两亲分子结构对铜网表面生长的Cu2S纳米材料形貌的影响

观察到两亲分子的结构对铜网表面生长的Cu2S一维纳米材料的形貌有较大的影响,含羧酸的强亲水型两亲分子--N-硬脂酰-L-谷氨酸有助于形成纳米线,而把两个羧基全部转化为酯基后,则倾向于形成具有分形结构的纳米带.     

乙烯基Ia3d介孔硅分子筛的环氧化及其固定化青霉素酰化酶(英文)

采用直接共聚法合成表面含有乙烯基的具有立方相Ia3d结构的介孔硅分子筛(V-ClMS),然后对乙烯基团进行环氧化制备得到表面环氧基功能化的介孔硅分子筛(E-CIMS),采用X射线衍射、N2吸附-脱附、透射电镜、热重分析和13C固体核磁共振对制备的介孔硅分子筛进行了表征.结果表明,表面含有乙烯基的V-ClMS介孔硅分子筛能被一步成功合成,并易于发生环氧化而获得表面环氧基功能化的E-CIMS介孔硅分子筛.将E-CIMS介孔硅分子筛作为载体用于固定化青霉素G酰化酶(PGA),研究了表面环氧基团对固定化PGA初活性和操作稳定性的影响.结果表明,随着表面环氧基团数量的增加,介孔硅分子筛孔径减小,表面疏水性增加,导致载酶量和初活性减小.但介孔硅分子筛表面适量的环氧基团能增强E-CIMS介孔硅分子筛与PGA之间的相互作用,从而提高固定化PGA的操作稳定性.     

A High Efficiency PDMS-Based Stabilizer for Dispersion Polymerization of L-lactide in Supercritical Carbon Dioxide

Dispersion polymerization of lactides and lactones has been studied and has received a great deal of attention used to prepare biodegradable polymers in supercritical carbon dioxide (ScCO₂). The triblock copolymers of poly(?-caprolactone) PCL-polydimethylsiloxane (PDMS)-poly(?-caprolactone) PCL by the feed ratio of 1:2:1 and 1:3:1, respectively were synthesized to be used as the stabilizers in the dispersion polymerization of L-lactide. The fine poly(L-lactide) (PLLA) powders were obtained at the concentrations of 3% to 5%w/w (stabilizer/monomer). The results demonstrated that the triblock copolymers were the effective stabilizers for the dispersion polymerization of L-lactide. It was also found that the cooling process had a significant effect on the particle size of the fine powders. In order to obtain the best PLLA powders, it would be necessary to use the cooling process with stirring.     

第七届全国固体力学青年学者学术研讨会报告综述

简要介绍了在哈尔滨工业大学召开的第七届全国固体力学青年学者学术研讨会的会议情况,概括总结了与会学者所做的学术报告内容,并就新时期固体力学的发展提出了一些思考和建议.     

Coupled atomic-molecular condensates in a double-well potential: decaying molecular oscillations

We present a four-mode model that describes coherent photo-association (PA) in a double-well Bose-Einstein condensate, focusing on the average molecular populations in certain parameters. Our numerical results predict an interesting strong-damping effect of molecular oscillations by controlling the particle tunnellings and PA light strength, which may provide a promising way for creating a stable molecular condensate via coherent PA in a magnetic double-well potential.     

Rheological study on structural transition in polyethersulfone‐modified bismaleimide resin during isothermal curing

The structural transition in the polyethersulfone (PES)‐modified bismaleimide resin, 4,4′‐bismaleimidodiphenylmethane (BDM), during isothermal curing was studied by using rheological technique, different scanning calorimetry (DSC), and time resolved light scattering (TRLS). Comparing with the cure of neat bismaleimide, two separate tan δ crossover points were observed because of the phase separation during curing the blends of PES/BDM. These two structural transitions stemmed from the fixing of phase structure of the system and the chemical crosslinking of bismaleimide, respectively. The effect of curing temperature and the PES content on structural transition was discussed and found that the occurrence of two structural transition exhibited the different dependency of curing temperature and PES content. The relaxation exponent n and gel strength S were also found to be temperature‐dependent and composition‐dependent. Moreover, the relaxation exponent n of the second structural transition is much lower than that of the first structural transition in the PES/bismaleimide blends. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3102–3108, 2006     

磁随机存储器中垂直电流驱动的磁性隧道结自由层的磁化翻转

在基于磁性隧道结(Magnetic Tunneling Junction，MTJ)的磁随机存储器(Magnetoresistantive Random Access Memory，MRAM)中利用通过MTJ的垂直电流，实现信息写入的新方法，同时给出了基于此新方法的一种新的MRAM结构和驱动原理图，并分析了它的读和写操作的可行性具体过程. 关键词： 垂直电流 磁性隧道结 磁随机存储器     

Optimal control of price and production in an assemble-to-order system

We study the optimal control of an assembly system that produces one assembled-to-order final product with multiple made-to-stock components and sells it at variable price. It is shown that a threshold control on component production, product price, and product orders maximizes total discounted profit over an infinite horizon.     

Solution to the Cosmological Constant Problem by Gauge Theory of Gravity

Based on geometry picture of gravitational gauge theory, the cosmological constant is determined theoreti-cally. The cosmological constant is related to the average energy density of gravitational gauge field. Because the energydensity of gravitational gauge field is negative, the cosmological constant is positive, which generates repulsive force onstars to make the expansion rate of the Universe accelerated. A rough estimation of it gives out its magnitude of theorder of about 10-52m-2, which is well consistent with experimental results.