleavable 2'-deoxyadenosine mimic, 3-nitro-3-deaza-2'-deoxyadenosine (NidA), was prepared and introduced into DNA fragments via its 6-O-trimethylphenyl precursor phophoramidite. Photocleavage of the resulting oligonucleotide is highly efficient in single and double strands. Hybridization properties of NidA are very similar to those of deoxyadenosine. 相似文献
50.
Back Cover: Indolizino[5,6‐b]quinoxaline Derivatives: Intramolecular Charge Transfer Characters and NIR Fluorescence (Chem. Asian J. 11/2015)
下载免费PDF全文
![点击此处可从《化学:亚洲杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)