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961.
Khalil Farhadi Mir Ali Farajzadeh Amir Abbas Matin 《Journal of separation science》2009,32(14):2442-2447
A dispersive liquid–liquid microextraction (DLLME) method combined with solvolysis reaction for extraction of the carbamate fungicide benomyl as carbendazim from water samples is described. The method is based on the extraction of benomyl from acidified sample solution and its conversion into carbendazim via solvolysis reaction with DMF as organic solvent. The proposed DLLME method was followed by HPLC with fluorimetric detection for determination of benomyl. The proposed method has good linearity (0.998) with wide linear dynamic range (0.01–25 mg/L) and low detection limit (0.0033 mg/L), making it suitable for benomyl determination in water samples. 相似文献
962.
Dispersive liquid-liquid microextraction and liquid chromatographic determination of pentachlorophenol in water 总被引:1,自引:0,他引:1
Khalil Farhadi Mir A. Farajzadeh Amir A. Matin Paria Hashemi 《Central European Journal of Chemistry》2009,7(3):369-374
A simple and sensitive dispersive liquid-liquid microextraction method for extraction and preconcentration of pentachlorophenol
(PCP) in water samples is presented. After adjusting the sample pH to 3, extraction was performed in the presence of 1% W/V
sodium chloride by injecting 1 mL acetone as disperser solvent containing 15 μL tetrachloroethylene as extraction solvent.
The proposed DLLME method was followed by HPLC-DAD for determination of PCP. It has good linearity (0.994) with wide linear
dynamic range (0.1–1000 μg L−1) and low detection limit (0.03 μg L−1), which makes it suitable for determination of PCP in water samples.
相似文献
963.
964.
Mir Faizal 《理论物理通讯》2012,(11)
In this paper we will study non-abelian Chern-Simons theory on a deformed superspace. We will deform the superspace in such a way that it includes the noncommutativity between bosonic and fermionic coordinates. We will first analyse the BRST and the anti-BRST symmetries of the Chern-Simons theory on this deformed superspace. Then we will analyse the extended BRST and the extended anti-BRST symmetries of this theory in the Batalin-Vilkovisky (BV) formalism. Finally, we will express these extended BRST and extended anti-BRST symmetries in extended superspace formalism by introducing new Grassmann coordinates. 相似文献
965.
Tariq Mahmood Chuanbao Cao Faheem K. Butt Haibo Jin Zahid Usman Waheed S. Khan Zulfiqar Ali Muhammad Tahir Faryal Idrees Maqsood Ahmed 《Physica B: Condensed Matter》2012,407(22):4495-4501
The ultrasoft pseudopotential technique is used to explore the elastic, electronic and optical properties of cotunnite TiO2 using LDA and GGA proposed by Perdew Wang (PW91), Perdew–Burke–Ernzerhof (PBE) functional as defined by Wu and Cohen (PBEWC) and PBE functional for solids (PBESOL). The calculated elastic constants bulk modulus, shear modulus and Young’s modulus are in agreement with the previous theoretical reports. From our investigated shear anisotropy factors (A1, A2, and A3), we infer that cotunnite TiO2 is strong anisotropy in case of A1 and A2 and less anisotropy in case of A3. The value of mean sound speed and Debye temperature are calculated using the obtained values of elastic moduli. The calculated structural parameters are in accord with the reported experiment and theoretical results. Our obtained values of direct bandgaps show an improvement over the other previous theoretical reports. The values of the dielectric constant (ε1(ω)) of cotunnite TiO2 calculated within LDA and GGA approximations are 7.655 (LDA (CA-PZ)), 7.578 (GGA (PW91)), 7.685 (GGA (WC)) and 7.655 (GGA (PBESOL)), which are slightly higher than the experimental values of rutile (6.69) and anatase (6.55) polymorphs. The obtained values of the refractive index are consistent with rutile TiO2 and higher than anatase phase. The investigated imaginary part of dielectric constant and absorption spectrum reflect that the cotunnite TiO2 is a weak photocatalytic material as compared to anatase and similar to rutile phases. 相似文献
966.
Diffraction phase microscopy with white light 总被引:1,自引:0,他引:1
We present white light diffraction phase microscopy (wDPM) as a quantitative phase imaging method that combines the single shot measurement benefit associated with off-axis methods, high temporal phase stability associated with common path geometries, and high spatial phase sensitivity due to the white light illumination. We propose a spatiotemporal filtering method that pushes the limit of the pathlength sensitivity to the subangstrom level at practical spatial and temporal bandwidths. We illustrate the utility of wDPM with measurements on red blood cell morphology and HeLa cell growth over 18 hours. 相似文献
967.
Faezeh Javanbakht Mohammad Reza Afshar Mogaddam Mahboob Nemati Mir Ali Farajzadeh 《Journal of separation science》2023,46(8):2200696
In this work, for the first time, a polymeric composite based on β-cyclodextrin grafted with polyethylene has been prepared through ball milling and used as an efficient sorbent for dispersive solid phase extraction of metronidazole and clarithromycin from plasma samples. The prepared sorbent was characterized using Fourier transform infrared spectrophotometry, X-ray diffraction, and scanning electron microscopy. In the extraction process, after precipitating the proteins, the sorbent was added into the sample solution, and the mixture was vortexed to facilitate and speed up the sorption of the analytes onto the sorbent surface. After centrifuging, the sorbent particles were contacted with methanol to elute the analytes under the vortexing process. After this step, an aliquot of the eluate was taken and injected into high-performance liquid chromatography–diode array detector for quantitative analysis. Under the optimum extraction conditions, the extraction recoveries for metronidazole and clarithromycin were 76 and 83%, respectively. The limits of detection were 2.6 and 2.2 ng/ml for metronidazole and clarithromycin, respectively. The repeatability of the offered approach, expressed as relative standard deviation, was equal to or less than 4.7%. Finally, the method was successfully applied to plasma samples of the patients treated with metronidazole and clarithromycin. 相似文献
968.
Mariola Brycht Karolina Kowalewska Sławomira Skrzypek Valentin Mirčeski 《Electroanalysis》2023,35(4):e202200398
An electrochemical study of the fungicide bixafen using a paste electrode based on thermally reduced graphene oxide (TRGOPE) synthesized in air is presented for the first time. Cyclic voltammetry and square-wave voltammetry (SWV) were conducted to characterize the mechanism of the underlying electrode process of bixafen. Optimization of the procedure for the quantitative determination of bixafen was carried out by SWV. Excellent electroanalytical performance in terms of a limit of detection of 31.5 nmol L−1 was achieved. The TRGOPE was effectively employed to analyze bixafen in spiked river and tap water samples. The selectivity towards bixafen determination was also assessed. 相似文献