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41.
Aysa Abbasalizadeh Saeed Mohammad Sorouraddin Mir Ali Farajzadeh Elnaz Marzi Mohammad Reza Afshar Mogaddam 《Journal of separation science》2022,45(9):1550-1559
A vortex-assisted dispersive micro-solid-phase extraction procedure using a new and green sorbent was developed as a simple, fast, and efficient sample preparation method for the extracting five pesticides in several fruit juice samples. In this study, for the first time, riboflavin was used as an efficient sorbent. A few milligrams of riboflavin was directly added into the aqueous solution containing the analytes to adsorb them. After adsorption the analytes, they were desorbed and more concentrated by a dispersive liquid–liquid microextraction procedure. The influence of several effective parameters such as amount of riboflavin, pH, vortex time, eluent nature and volume, and extraction solvent type and volume on the extraction efficiency was investigated. In optimal conditions, linear ranges of the calibration curves were broad. The limits of detection and quantification were attained in the ranges of 0.56–1.5 and 1.9–0.52 ng mL−1, respectively. The proposed method demonstrated to be suitable for concurrent extraction of the studied pesticides in various fruit juice samples with high enrichment factors (320–360) and precision (relative standard deviation ≤7.8% for intra- [n = 6] and interday [n = 4] precisions at a concentration of 25 ng mL−1 of each pesticide). 相似文献
42.
Aubert B Barate R Bona M Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges E Palano A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Battaglia M Brown DN Button-Shafer J Cahn RN Charles E Gill MS Groysman Y Jacobsen RG Kadyk JA Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA del Amo Sanchez P Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE Watson AT Held T Koch H Lewandowski B 《Physical review letters》2007,98(5):051802
We present an observation of B-->eta'K*. The data sample corresponds to 232x10(6) BB[over ] pairs collected with the BABAR detector at the PEP-II asymmetric-energy B factory at the Stanford Linear Accelerator Center. We measure the branching fractions (in units of 10(-6)) B(B(0)-->eta'K*0)=3.8+/-1.1+/-0.5 and B(B+-->eta'K*+)=4.9(1.7)(+1.9)+/-0.8, where the first error is statistical and the second systematic. A simultaneous fit results in the observation of B-->eta'K* with B(B-->eta'K*)=4.1(-0.9)(+1.0)+/-0.5. We also search for B-->eta'rho and eta'f(0)(980)(f(0)-->pi+pi-) with results and 90% confidence level upper limits B(B+-->eta'rho+)=8.7(-2.8-1.3)(+3.1+2.3) (<14), B(B(0)-->eta'rho0)<3.7, and B(B(0)-->eta'f(0)(980)(f(0)-->pi+pi-))<1.5. Charge asymmetries in the channels with significant yields are consistent with zero. 相似文献
43.
We use a third-order perturbation theory and Melnikov's method to prove the existence of chaos in spinning circular disks subject to a lateral point load. We show that the emergence of transverse homoclinic and heteroclinic points lead, respectively, to a random reversal in the traveling direction of circumferential waves and a random phase shift of magnitude pi for both forward and backward wave components. These long-term phenomena occur in imperfect low-speed disks sufficiently far from fundamental resonances. 相似文献
44.
A Silver Bite: Crystalline Heterometallic Architectures Based on Ag–π Interactions with a Bis‐Dipyrrin Zinc Helicate 下载免费PDF全文
Hervé Ruffin Dr. Stéphane A. Baudron Dr. Domingo Salazar‐Mendoza Prof. Mir Wais Hosseini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(9):2449-2453
An unprecedented mode of assembly of helical motives and AgI ions in the crystalline state is described. The combination of a ZnII helicate based on a 2,2′‐bisdpm bearing peripheral benzonitrile moieties with AgX salts, leads to the formation of a tetranuclear core containing Ag–π interactions. Depending on the coordinating ability of the X? anion and the solvents used, the tetranuclear complex self‐assembles into coordination polymers of varying dimensionality. From the sequence of coordination events (Ag–π or Ag–peripheral site), one may envisage two possible construction scenarios. However, the Ag–π as primary event seems reasonable owing to the rather weak binding propensity of the nitrile group and the chelating nature of the π‐clefts. 相似文献
45.
Asghar Mardani Mohammad Reza Afshar Mogaddam Mir Ali Farajzadeh Ali Mohebbi Mahboob Nemati Mohammadali Torbati 《Journal of separation science》2020,43(18):3674-3682
A sample pretreatment method based on the combination of a three‐phase solvent extraction system and deep eutectic solvent‐based dispersive liquid–liquid microextraction has been introduced for the extraction of four organochlorine pesticides in cocoa samples before their determination by gas chromatography‐electron capture detection. A mixture of sodium chloride, acetonitrile, and potassium hydroxide solution is added to cocoa bean or powder. After vortexing and centrifugation of the mixture, the collected upper phase (acetonitrile) is removed and mixed with a few microliters of N,N‐diethanol ammonium chloride: pivalic acid deep eutectic solvent. Then it is rapidly injected into deionized water and a cloudy solution is obtained. Under optimum conditions, the limits of detection and quantification were found to be 0.011‐0.031 and 0.036‐0.104 ng/g, respectively. The obtained extraction recoveries varied between 74 and 92%. Also, intra‐ (n = 6) and interday (n = 4) precisions were less than or equal to 7.1% for the studied pesticides at a concentration of 0.3 ng/g of each analyte. The suggested method was applied to determine the studied organochlorine pesticide residues in various cocoa powders and beans gathered from groceries in Tabriz city (Iran) and aldrin and dichlobenil were found in some of them. 相似文献
46.
Mahboob Nemati Mir Ali Farajzadeh Ali Mohebbi Fariba Khodadadeian Mohammad Reza Afshar Mogaddam 《Journal of separation science》2020,43(6):1119-1127
A stir bar sorptive extraction method coupled with deep eutectic solvent based solidification of floating organic droplets–dispersive liquid–liquid microextraction has been used for the simultaneous derivatization and extraction of some acidic pesticides in tomato samples. In this method, initially the analytes are adsorbed on a coated stir bar from tomato juice filled in a narrow tube. After extraction, the stir bar is removed and a water–miscible deep eutectic solvent is used to elute the analytes. Afterward, a derivatization agent and a water–immiscible deep eutectic solvent (as an extraction solvent) with melting point near to room temperature are added to the obtained eluant at µL–levels and the obtained mixture is rapidly injected into deionized water. Under the optimum conditions, the introduced method indicated high enhancement (1543–3353) and enrichment (2530–2999) factors, low limits of detection (7–14 ng/L) and quantification (23–47 ng/L), good linearity (r2 ≥ 0.9982), and satisfactory repeatabilities (relative standard deviation ≤12% for intra– and inter–day precisions at a concentration of 100 ng/L of each analyte). Finally, the proposed method was applied in analysis of the analytes in tomato samples. 相似文献
47.
Nowadays, the eye-catching characteristics of boron nitride nanotubes, in particular, the capability of sensing nano-objects, have opened up new prospects to develop the bio-/nano-sensing technologies. This research deals with physically affected single-walled boron nitride nanotubes (SWBNNT) as nano-sensors for sensing attached nanoscale objects. Three different boundary conditions including simply supported at both ends, clamped-free and clamped-clamped are considered to illustrate the vibrational behaviour of SWBNNTs as nano-sensor. The Rayleigh and Timoshenko beam theories are employed to model the SWBNNT. Also, the nonlocal strain gradient model is utilized to capture the size-dependent effects. One of the major factors in the scrutiny of mass nano-sensors is pertinent to the variation in frequency shift magnitudes against the number and mass weight values of attached nanoparticles. Herein, the effects of the nonlocal and material length scale parameters, the number and location of nano-objects, the rotary inertia and mass weight magnitudes of attached nanoparticles, the aspect ratio of SWBNNT, electrical potential and different boundary conditions on the variation in frequency shift and resonant frequency are analysed. 相似文献
48.
Rice Bran as an Excellent Sorbent for Heavy Metals from Aqueous Media, 1. Optimization of Conditions
In this two‐part report, the efficiency of rice bran in removal of heavy metals such as cadmium, lead, zinc, nickel, copper and iron(III) from aqueous solution is investigated. The different experimental conditions such as pH, temperature, volume of solution, bran amount, particle size, exchange time, stirring speed, etc. are studied, and the optimum conditions are selected in part 1 of this series of reports. The efficiency of bran in removal of heavy metals is presented with and without treatments. For treatment, heat or acid, alkali and salt solutions were used. The results obtained show that after treating with saturated sodium chloride solution, its efficiency for Ni2+ and Zn2+ improves. At pH 5, all studied cations have recoveries more than 93% (lead and cadmium 100%). The exchange speed is very high and has preference over the classical ion exchangers. 相似文献
49.
In this paper, we consider the class of polynomials P(z)= anz^n+ ∑vn=μan-vz^n-v,1≤μ≤n , having all zeros in |z|≤k, k ≤1 and thereby present an alternative proof, independent of Laguerre's theorem, of an inequality concerning the polar derivative of a polynomial. 相似文献
50.
In our previous paper Ohkuwa et al. (2016) corrigendum was found in Eqs. (3.4) and (3.6). However, conclusions of our previous paper are not changed. 相似文献