顶棚辐射供冷与新风联合系统的辐射顶棚热特性研究

介绍了一种上送上回式新风与顶棚辐射联合供冷系统,通过搭建实验房间,研究了新风系统以及三种不同供水温度对于辐射顶棚的热特性的影响,并且分析了联合系统的防结露能力。实验分析得出,在本次实验条件下,当供水温度高于14℃时,能够保证辐射顶棚不结露。     

1319-nm single-frequency output from dif fusion-bonded monolithic nonplanar Nd:YAG ring resonator with undop0ed end

An efficient 1 319-nm Nd:YAG single-frequency laser is demonstrated in a diffusion-bonded nonplanar ring oscillator (NPRO) with an undoped end. The thermal model of diffusion-bonded NPRO is generated to analyze the temperature field and thermal focal length. A stable single-frequency output power of up to 1.55 W is obtained at 1 319 nm.     

Thermal effects of the zig-zag Yb:YAG slab laser with composite crystals

Applied Physics B - In this study, we propose an optical hybrid encryption scheme based on compressive temporal ghost imaging. This scheme combines the asymmetric of the public key cryptography and...     

Chemical bonding and elastic properties of Ti3AC2 phases (A = Si,Ge, and Sn): A first-principle study

The chemical bonding and elastic properties as well as the effect of atomic radii for A element in the Ti₃AC₂ phases (A = Si, Ge, and Sn) were studied by ab initio total energy calculations using plane-wave pseudopotential method based on DFT. The atomic radii of A element has a weak effect on the electronic structure. However, the bond stiffness was quantitatively examined, which shows that the bond stiffness is affected by the atomic radii of A element. The calculated results including lattice constants, internal coordinate, elastic modulus, sound velocity, and Debye temperature agree with experimental values very well. With the increase of atomic radii of A element from Si, Ge to Sn, the cohesive energy and elastic moduli as well as Debye temperature decrease, but the elastic anisotropy increases. This is related to the change of bond stiffness. It can be predicted that the fracture toughness of Ti₃SnC₂ would be comparable with that of Ti₃SiC₂ and Ti₃GeC₂.     

Catalytic metal-free intramolecular hydroaminations of non-activated aminoalkenes: a computational exploration

Frustrated Lewis pairs (FLPs) has been applied to catalytic metal-free hydrogenation. Can the FLP reactivity be used for catalytic hydroamination? Using density functional theory (DFT) calculations, we have explored whether the molecules cat1-cat3, which were previously designed by integrating the dearomatization-aromatization effect and the FLP reactivity, can catalyze the intramolecular hydroaminations of non-activated aminoalkenes to afford nitrogen heterocycles. The study shows that the γ-aminoalkene (am1) hydroamination catalyzed by cat1 proceeds via two steps (aminoalkene N-H bond activation and C-N bond formation) with experimentally accessible energetics, giving the five-membered nitrogen heterocycle product 1,1-dimethylpyrrolidine. The N-H bond activation is reversible. The C-N bond formation step undergoes a concerted mechanism and complies with the Markovnikov addition rule. Possible side reactions which may cause catalyst deactivation were confirmed to be energetically unfavorable. The molecules cat2 and cat3 are less effective than cat1 in catalyzing the am1 hydroamination, but the barriers are not too high. By following the most favorable pathway of the cat1-mediated am1 hydroamination, we further extended the substrate (am1) to other aminoalkenes, including the methyl and phenyl β-substituted am1 (i.e. am2 and am3, respectively), the benzyl-protected primary aminoalkene (am4), and the δ-aminoalkene (am5). The hydroaminations of am2 and am3 have energetics comparable with am1 hydroamination, the am5 hydroamination is energetically less favorable, and the am4 hydroamination is least favorable but could be realizable by elevating the temperature and pressure. We call experimental efforts to synthesize cat1-cat3 or similar new molecules on the basis of the design strategy.     

Resonantly pumped 1.645 μm high repetition rate Er:YAG laser Q-switched by a graphene as a saturable absorber

A fiber laser resonantly pumped 1.645 μm passively Q-switched Er:YAG laser is reported. Graphene on a silicon carbide was used as the saturable absorber for the Q-switching. The pulse energy of the 1.645 μm Q-switched Er:YAG laser was 7.05 μJ, with a pulse repetition rate of 35.6 kHz and an average output power of 251 mW.